Search Results - "Belogorlova, Natalia A"
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Structure of Tris[2-(4-pyridyl)ethyl]phosphine, Tris[2-(2-pyridyl)ethyl]phosphine, and Their Chalcogenides in Solution: Dipole Moments, IR Spectroscopy, and DFT Study
Published in Molecules (Basel, Switzerland) (23-12-2023)“…Tris(hetaryl)substituted phosphines and their chalcogenides are promising polydentate ligands for the design of metal complexes. An experimental and…”
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Triton-X-100 as an Organic Catalyst for One-Pot Synthesis of Arylmethyl-H-phosphinic Acids from Red Phosphorus and Arylmethyl Halides in the KOH/H2O/Toluene Multiphase Superbase System
Published in Catalysts (01-04-2023)“…Triton-X-100, a polyethylene glycol 4-(tert-octyl)phenyl ether, has been found to be an active micellar organic catalyst for the one-pot selective synthesis of…”
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Synthesis of Long‐Chain n‐Alkylphosphonic Acids by Phosphonylation of Alkyl Bromides with Red Phosphorus and Superbase under Micellar/Phase Transfer Catalysis
Published in European journal of organic chemistry (12-03-2021)“…Long‐chain n‐Alkylphosphonic acids, AlkP(O)(OH)2, are synthesized in up to 91 % yield (mostly 40–60 %) by straightforward phosphonylation of alkyl bromides…”
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Superbase‐Assisted Selective Synthesis of Triarylphosphines from Aryl Halides and Red Phosphorus: Three Consecutive Different SNAr Reactions in One Pot
Published in European journal of organic chemistry (30-09-2019)“…Aryl halides, ArX (Ar = Ph, 2‐, 3‐ and 4‐Tol, 1‐ and 2‐Np, 4‐C6H4CONH2; X = F, Cl, Br), rapidly and exothermically (100–180 °C, 0.5–2 h) react with red…”
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Conformational analysis and stereochemical dependences of (31)P-(1)H spin-spin coupling constants of bis(2-phenethyl)vinylphosphine and related phosphine chalcogenides
Published in Magnetic resonance in chemistry (01-04-2009)“…Theoretical energy-based conformational analysis of bis(2-phenethyl)vinylphosphine and related phosphine oxide, sulfide and selenide synthesized from available…”
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Conformational analysis and stereochemical dependences of 31P-1H spin-spin coupling constants of bis(2-phenethyl)vinylphosphine and related phosphine chalcogenides
Published in Magnetic resonance in chemistry (01-04-2009)“…Theoretical energy‐based conformational analysis of bis(2‐phenethyl)vinylphosphine and related phosphine oxide, sulfide and selenide synthesized from available…”
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Structure of Tris[2-ethyl]phosphine, and Their Chalcogenides in Solution: Dipole Moments, IR Spectroscopy, and DFT Study
Published in Molecules (Basel, Switzerland) (01-12-2023)“…Tris(hetaryl)substituted phosphines and their chalcogenides are promising polydentate ligands for the design of metal complexes. An experimental and…”
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Superbase‐Assisted Selective Synthesis of Triarylphosphines from Aryl Halides and Red Phosphorus: Three Consecutive Different S N Ar Reactions in One Pot
Published in European journal of organic chemistry (30-09-2019)“…Aryl halides, ArX (Ar = Ph, 2‐, 3‐ and 4‐Tol, 1‐ and 2‐Np, 4‐C 6 H 4 CONH 2 ; X = F, Cl, Br), rapidly and exothermically (100–180 °C, 0.5–2 h) react with red…”
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Synthesis of Diorganylphosphine Oxides Bearing Hetarylalkyl Moieties and Study of Their Antimicrobial Activities
Published in ChemistrySelect (Weinheim) (20-09-2022)“…Tertiary phosphine oxides have been synthesized by the reaction of secondary phosphine oxides with diverse hetarylmethylchlorides (pyridines, imidazoles,…”
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Single-stage synthesis of alkyl-H-phosphinic acids from elemental phosphorus and alkyl bromides
Published in Mendeleev communications (01-05-2019)“…[Display omitted] Elemental phosphorus (red or white) reacts with alkyl bromides at 60–62°C in the phase-transfer catalytic system KOH/H2O/PhMe/Et3BnNCl to…”
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2-Halopyridines in the triple reaction in the Pn/KOH/DMSO system to form tri(2-pyridyl)phosphine: Experimental and quantum-chemical dissimilarities
Published in Mendeleev communications (01-09-2018)“…[Display omitted] Experimental and quantum-chemical features of the triple nucleophilic substitution of halogen atoms in 2-chloro- and 2-bromopyridines under…”
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Catalyst-free addition of secondary phosphine chalcogenides to pyrazolecarbaldehydes
Published in Mendeleev communications (01-11-2019)“…[Display omitted] (Chalcogenophosphoryl)(hydroxyl)methyl-substituted pyrazoles were obtained by catalyst-free reaction between 4- and 5-pyrazolecarbaldehydes…”
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Phosphorus halide free synthesis of 1,2,3,4-tetrahydroisophosphinoline 2-oxides
Published in Mendeleev communications (01-01-2018)“…[Display omitted] The herein developed phosphorus halide free synthesis of 1,2,3,4-tetrahydroisophosphinoline 2-oxides involves intramolecular…”
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Conformational analysis and stereochemical dependences of 31 P– 1 H spin–spin coupling constants of bis(2‐phenethyl)vinylphosphine and related phosphine chalcogenides
Published in Magnetic resonance in chemistry (01-04-2009)“…Theoretical energy‐based conformational analysis of bis(2‐phenethyl)vinylphosphine and related phosphine oxide, sulfide and selenide synthesized from available…”
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