Search Results - "Bényei, Attila C"
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Asymmetric Hydrogenation of Ketones by Simple Alkane-Diyl-Based Ir(P,N,O) Catalysts: A Comparative Study
Published in Molecules (Basel, Switzerland) (07-08-2024)“…The development of new chiral ligands with simple and modular structure represents a challenging direction in the design of efficient homogeneous transition…”
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Novel Sulfonated N-Heterocyclic Carbene Gold(I) Complexes: Homogeneous Gold Catalysis for the Hydration of Terminal Alkynes in Aqueous Media
Published in Organometallics (14-06-2010)“…A series of novel water-soluble AuI complexes using sulfonated N-heterocyclic imidazolylidene carbenes as ligands was prepared by transmetalation from the…”
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3
Lower Denticity Leading to Higher Stability: Structural and Solution Studies of Ln(III)–OBETA Complexes
Published in Inorganic chemistry (01-12-2014)“…The heptadentate ligand OBETA (2,2′-oxybis(ethylamine)-N,N,N′,N′-tetraacetic acid) was reported to form complexes with Ln3+ ions more stable than those formed…”
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4
Ruthenium complexes of new chiral phosphine‐amine‐ether ligands (Ru‐PNO) for asymmetric hydrogenation – the role of backbone chirality in pincer ligand design
Published in Applied organometallic chemistry (01-03-2024)“…New chiral phosphine‐amine‐ether (PNO) ligands of the general formula Ph2PCH(R1)(CH2)nCH(R1)N(R2)CH(R3)CH2OMe, where R1, R2, and R3 = H or Me, n = 0 or 1, and…”
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5
Hydrogenation and Redox Isomerization of Allylic Alcohols Catalyzed by a New Water-Soluble Pd–tetrahydrosalen Complex
Published in Organometallics (12-08-2013)“…For applications in aqueous media, sulfonated tetrahydrosalen (sulfosalan, HSS) was synthesized by sulfonation of tetrahydrosalen in fuming sulfuric acid. The…”
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Modular Synthesis of Heterocyclic Carbene Precursors
Published in Journal of organic chemistry (04-08-2006)“…A series of N-heterocyclic carbene precursors, containing an imidazoline or tetrahydropyrimidine framework, were prepared from ω-chloroalkanoyl chlorides. The…”
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7
Quinoidal Tetrazines: Formation of a Fascinating Compound Class
Published in Organic letters (16-08-2007)“…A series of different N-heterocyclic carbenes (NHCs) were reacted with 3,6-bis(3‘,5‘-dimethylpyrazolyl)-tetrazine in the presence of an inorganic carbonate to…”
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8
Application of alkane-diyl based chiral phosphine-aminophosphine (P-NP) and thioether-aminophosphine (S-NP) ligands in Rh-catalyzed asymmetric hydrogenation
Published in Journal of organometallic chemistry (01-08-2023)“…•Novel highly modular phosphine-aminophosphine (P-NP) ligands have been synthesized.•[Rh(COD)(P-NP)]BF4 and [Rh(CO)2(P-NP)]BF4 type complexes were…”
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9
Chelate ring size effects of Ir(P,N,N) complexes: Chemoselectivity switch in the asymmetric hydrogenation of α,β-unsaturated ketones
Published in Catalysis communications (01-11-2020)“…A novel, highly modular approach has been developed for the synthesis of new chiral P,N,N ligands with the general formula…”
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10
Hydrogen bond-directed coordination of phosphine-amino-alcohol (P,N,OH) ligands: Stereochemical considerations and catalytic studies
Published in Inorganica Chimica Acta (01-12-2022)“…[Display omitted] •3 novel phosphine-amino-alcohol type chiral ligands have been synthesized.•[Pd(P,N,OH)Cl2] complexes have been prepared and…”
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11
Backbone effects in the synthesis, coordination chemistry and catalytic properties of new chiral heterobidentate ligands with P,N and S,N donor sets
Published in Journal of organometallic chemistry (15-08-2020)“…Novel alkane-diyl based heterobidentate P,N and S,N ligands with the general formula R1R2NCH(R3)(CH2)nCH(R4)Q (R1 = Me or iPr; R2 = H or Me; R3, R4 = H or Me;…”
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12
Characterization of the ionic liquid obtained by chlorosulfonation of 1-methylimidazole: 1-methyl-3-sulfonic acid imidazolium chloride, 1-methylimidazolium chlorosulfate or a zwitterionic salt?
Published in Journal of molecular liquids (15-03-2021)“…A great number of organic reactions catalyzed by the ionic liquid product of chlorosulfonation of 1-methylimidazole have been reported recently. At the same…”
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13
Pd-Tetrahydrosalan-Type Complexes as Catalysts for Sonogashira Couplings in Water: Efficient Greening of the Procedure
Published in ChemSusChem (01-08-2014)“…New sulfonated tetrahydrosalen‐type ligands and their water‐soluble palladium(II) complexes have been synthesized. The palladium(II) complexes catalyze the…”
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14
Molecular and crystal structure of bis( N-cyclohexyl-2-pyrrolidone)dioxouranium(VI) nitrate
Published in Inorganica Chimica Acta (01-01-2003)“…Bis( N-cyclohexyl-2-pyrrolidone)dioxouranium(VI) nitrate, UO 2(NO 3) 2(NCP) 2, has been prepared by mixing UO 2(NO 3) 2·6H 2O and N-cyclohexyl-2-pyrrolidone…”
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15
Novel Pd(PN,S)-complexes: Highly active catalysts designed for asymmetric allylic etherification
Published in Molecular catalysis (01-08-2021)“…•A highly modular approach has been developed for the synthesis of chiral PN,S-ligands.•The ligands were used in Pd-catalyzed asymmetric allylic…”
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16
Formation and Solid State Structures of Highly Crystalline Guanidinium Salts of Sulfonated Tertiary Phosphanes
Published in Advanced synthesis & catalysis (01-06-2002)“…Formation of highly crystalline guanidinium salts of sulfonated triphenylphosphane derivatives is demonstrated as a general method for obtaining samples…”
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17
Versatility of Coordination Modes in Complexes of Monohydroxamic Acids with Half‐Sandwich Type Ruthenium, Rhodium, Osmium and Iridium Cations
Published in ChemistrySelect (Weinheim) (11-09-2017)“…Complexation of the secondary N‐methyl‐acetohydroxamic acid (HMeaha) with [(η6‐p‐cym)Ru(H2O)3]2+, [(η5‐Cp*)Rh(H2O)3]2+, [(η6‐p‐cym)Os(H2O)3]2+ or…”
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18
Modular Synthesis of Chiral NHC Precursors and Their Silver and Gold Complexes
Published in Organometallics (12-10-2020)“…The stereoselective synthesis of chiral heterocyclic carbene precursors and the structural features of their silver and gold complexes were investigated. The…”
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19
Catalytic properties of water-soluble rhodium and iridium complexes: the influence of the ligand structure
Published in Inorganica Chimica Acta (20-07-2004)“…Rhodium and iridium complexes of trisulfonated triarylphosphanes, TPPTS (tris(3-sulfonatophenyl)phosphane), T( p-A)PTS…”
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20
Metal−Metal Bond or Isolated Metal Centers? Interaction of Hg(CN)2 with Square Planar Transition Metal Cyanides
Published in Inorganic chemistry (26-12-2005)“…Three adducts have been prepared from Hg(CN)2 and square planar MII(CN)4 2- transition metal cyanides (M = Pt, Pd, or Ni, with d8 electron shell) as solids…”
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