Search Results - "Belogolova, Elena"
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Electrooxidation of Hypercoordinated Derivatives of Silicon and Reactivity of Their Electrogenerated Cation Radicals: 1-Substituted Silatranes
Published in Molecules (Basel, Switzerland) (20-07-2023)“…Electrochemical oxidation of 1-R-substituted silatranes (R = Me, vinyl, (CH ) CN, CH Ph, CH (C H ), Ph, C H Me, -Cl-C H , Cl)-classical representatives of…”
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“Outlaw” Dipole-Bound Anions of Intra-Molecular Complexes
Published in Journal of the American Chemical Society (29-01-2020)“…Using the example of silatranes XSi(OCH2CH2)3N (X = Me, H, F, Cl), XS, it was found that the effect of the dipole-bound (DB) electron on the cage…”
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3
Correlation among the Gas-Phase, Solution, and Solid-Phase Geometrical and NMR Parameters of Dative Bonds in the Pentacoordinate Silicon Compounds. 1‑Substituted Silatranes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (27-06-2013)“…Silatranes XSi(OCH2CH2)3N exhibit a good linear relationship between their experimental and calculated (IGLO and GIAO) values of the NMR chemical shifts of…”
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Electrochemical Oxidation and Radical Cations of Structurally Non‐rigid Hypervalent Silatranes: Theoretical and Experimental Studies
Published in Chemistry : a European journal (03-02-2017)“…Using 18 silatranes XSi(OCH2CH2)3N (1) as examples, the potentials of electrochemical oxidation E0 of the hypervalent compounds of Si were calculated for the…”
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5
Dipole-Bound Anions of Intramolecular Complexes
Published in The journal of physical chemistry letters (15-03-2018)“…Dipole-bound molecular anions are often envisioned as unperturbed neutral, polar molecules with single excess electrons. We report the observation of…”
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Correction to “ ‘Outlaw’ Dipole-Bound Anions of Intra-Molecular Complexes”
Published in Journal of the American Chemical Society (05-08-2020)Get full text
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7
Comparative Analysis of the Interaction of Helicobacter pylori with Human Dendritic Cells, Macrophages, and Monocytes
Published in Infection and Immunity (01-08-2012)“…Classifications Services IAI Citing Articles Google Scholar PubMed Related Content Social Bookmarking CiteULike Delicious Digg Facebook Google+ Mendeley Reddit…”
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Helicobacter pylori induces miR-155 in T cells in a cAMP-Foxp3-dependent manner
Published in PloS one (02-03-2010)“…Amongst the most severe clinical outcomes of life-long infections with Helicobacter pylori is the development of peptic ulcers and gastric…”
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9
A New Approach to the Design of Neutral 10-C-5 Trigonal-Bipyramidal Carbon Compounds: A "[pi]-Electron Cap" Effect
Published in Chemistry : a European journal (29-07-2013)“…DFT (B3LYP, M06-2X) and MP2 methods are applied to the design of a wide series of the potentially 10-C-5 neutral compounds based on 6-azabicyclotetradecanes:…”
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A New Approach to the Design of Neutral 10-C-5 Trigonal-Bipyramidal Carbon Compounds: A "π-Electron Cap" Effect
Published in Chemistry : a European journal (29-07-2013)“…DFT (B3LYP, M06‐2X) and MP2 methods are applied to the design of a wide series of the potentially 10‐C‐5 neutral compounds based on 6‐azabicyclotetradecanes:…”
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11
Molecular Design of Hypercoordinated Silacyclophanes
Published in Organometallics (14-11-2011)“…MP2 and DFT (B3LYP, M06-2X) methods using the 6-31G(d) and 6-311++G(d,p) basis sets are applied to the investigation of the structure of a wide series of…”
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12
Molecular Design of Neutral Intramolecular Complexes Bearing Two Silicon Atoms Anchored by a Carbonyl Oxygen Atom: N,N′-Bis(silylmethyl)propylene Ureas
Published in Chemistry : a European journal (20-02-2006)“…B3LYP and MP2 computations have been performed on a variety of Si,Si′‐substituted N,N′‐bis(silylmethyl)propylene ureas. According to electron‐density…”
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13
Hypercoordinated Carbon in 2,8,9-Sila- and Thia-Substituted Carbatranes
Published in Organometallics (27-08-2007)“…The structures of carbatranes XC(SiH2CH2CH2)3N (8) and XC(SCH2CH2)3N (9), where X = H, F, and their in and out protonated forms were studied at the MP2 level…”
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14
AIM and ELF Electronic Structure/G2 and G3 π-Bond Energy Relationship for Doubly Bonded Silicon Species, H2SiX (X = E14H2, E15H, E16)1
Published in Organometallics (18-12-2006)“…π-Bond energies in doubly bonded silicon species, H2SiX (X = E14H2, E15H, E16), were determined using G2 and G3 procedures. In addition, the distribution of…”
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15
Molecular Design of Bis-Chelate N-Donor-Stabilized Silaethenes: Theoretical Study of 1,1-Bis[N-(dimethylamino)acetimidato]silene
Published in Organometallics (10-05-2004)“…RHF/6-31G* and B3LYP/6-31G* computations were performed on the silene [Me2NNC(Me)O]2SiCH2 (6) and analyzed through the use of properties of atoms in…”
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Isomer-selective dative bond O→M (M = Si, Ge) for designing new photochromic hemi-indigo systems
Published in Journal of organometallic chemistry (15-01-2022)“…•Silyl and germyl-substituted hemi-indigo photochromic systems were theoretically designed.•The coordination of Si and Ge with carbonyl oxygen atom is…”
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17
Hypervalent benzophenones
Published in Journal of organometallic chemistry (01-03-2018)“…Benzophenones (BPs) of the type 2-R-BP and 2,2′-R-BP, carrying silicon- or germanium-containing substituents R (R = EY2X; E = Si, Ge; Y = H, Me, F, Cl; X = H,…”
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18
Helicobacter pylori outer membrane protein HopQ identified as a novel T4SS‐associated virulence factor
Published in Cellular microbiology (01-11-2013)“…Summary Helicobacter pylori is a bacterial pathogen that colonizes the gastric niche of ∼ 50% of the human population worldwide and is known to cause peptic…”
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Modulation of the CD4⁺ T-Cell Response by Helicobacter pylori Depends on Known Virulence Factors and Bacterial Cholesterol and Cholesterol α-Glucoside Content
Published in The Journal of infectious diseases (01-11-2011)“…Helicobacter pylori blocks the proliferation of human CD4⁺ T cells, facilitated by vacuolating exotoxin (VacA) and γ-glutamyl transpeptidase (GGT). H…”
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Cage Complexes of Carbenium and Silylium Cations with an Aromatic Base. Is the η 6 Coordination Type Realizable?
Published in Organometallics (12-11-2012)Get full text
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