Search Results - "Benetti, Edmondo M"
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Polyoxazoline biointerfaces by surface grafting
Published in European polymer journal (01-03-2017)“…[Display omitted] Functionalization of biomaterials by “grafting-to” of functional polymers represents a pivotal strategy to hinder unspecific biological…”
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Topological Polymer Chemistry Enters Surface Science: Linear versus Cyclic Polymer Brushes
Published in Angewandte Chemie International Edition (12-12-2016)“…The cyclic polymer topology strongly alters the interfacial, physico‐chemical properties of polymer brushes, when compared to the linear counterparts. In this…”
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3
Surface-Initiated Photoinduced ATRP: Mechanism, Oxygen Tolerance, and Temporal Control during the Synthesis of Polymer Brushes
Published in Macromolecules (28-04-2020)“…Surface-initiated, photoinduced atom transfer radical polymerization (SI-photoATRP) enables the controlled and rapid synthesis of compositionally diverse…”
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Oxygen Tolerant and Cytocompatible Iron(0)-Mediated ATRP Enables the Controlled Growth of Polymer Brushes from Mammalian Cell Cultures
Published in Journal of the American Chemical Society (12-02-2020)“…The use of zerovalent iron (Fe0)-coated plates, which act both as a source of catalyst and as a reducing agent during surface-initiated atom transfer radical…”
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Surface-Initiated Cu(0)-Mediated CRP for the Rapid and Controlled Synthesis of Quasi-3D Structured Polymer Brushes
Published in ACS macro letters (19-02-2019)“…Surface-initiated controlled radical polymerization mediated by Cu(0) plate (SI-Cu(0)plate-CRP) is an extremely effective and versatile technique for the…”
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Nanoassemblies of Tissue-Reactive, Polyoxazoline Graft-Copolymers Restore the Lubrication Properties of Degraded Cartilage
Published in ACS nano (28-03-2017)“…Osteoarthritis leads to an alteration in the composition of the synovial fluid, which is associated with an increase in friction and the progressive and…”
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7
Oxygen Tolerance during Surface-Initiated Photo-ATRP: Tips and Tricks for Making Brushes under Environmental Conditions
Published in ACS macro letters (15-08-2023)“…Achieving tolerance toward oxygen during surface-initiated reversible deactivation radical polymerization (SI-RDRP) holds the potential to translate the…”
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8
C1q-Mediated Complement Activation and C3 Opsonization Trigger Recognition of Stealth Poly(2-methyl-2-oxazoline)-Coated Silica Nanoparticles by Human Phagocytes
Published in ACS nano (26-06-2018)“…Poly(2-methyl-2-oxazoline) (PMOXA) is an alternative promising polymer to poly(ethylene glycol) (PEG) for design and engineering of macrophage-evading…”
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9
Bioinert and Lubricious Surfaces by Macromolecular Design
Published in Langmuir (22-10-2019)“…The modification of a variety of biomaterials and medical devices often encompasses the generation of biopassive and lubricious layers on their exposed…”
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10
Topology Effects on the Structural and Physicochemical Properties of Polymer Brushes
Published in Macromolecules (10-10-2017)“…The application of polymer “brushes”, with their unique physicochemical properties, has led to a radical change in the way we functionalize biomaterials or…”
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Next‐Generation Polymer Shells for Inorganic Nanoparticles are Highly Compact, Ultra‐Dense, and Long‐Lasting Cyclic Brushes
Published in Angewandte Chemie International Edition (10-04-2017)“…Cyclic poly‐2‐ethyl‐2‐oxazoline (PEOXA) ligands for superparamagnetic Fe3O4 nanoparticles (NPs) generate ultra‐dense and highly compact shells, providing…”
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12
Loops and Cycles at Surfaces: The Unique Properties of Topological Polymer Brushes
Published in Chemistry : a European journal (12-09-2017)“…Grafting synthetic polymers to inorganic and organic surfaces to yield polymer “brushes” has represented a revolution in many fields of materials science…”
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13
Surface-grafted assemblies of cyclic polymers: Shifting between high friction and extreme lubricity
Published in European polymer journal (01-01-2019)“…[Display omitted] •The nanotribological properties of cyclic polymer brushes are strongly determined by their grafting density.•By increasing the surface…”
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14
Topological Polymer Chemistry Enters Materials Science: Expanding the Applicability of Cyclic Polymers
Published in ACS macro letters (21-07-2020)“…Polymer-topology effects can alter technologically relevant properties when cyclic macromolecules are applied within diverse materials formulations. These…”
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15
Controlled Crosslinking Is a Tool To Precisely Modulate the Nanomechanical and Nanotribological Properties of Polymer Brushes
Published in Macromolecules (11-04-2017)“…Covalent crosslinking of weak polyelectrolyte brushes widens the tuning potential for their swelling, nanomechanical, and nanotribological properties, which…”
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16
Functional Nanoassemblies of Cyclic Polymers Show Amplified Responsiveness and Enhanced Protein-Binding Ability
Published in ACS nano (25-08-2020)“…The physicochemical properties of cyclic polymer adsorbates are significantly influenced by the steric and conformational constraints introduced during their…”
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17
Self-Assembly of Focal Point Oligo-catechol Ethylene Glycol Dendrons on Titanium Oxide Surfaces: Adsorption Kinetics, Surface Characterization, and Nonfouling Properties
Published in Journal of the American Chemical Society (20-07-2011)“…This work covers the synthesis of second-generation, ethylene glycol dendrons covalently linked to a surface anchor that contains two, three, or four catechol…”
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Understanding the effect of hydrophobic protecting blocks on the stability and biopassivity of polymer brushes in aqueous environments: A Tiramisù for cell-culture applications
Published in Polymer (Guilford) (19-08-2016)“…Despite the wide range and versatility of polymer-grafting methods to produce biopassive interfaces, commonly applied polymer brushes suffer from an intrinsic…”
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The role of the interplay between polymer architecture and bacterial surface properties on the microbial adhesion to polyoxazoline-based ultrathin films
Published in Biomaterials (01-12-2010)“…Abstract Surface platforms were engineered from poly( l -lysine)- graft -poly(2-methyl-2-oxazoline) (PLL- g -PMOXA) copolymers to study the mechanisms involved…”
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Buried, Covalently Attached RGD Peptide Motifs in Poly(methacrylic acid) Brush Layers: The Effect of Brush Structure on Cell Adhesion
Published in Langmuir (07-10-2008)“…Iniferter-mediated surface-initiated photopolymerization was used to graft poly(methacrylic acid) (PMAA) brush layers obtained from surface-attached iniferters…”
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