Search Results - "Barrios, Am"
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Interaction of Urea with a Hydroxide-Bridged Dinuclear Nickel Center: An Alternative Model for the Mechanism of Urease
Published in Journal of the American Chemical Society (27-09-2000)“…A hydroxide-bridged dinuclear nickel complex with a urea molecule linking the two metal ions through its carbonyl oxygen atom has been prepared as a model for…”
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Inhibition of lysosomal cysteine proteases by chrysotherapeutic compounds: a possible mechanism for the antiarthritic activity of Au(I)
Published in Bioorganic & medicinal chemistry letters (18-10-2004)“…[Display omitted] Although Au(I) complexes have been used to treat rheumatoid arthritis for over 75years, their mechanism of action is still poorly understood…”
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Amide Hydrolysis Effected by a Hydroxo-Bridged Dinickel(II) Complex: Insights into the Mechanism of Urease
Published in Journal of the American Chemical Society (22-12-1999)“…A series of dinuclear nickel complexes, [Ni2(H2O)4(bdptz)](OTs)4, [Ni2(OH)(H2O)3(bdptz)](OTs)3, and [Ni2(H2O)(OH)2(bdptz)]2(OTs)4, where bdptz is the…”
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A low-cost, sustainable, second generation system for surveillance of people living with HIV in Spain: 10-year trends in behavioural and clinical indicators, 2002 to 2011
Published in Euro surveillance : bulletin européen sur les maladies transmissibles (22-05-2014)“…A second-generation surveillance system of people infected with human immunodeficiency virus (HIV) has been implemented in Spain. Behavioural and clinical data…”
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Decomposition of Alkyl-Substituted Urea Molecules at a Hydroxide-Bridged Dinickel Center
Published in Inorganic chemistry (12-03-2001)“…The interactions between N-methylurea, N,N‘-dimethylurea, N,N-dimethylurea, tetramethylurea, and thiourea and the hydroxide-bridged dinickel complex…”
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Highly sensitive peptide-based probes for protein tyrosine phosphatase activity utilizing a fluorogenic mimic of phosphotyrosine
Published in Bioorganic & medicinal chemistry letters (01-12-2005)“…The high-yielding synthesis of an enantiomerically pure phosphocoumarin-based amino acid and its incorporation into peptides are reported. Peptides containing…”
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Modeling the Diiron Centers of Non-Heme Iron Enzymes. Preparation of Sterically Hindered Diiron(II) Tetracarboxylate Complexes and Their Reactions with Dioxygen
Published in Journal of the American Chemical Society (09-09-1998)“…A series of diiron(II) complexes, [Fe2(μ-L)(μ-O2CR)(O2CR)(N)2], where L is a dinucleating bis(carboxylate) ligand based on m-xylylenediamine bis(Kemp's triacid…”
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Scanning the prime-Site substrate specificity of proteolytic enzymes: A novel assay based on ligand-Enhanced lanthanide ion fluorescence
Published in Bioorganic & medicinal chemistry letters (16-12-2002)“…A novel method for assaying the substrate specificity of proteolytic enzymes has been developed utilizing ligand-enhanced lanthanide ion fluorescence. This…”
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Phthalazine-Based Dinucleating Ligands Afford Dinuclear Centers Often Encountered in Metalloenzyme Active Sites
Published in Inorganic chemistry (26-02-2001)Get full text
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Diiron Complexes of 1,8-Naphthyridine-Based Dinucleating Ligands as Models for Hemerythrin
Published in Journal of the American Chemical Society (27-12-2000)“…The hydroxo-bridged diiron(II) compounds [Fe2(BPEAN)(μ-OH)(OTf)](OTf)2 (1) and [Fe2(BEPEAN)(μ-OH)](OTf)3 (2) were prepared by using 1,8-naphthyridine-based…”
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The Reactivity of well defined diiron(III) peroxo complexes toward substrates: addition to electrophiles and hydrocarbon oxidation
Published in Bioorganic & medicinal chemistry (01-05-1999)“…The reactivity of previously reported peroxo adducts [Fe(μ-O 2)(μ- L)(O 2CPhCy) 2(1-Bu-Im) 2] ( 1), and [Fe(μ-O 2)(μ- L)(O 2CPhCy) 2(py) 2] ( 2), where L is a…”
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Variación de la Presión Intraocular Durante la Hemodiálisis
Published in Revista del Nacional (Itauguá) (01-12-2009)“…RESUMEN La mayoría de los estudios posibilitan actualmente relacionar los cambios de la presión intraocular como un hecho más del síndrome de desequilibrio…”
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