Search Results - "Behm, R. J"
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Activation of Molecular Oxygen and the Nature of the Active Oxygen Species for CO Oxidation on Oxide Supported Au Catalysts
Published in Accounts of chemical research (18-03-2014)“…Although highly dispersed Au catalysts with Au nanoparticles (NPs) of a few nanometers in diameter are well-known for their high catalytic activity for several…”
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2
Ethanol, Acetaldehyde and Acetic Acid Adsorption/Electrooxidation on a Pt Thin Film Electrode under Continuous Electrolyte Flow: An in Situ ATR-FTIRS Flow Cell Study
Published in Journal of physical chemistry. C (03-06-2010)“…The interaction of ethanol and its oxidative C2 derivatives acetaldehyde and acetic acid with a Pt thin film electrode in 0.5 M H2SO4 solution was investigated…”
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3
Selective CO Methanation on Ru/TiO2 Catalysts: Role and Influence of Metal–Support Interactions
Published in ACS catalysis (06-11-2015)“…Aiming at a detailed understanding of the role of metal–support interactions in the selective methanation of CO in CO2-rich reformate gases, we have…”
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4
Ethanol Electrooxidation on a Carbon-Supported Pt Catalyst: Reaction Kinetics and Product Yields
Published in The journal of physical chemistry. B (16-12-2004)“…The ethanol oxidation reaction (EOR) on a carbon-supported Pt nanoparticle catalyst was studied by cyclic voltammetry and potential-step measurements as a…”
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Ethanol electro-oxidation on carbon-supported Pt, PtRu and Pt3Sn catalysts : A quantitative DEMS study
Published in Journal of power sources (01-03-2006)“…The electrocatalytic activity of commercial carbon supported PtRu/Vulcan and Pt3Sn/Vulcan bimetallic catalysts (E-TEK, Inc.) for ethanol oxidation under well…”
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Conference Proceeding Journal Article -
6
Bridge-Bonded Formate: Active Intermediate or Spectator Species in Formic Acid Oxidation on a Pt Film Electrode?
Published in Langmuir (05-12-2006)“…We present and discuss the results of an in situ IR study on the mechanism and kinetics of formic acid oxidation on a Pt film/Si electrode, performed in an…”
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Ethanol electrooxidation on novel carbon supported Pt/SnOx/C catalysts with varied Pt:Sn ratio
Published in Electrochimica acta (01-12-2007)“…Novel carbon supported Pt/SnOx/C catalysts with Pt:Sn atomic ratios of 5:5, 6:4, 7:3 and 8:2 were prepared by a modified polyol method and characterized with…”
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Conference Proceeding Journal Article -
8
The Role of Atomic Ensembles in the Reactivity of Bimetallic Electrocatalysts
Published in Science (American Association for the Advancement of Science) (07-09-2001)“…Bimetallic electrodes are used in a number of electrochemical processes, but the role of particular arrangements of surface metal atoms (ensembles) has not…”
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Kinetics and mechanism of the low-temperature water-gas shift reaction on Au/CeO2 catalysts in an idealized reaction atmosphere
Published in Journal of catalysis (10-12-2006)“…Kinetic and mechanistic aspects of the low-temperature water-gas shift reaction on Au/CeO2 catalysts in idealized reaction atmosphere (1 kPa CO, 2 kPa H2O) and…”
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10
Activity, selectivity, and adsorbed reaction intermediates/reaction side products in the selective methanation of CO in reformate gases on supported Ru catalysts
Published in Journal of catalysis (05-02-2010)“…The removal of CO in hydrogen rich containing feed gas via selective methanation was studied on two differently supported Ru catalysts. The kinetic activity is…”
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11
Support effects in the Au-catalyzed CO oxidation – Correlation between activity, oxygen storage capacity, and support reducibility
Published in Journal of catalysis (15-12-2010)“…We demonstrate a clear correlation between the oxygen storage capacity (OSC) and the activity for CO oxidation for four different oxide-supported gold…”
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12
Adsorption and oxidation of ethanol on colloid-based Pt/C, PtRu/C and Pt3Sn/C catalysts: in situ FTIR spectroscopy and on-line DEMS studies
Published in Physical chemistry chemical physics : PCCP (07-06-2007)“…The interaction of colloid-based, carbon supported Pt/C (40 wt%), PtRu/C (45 wt%) and Pt3Sn/C (24 wt%) catalysts with ethanol and their performance for ethanol…”
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13
Reactive oxygen on a Au/TiO2 supported catalyst
Published in Journal of catalysis (15-05-2009)“…We investigated the oxygen storage capacity (OSC) of Au/TiO2 catalysts as well as its correlation with the activity for CO oxidation and in particular the…”
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14
Activation of a Au/CeO2 catalyst for the CO oxidation reaction by surface oxygen removal/oxygen vacancy formation
Published in Journal of catalysis (25-10-2007)“…Applying quantitative temporal analysis of products (TAP) techniques, we demonstrate that after calcination, a Au/CeO2 catalyst is only slightly active for CO…”
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15
Methanol Electrooxidation over Pt/C Fuel Cell Catalysts: Dependence of Product Yields on Catalyst Loading
Published in Langmuir (19-08-2003)“…We have investigated the influence of the catalyst loading (7−35 μgPt·cm-2) on methanol oxidation product yields over Vulcan XC72 supported Pt catalyst by…”
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TAP reactor studies of the oxidizing capability of CO2 on a Au/CeO2 catalyst – A first step toward identifying a redox mechanism in the Reverse Water–Gas Shift reaction
Published in Journal of catalysis (01-06-2013)“…Active oxygen is formed by interaction of CO2 with a pre-reduced Au/CeO2 catalyst, supporting a redox mechanism for the RWGS reaction at T>200°C. [Display…”
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17
Ethanol electrooxidation on a carbon-supported Pt catalyst at elevated temperature and pressure: A high-temperature/high-pressure DEMS study
Published in Journal of power sources (01-05-2009)“…The electrooxidation of ethanol on a Pt/Vulcan catalyst was investigated in model studies by on-line differential electrochemical mass spectrometry (DEMS) over…”
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Journal Article Conference Proceeding -
18
Highly active Au/TiO2 catalysts for low-temperature CO oxidation: preparation, conditioning and stability
Published in Catalysis letters (01-07-2003)“…Using a modified depositionprecipitation procedure and a new reductive conditioning method, Au/TiO2 catalysts with small metallic Au particles (<2 nm) and a…”
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In situ ATR-FTIRS coupled with on-line DEMS under controlled mass transport conditions—A novel tool for electrocatalytic reaction studies
Published in Electrochimica acta (10-05-2007)“…We present a novel combination of in situ attenuated total reflection-infrared spectroscopy (ATR-FTIRS) and on-line differential electrochemical mass…”
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Journal Article Conference Proceeding -
20
Ethanol oxidation on novel, carbon supported Pt alloy catalysts—Model studies under defined diffusion conditions
Published in Electrochimica acta (05-10-2006)“…The structure, surface composition and activity/selectivity for ethanol oxidation of carbon supported Pt alloy catalysts with different composition and…”
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