Search Results - "Bedekar, A. V."
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Investigations in the Transition Metal Catalyzed Aziridination of Olefins, Amination, and Other Insertion Reactions with Bromamine-T as the Source of Nitrene
Published in Journal of organic chemistry (12-01-2001)“…Investigations into the transition metal catalyzed aziridination of olefins with Bromamine-T as a new source of nitrene is presented in this account…”
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2
Preparation of polymer anchored Pd-catalysts: Application in Mizoroki–Heck Reaction
Published in Journal of molecular catalysis. A, Chemical (01-11-2010)“…A series of polymer anchored Schiff bases were prepared from chloromethylated styrene–divinylbenzene copolymer beads and loaded with PdCl 2 to get air and…”
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3
Bromamine-T mediated aziridination of olefins with a new polymer supported Manganese(II) complex as catalyst
Published in Journal of molecular catalysis. A, Chemical (31-10-2000)“…Chloromethylated styrene-divinyl benzene of 8% cross-link was functionalized using o-phenylene diamine and finally it was treated with Mn(II) for the formation…”
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4
Natural Kaolinitic clay catalyzed conversion of nitriles to 2-oxazolines
Published in Tetrahedron letters (01-01-1998)“…Natural Kaolinitic clay has been found effective as catalyst in the conversion of aromatic and aliphatic nitriles with 1,2-aminoalcohol to 2-oxazolines (56 –…”
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1-(α-Aminobenzyl)-2-naphthol as phosphine-free ligand for Pd-catalyzed Suzuki and one-pot Wittig-Suzuki reaction
Published in Applied organometallic chemistry (01-08-2012)“…Air stable and easily accessible, 1‐(α‐aminobenzyl)‐2‐naphthols are used as efficient phosphine‐free ligands in palladium‐catalyzed Suzuki reaction for a…”
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6
Microwave Assisted Preparation of Isatins and Synthesis of (±)-Convolutamydine-A
Published in Synthetic communications (01-10-1999)“…Microwave assisted preparation of a number of isatin derivatives is reported. A simple synthesis of (±)-convolutamydine-A, a potent compound against leukemia…”
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Annulated bicyclo[2.2.2]octenones : 9-hydroxy-9-chloromethyl-endo-tricyclo[5.2.2.02,6]undeca-4,10-diene-3-spiro(1'-cyclopropane)-8-one and 12-hydroxy-12-chloromethyl-endo-tricyclo [8.2.2.02,9]tetradeca-13-en-11-one
Published in Journal of chemical crystallography (01-09-1995)Get full text
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Environmentally benign chlorination and bromination of aromatic amines, hydrocarbons and naphthols
Published in Tetrahedron letters (19-05-2003)“…A simple and efficient procedure for chlorination and bromination of aromatic amines, hydrocarbons and naphthols by the action of aqueous hydrohalic acid and…”
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Clay catalyzed chemoselective Michael type addition of aliphatic amines to α,β-ethylenic compounds
Published in Tetrahedron (22-10-2001)Get full text
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10
A new, environment friendly protocol for iodination of electron-rich aromatic compounds
Published in Tetrahedron letters (30-06-2003)“…A new environment friendly procedure for effective aromatic iodination is presented. A mixture of potassium iodide and potassium iodate is used in the presence…”
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11
Simple and practical halogenation of arenes, alkenes and alkynes with hydrohalic acid/H2O2 (or TBHP)
Published in Tetrahedron (03-09-1999)Get full text
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12
Simple and efficient chlorination and bromination of aromatic compounds with aqueous TBHP (or H 2O 2) and a hydrohalic acid
Published in Tetrahedron letters (27-08-1998)“…A combination of aqueous tert-butylhydroperoxide (70%) or hydrogen peroxide (34%) and a hydrohalic acid was found effective in chlorination and bromination of…”
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13
Preparation and evaluation of nitrene precursors (PhI=NSO 2Ar) for the copper-catalyzed aziridination of olefins
Published in Tetrahedron letters (29-09-1997)“…The preparation of different [ N-(arenesulfonyl)imino]phenyliodinones is described, along with an evaluation of their utility as nitrene precursors for the…”
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14
A new class of bis-oxazoline ligands for the Cu-catalysed asymmetric cyclopropanation of olefins
Published in Tetrahedron letters (03-06-1996)“…A set of new chiral bis-oxazolines, 5a-b and 6a-c, has been syntheised from D and L-diethyl 2,3- O-isopropylidene tartrates and chiral amino alcohols. These…”
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15
A novel application of Hβ-zeolite in catalytic dehalogenation of halophenols
Published in Tetrahedron letters (18-08-2003)“…A new application of Hβ-zeolite for debromination of bromophenols and deiodination of iodophenols is presented in this note. The heterogeneous catalyst can be…”
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16
Investigation of the Effects of the Structure and Chelate Size of Bis-oxazoline Ligands in the Asymmetric Copper-Catalyzed Cyclopropanation of Olefins: Design of a New Class of Ligands
Published in Journal of organic chemistry (18-04-1997)“…A set of novel, C 2-symmetric bis-oxazoline ligands has been synthesized by mounting two oxazoline rings onto an optically active 1,3-dioxolane backbone. This…”
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17
Bromamine-T: A superior source of nitrene for aziridination of olefins
Published in Tetrahedron letters (25-06-1998)“…Bromamine-T as a superior source of nitrene compared to Chloramine-T in the Cu-catalyzed aziridination of olefins is reported in this communication…”
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18
Synthesis of novel 1-aryl-substituted 8-methoxynaphthalenes and their tendency for atropisomerization
Published in Tetrahedron (01-03-2004)“…Novel 1-aryl-substituted 8-methoxynaphthalenes were conveniently prepared by using Suzuki–Miyaura cross-coupling as a key reaction. Chemical transformations of…”
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Studies on Bromination of Active Methylene by a Mixture of Hydrobromic Acid and Hydrogen Peroxide (or TBHP)
Published in Synthetic communications (05-01-2003)“…Studies on bromination of active methylene with a mixture of hydrogen peroxide or tert-butylhydroperoxide (TBHP) and hydrobromic acid are discussed…”
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20
A mild procedure for the clay catalyzed selective removal of the tert-butoxycarbonyl protecting group from aromatic amines
Published in Tetrahedron letters (15-01-2000)“…The application of solid acidic catalysts for the selective removal of N-Boc protection is presented in this report. Montmorillonite K10 was found to be an…”
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