Search Results - "Bera, Sachinath"
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Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids
Published in Chemistry : a European journal (16-05-2022)“…Herein, we disclose cyclic(alkyl)(amino)carbenes (CAACs) to be one‐electron reductants under the formation of a transient radical cation as indicated by EPR…”
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Mixed-Valence o-Iminobenzoquinone and o-Iminobenzosemiquinonate Anion Radical Complexes of Cobalt: Valence Tautomerism
Published in European journal of inorganic chemistry (01-08-2016)“…2,4‐Di‐tert‐butyl‐N‐[2‐(phenylthio)]phenyl‐o‐iminobenzosemiquinonate anion radical (LSPhISQ·–) and o‐iminobenzoquinone (LSPhIQ) based mixed‐valence complexes…”
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Oxidovanadium Complexes of 2,2′-Bipyridine, 1,10 Phenanthroline, and p-Nitro-o-aminophenol - Radical versus Nonradical States
Published in European journal of inorganic chemistry (01-01-2016)“…2,2′‐Bipyridine (bpy), 1,10‐phenanthronline (phen) and p‐nitro‐o‐aminophenol (NO2LH2) oxidovanadium complexes of the types [(LONO2–)(VO)(bpy)] (1),…”
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Orthometalated N‑(Benzophenoxazine)‑o‑aminophenol: Phenolato versus Phenoxyl States
Published in ACS omega (31-10-2018)“…The molecular and electronic structures of the orthometalated ruthenium(III) and osmium(III) complexes of N-(benzophenoxazine)-o-aminophenol (OXLH2) that…”
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Redox Cascades and Making of a C–C Bond: 1,2-Benzodiazinyl Radicals and a Copper Complex of a Benzodiazine
Published in Journal of organic chemistry (15-02-2019)“…Two 1,2-benzodiazinyl radicals, cinnolinyl radicals by name, were successfully isolated by cascade routes using 1,4-naphthoquinone as a precursor. Reaction of…”
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Synthesis and comparative studies of photophysical and electrochemical properties of three different types of new heteroleptic 5-arylazo-8-hydroxyquinoline complexes of rhodium including trans → cis isomerism studies
Published in Journal of organometallic chemistry (01-05-2019)“…Refluxing [Rh(2-phpy)2(Cl)]2 separately with the equivalent amount of 5-phenylazo-8-hydroxyquinoline (Hq1), 5-(4-fluorophenylazo)-8-hydroxyquinoline (Hq2) and…”
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Molecular and Electronic Structures of Ruthenium Complexes Containing an ONS-Coordinated Open-Shell π Radical and an Oxidative Aromatic Ring Cleavage Reaction
Published in Inorganic chemistry (20-03-2017)“…The coordination chemistry of 2,4-di-tert-butyl-6-[(2-mercaptophenyl)amino]phenol (LONSH3), which was isolated as a diaryl disulfide form, (LONSH2)2, with a…”
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Cobalt Ion Promoted Redox Cascade: A Route to Spiro Oxazine-Oxazepine Derivatives and a Dinuclear Cobalt(III) Complex of an N‑(1,4-Naphthoquinone)‑o‑aminophenol Derivative
Published in Inorganic chemistry (06-11-2017)“…The study discloses that the redox activity of N-(1,4-naphthoquinone)-o-aminophenol derivatives (LRH2) containing a (phenol)-NH-(1,4-naphthoquinone) fragment…”
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Oxo transfer reaction: Dioxido and monooxidovanadium(V) complexes
Published in Journal of the Indian Chemical Society (01-07-2022)“…A dioxidovanadium(V) complex of type [(LONOH−)(VO2)] (1) was isolated where LONOH2 is a tridentate ONO donor benzhydrazide ligand. 1 undergoes an oxo transfer…”
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Cover Feature: Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids (Chem. Eur. J. 28/2022)
Published in Chemistry : a European journal (16-05-2022)“…Creating Kekulé diradicaloids: That cyclic(alkyl)(amino)(carbene)—CAAC—donates one electron during the formation of a transient radical‐cation was evidenced by…”
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Radical and Non-Radical States of the [Os(PIQ)] Core (PIQ = 9,10-Phenanthreneiminoquinone): Iminosemiquinone to Iminoquinone Conversion Promoted o‑Metalation Reaction
Published in Inorganic chemistry (16-05-2016)“…The coordination and redox chemistry of 9,10-phenanthreneiminoquinone (PIQ) with osmium ion authenticating the [OsII(PIQ•–)], [OsIII(PIQ•–)], [OsIII(C,N-PIQ)],…”
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Comment on “Disclosing Cyclic(Alkyl)(Amino)Carbenes as a One‐Electron Reductant: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids”
Published in Chemistry : a European journal (06-12-2023)“…This correspondence addresses a misassignment of an EPR spectrum of 2 in a recent publication (Chem. Eur. J. 2022, 28, e202104567) by Dr. Jana and co‐workers…”
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Crystallographic Elucidation of Stimuli-Controlled Molecular Rotation for a Reversible Sol–Gel Transformation
Published in Journal of organic chemistry (20-03-2020)“…To get an idea about the most probable microporous supramolecular environment in the gel state, gelator molecule 1 has been crystallized from its gelling…”
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o-Iminobenzoquinone and o-Iminobenzosemiquinonate Anion Radical Complexes of Rhodium and Ruthenium
Published in European journal of inorganic chemistry (01-08-2016)“…2,4‐Di‐tert‐butyl‐N‐[2‐(phenylthio)]phenyl‐o‐iminobenzosemiquinonate anion radical (LSPhISQ·–) and o‐iminobenzoquinone (LSPhIQ) complexes of types…”
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