γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) Vol. 48; no. 100; p. 12180
Main Authors: Smith, Sean M, Hoang, Gia L, Pal, Rhitankar, Bani Khaled, Mohammad O, Pelter, Liberty S W, Zeng, Xiao Cheng, Takacs, James M
Format: Journal Article
Language:English
Published: England 28-12-2012
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Description
Summary:Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).
ISSN:1364-548X
DOI:10.1039/c2cc36199j