Search Results - "Barwe, Stefan"
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Online Monitoring of Electrochemical Carbon Corrosion in Alkaline Electrolytes by Differential Electrochemical Mass Spectrometry
Published in Angewandte Chemie International Edition (20-01-2020)“…Carbon corrosion at high anodic potentials is a major source of instability, especially in acidic electrolytes and impairs the long‐term functionality of…”
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Powder Catalyst Fixation for Post‐Electrolysis Structural Characterization of NiFe Layered Double Hydroxide Based Oxygen Evolution Reaction Electrocatalysts
Published in Angewandte Chemie International Edition (04-09-2017)“…Highly active electrocatalysts for the oxygen evolution (OER) reaction are in most cases powder nanomaterials, which undergo substantial changes upon applying…”
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Cobalt-metalloid alloys for electrochemical oxidation of 5-hydroxymethylfurfural as an alternative anode reaction in lieu of oxygen evolution during water splitting
Published in Beilstein journal of organic chemistry (13-06-2018)“…The electrochemical water splitting commonly involves the cathodic hydrogen and anodic oxygen evolution reactions (OER). The oxygen evolution reaction is more…”
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Overcoming the Instability of Nanoparticle‐Based Catalyst Films in Alkaline Electrolyzers by using Self‐Assembling and Self‐Healing Films
Published in Angewandte Chemie International Edition (10-07-2017)“…Engineering stable electrodes using highly active catalyst nanopowders for electrochemical water splitting remains a challenge. We report an innovative and…”
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Bipolar Electrochemistry for Concurrently Evaluating the Stability of Anode and Cathode Electrocatalysts and the Overall Cell Performance during Long-Term Water Electrolysis
Published in Analytical chemistry (Washington) (06-09-2016)“…Electrochemical efficiency and stability are among the most important characteristics of electrocatalysts. These parameters are usually evaluated separately…”
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Doping Level of Boron-Doped Diamond Electrodes Controls the Grafting Density of Functional Groups for DNA Assays
Published in ACS applied materials & interfaces (02-09-2015)“…The impact of different doping levels of boron-doped diamond on the surface functionalization was investigated by means of electrochemical reduction of…”
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Low Overpotential Water Splitting Using Cobalt–Cobalt Phosphide Nanoparticles Supported on Nickel Foam
Published in ACS energy letters (09-12-2016)“…We report a simple, facile, and safe route for preparation of cobalt–cobalt phosphide (Co/Co2P) nanoparticles and demonstrate their application as efficient…”
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Recovering activity of anodically challenged oxygen reduction electrocatalysts by means of reductive potential pulses
Published in Electrochemistry communications (01-03-2021)“…[Display omitted] •Potential pulses prior to the ORR reactivate catalytic sites which were oxidized at high anodic potentials.•Optimisation of the pulse…”
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Enhancing the Selectivity between Oxygen and Chlorine towards Chlorine during the Anodic Chlorine Evolution Reaction on a Dimensionally Stable Anode
Published in ChemElectroChem (14-06-2019)“…The selectivity of the chlorine evolution reaction over the oxygen evolution reaction during the electrolysis of aqueous NaCl is, despite being very high,…”
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Electrocatalytic Oxidation of 5‐(Hydroxymethyl)furfural Using High‐Surface‐Area Nickel Boride
Published in Angewandte Chemie International Edition (27-08-2018)“…The electrochemical oxidation of the biorefinery product 5‐(hydroxymethyl)furfural (HMF) to 2,5‐furandicarboxylic acid (FDCA), an important platform chemical…”
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On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius
Published in Chemistry : a European journal (02-01-2019)“…Svante Augustus Arrhenius (1859, Vik ‐ 1927, Stockholm) received the Nobel Prize for Chemistry in 1903 “in recognition of the extraordinary services he…”
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Influence of Ni to Co ratio in mixed Co and Ni phosphides on their electrocatalytic oxygen evolution activity
Published in Electrochemistry communications (01-06-2017)“…Prompted by the impact of Ni-based support materials on the intrinsic activity of electrocatalysts, we investigated the influence of partial Co substitution by…”
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Influence of Temperature and Electrolyte Concentration on the Structure and Catalytic Oxygen Evolution Activity of Nickel–Iron Layered Double Hydroxide
Published in Chemistry : a European journal (18-09-2018)“…NiFe layered double hydroxide (LDH) is inarguably the most active contemporary catalyst for the oxygen evolution reaction under alkaline conditions. However,…”
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Optimizing the synthesis of Co/Co–Fe nanoparticles/N-doped carbon composite materials as bifunctional oxygen electrocatalysts
Published in Electrochimica acta (20-09-2019)“…A future widespread application of electrochemical energy conversion and storage technologies strongly depends on the substitution of precious metal-based…”
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Electrocatalytic Functionalized Specialty Paper as Low‐Cost Porous Transport Layer Material in CO2‐Electrolysis
Published in ChemCatChem (22-01-2024)“…The development of low‐cost and efficient electrolyzer components is crucial for practical electrochemical carbon dioxide reduction (ECR). In this study,…”
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Electrocatalytic Functionalized Specialty Paper as Low‐Cost Porous Transport Layer Material in CO 2 ‐Electrolysis
Published in ChemCatChem (22-01-2024)“…Abstract The development of low‐cost and efficient electrolyzer components is crucial for practical electrochemical carbon dioxide reduction (ECR). In this…”
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Overcoming cathode poisoning from electrolyte impurities in alkaline electrolysis by means of self-healing electrocatalyst films
Published in Nano energy (01-11-2018)“…The performance of electrolyzers for hydrogen production is strongly influenced by electrolyte impurities having either a positive or negative impact on the…”
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Enhancing Electrocatalytic Activity through Liquid‐Phase Exfoliation of NiFe Layered Double Hydroxide Intercalated with Metal Phthalocyanines in the Presence of Graphene
Published in Chemphyschem (19-11-2019)“…Earth‐abundant transition‐metal‐based catalysts are attractive for alkaline water electrolysis. However, their catalytic properties are often limited by their…”
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High resolution, binder-free investigation of the intrinsic activity of immobilized NiFe LDH nanoparticles on etched carbon nanoelectrodes
Published in Nano research (01-11-2018)“…The determination of the intrinsic properties of nanomaterials is essential for their optimization as electrocatalysts, however it poses great challenges from…”
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Cobalt metalloid and polybenzoxazine derived composites for bifunctional oxygen electrocatalysis
Published in Electrochimica acta (20-02-2019)“…The development of bifunctional oxygen electrodes is a key factor for the envisaged application of rechargeable metal-air batteries. In this work, we present a…”
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