Search Results - "Batsanov, Andrei S."
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1
Carbazole isomers induce ultralong organic phosphorescence
Published in Nature materials (01-02-2021)“…Commercial carbazole has been widely used to synthesize organic functional materials that have led to recent breakthroughs in ultralong organic phosphorescence…”
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2
Intramolecular Charge Transfer Controls Switching Between Room Temperature Phosphorescence and Thermally Activated Delayed Fluorescence
Published in Angewandte Chemie International Edition (10-12-2018)“…Chemical modification of phenothiazine‐benzophenone derivatives tunes the emission behavior from triplet states by selecting the geometry of the intramolecular…”
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3
Regio- and conformational isomerization critical to design of efficient thermally-activated delayed fluorescence emitters
Published in Nature communications (13-04-2017)“…Regio- and conformational isomerization are fundamental in chemistry, with profound effects upon physical properties, however their role in excited state…”
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4
Bond Rotations and Heteroatom Effects in Donor–Acceptor–Donor Molecules: Implications for Thermally Activated Delayed Fluorescence and Room Temperature Phosphorescence
Published in Journal of organic chemistry (07-12-2018)“…The synthesis of 1-methylphenoxazine via CO2-directed lithiation chemistry is reported. This electron donor was coupled with…”
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5
Persistent Dimer Emission in Thermally Activated Delayed Fluorescence Materials
Published in Journal of physical chemistry. C (02-05-2019)“…We expose significant changes in the emission color of carbazole-based thermally activated delayed fluorescence (TADF) emitters that arise from the presence of…”
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6
The Role of Local Triplet Excited States and D‐A Relative Orientation in Thermally Activated Delayed Fluorescence: Photophysics and Devices
Published in Advanced science (01-12-2016)“…Here, a comprehensive photophysical investigation of a the emitter molecule DPTZ‐DBTO2, showing thermally activated delayed fluorescence (TADF), with…”
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7
Importance of Chromophore Rigidity on the Efficiency of Blue Thermally Activated Delayed Fluorescence Emitters
Published in Journal of physical chemistry. C (20-12-2018)“…Four new symmetrical donor–acceptor–donor (D–A–D)-type molecules are reported with diphenylamine (DPA) or 10,11-dihydro-5H-dibenz[b,f]azepine (Az) as…”
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Triazatruxene: A Rigid Central Donor Unit for a D–A3 Thermally Activated Delayed Fluorescence Material Exhibiting Sub‐Microsecond Reverse Intersystem Crossing and Unity Quantum Yield via Multiple Singlet–Triplet State Pairs
Published in Advanced science (01-06-2018)“…By inverting the common structural motif of thermally activated delayed fluorescence materials to a rigid donor core and multiple peripheral acceptors, reverse…”
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9
Oxidation State Tuning of Room Temperature Phosphorescence and Delayed Fluorescence in Phenothiazine and Phenothiazine‐5,5‐dioxide Dimers
Published in Chemistry : a European journal (26-05-2023)“…Heterocyclic dimers consisting of combinations of butterfly‐shaped phenothiazine (PTZ) and its chemically oxidized form phenothiazine‐5,5‐dioxide (PTZ(SO2))…”
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10
Synthesis of 2- and 2,7-Functionalized Pyrene Derivatives: An Application of Selective CH Borylation
Published in Chemistry : a European journal (16-04-2012)“…An efficient synthetic route to 2‐ and 2,7‐substituted pyrenes is described. The regiospecific direct CH borylation of pyrene with an iridium‐based catalyst,…”
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11
Direct Amidation of Amino Acid Derivatives Catalyzed by Arylboronic Acids: Applications in Dipeptide Synthesis
Published in European journal of organic chemistry (01-09-2013)“…The direct amidation of amino acid derivatives catalyzed by arylboronic acids has been examined. The reaction was generally slow relative to simple…”
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12
Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State
Published in Journal of organic chemistry (06-01-2012)“…The Lewis base adduct of B2pin2 and the NHC (1,3-bis(cyclohexyl)imidazol-2-ylidene), which was proposed to act as a source of nucleophilic boryl groups in the…”
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13
Copper-Mediated Nitrosation: 2-Nitrosophenolato Complexes and Their Use in the Synthesis of Heterocycles
Published in Molecules (Basel, Switzerland) (16-11-2019)“…A simple protocol yielding -substituted nitrosophenols from phenols is demonstrated, in the form of copper(II) (nitrosophenolato) complexes. The developed…”
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14
Thermally Induced Defluorination during a mer to fac Transformation of a Blue-Green Phosphorescent Cyclometalated Iridium(III) Complex
Published in Inorganic chemistry (02-01-2012)“…The new homoleptic tris-cyclometalated [Ir(C∧N)3] complexes mer-8, fac-8, and fac-9 incorporating γ-carboline ligands are reported. Reaction of…”
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15
Ferroelasticity in a metal–organic framework perovskite; towards a new class of multiferroics
Published in Acta materialia (01-08-2013)“…A metal–organic framework perovskite, [(CH2)3NH2][Mn(HCOO)3], exhibits a weakly first order ferroelastic phase transition at ∼272K, from orthorhombic Pnma to…”
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16
Precision control of single-molecule electrical junctions
Published in Nature materials (01-12-2006)“…There is much discussion of molecules as components for future electronic devices. However, the contacts, the local environment and the temperature can all…”
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17
Iridium-Catalyzed CH Activation versus Directed ortho Metalation: Complementary Borylation of Aromatics and Heteroaromatics
Published in Chemistry : a European journal (19-07-2010)“…Systematic studies are presented demonstrating the complementarity of directed ortho metalation (DoM) and Ir‐catalyzed strategies for the provision of…”
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18
Transparent Colloids of Detonation Nanodiamond: Physical, Chemical and Biological Properties
Published in Materials (01-09-2023)“…Aqueous suspensions (colloids) containing detonation nano-diamond (DND) feature in most applications of DND and are an indispensable stage of its production;…”
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19
Fully Borylated Methane and Ethane by Ruthenium-Mediated Cleavage and Coupling of CO
Published in Angewandte Chemie International Edition (04-04-2016)“…Many transition‐metal complexes and some metal‐free compounds are able to bind carbon monoxide, a molecule which has the strongest chemical bond in nature…”
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20
Structural versus Electrical Functionalization of Oligo(phenylene ethynylene) Diamine Molecular Junctions
Published in Journal of physical chemistry. C (18-09-2014)“…We explore both experimentally and theoretically the conductance and packing of molecular junctions based on oligo(phenyleneethynylene) (OPE) diamine wires,…”
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