Synthesis and Structure of Phosphito- and Thiophosphatocavitands

Phosphitocavitands, which on sulfurization result in all-cis-thiophosphatocavitands, have been obtained by phosphocyclization of octahydroxytetramethyl[14] metacyclophane with amides of phosphorous acid, as confirmed by 1H and 31P NMR spectroscopy and X-ray analysis.

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Bibliographic Details
Published in:Mendeleev communications Vol. 5; no. 4; pp. 131 - 133
Main Authors: Nifantyev, Eduard E., Maslennikova, Vera I., Panina, Elena V., Bekker, Anna R., Vasyanina, Larisa K., Lysenko, Konstantin A., Antipin, Mikhail Yu, Struchkov, Yurii T.
Format: Journal Article
Language:English
Published: Elsevier B.V 1995
Online Access:Get full text
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Summary:Phosphitocavitands, which on sulfurization result in all-cis-thiophosphatocavitands, have been obtained by phosphocyclization of octahydroxytetramethyl[14] metacyclophane with amides of phosphorous acid, as confirmed by 1H and 31P NMR spectroscopy and X-ray analysis.
ISSN:0959-9436
DOI:10.1070/MC1995v005n04ABEH000490