Search Results - "Baldinelli, Lorenzo"
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Mechanism of Nitrous Oxide Activation in C(sp2)–O Bond Formation Reactions Catalyzed by Nickel Complexes
Published in Journal of the American Chemical Society (06-03-2024)“…Recent groundbreaking experimental reports demonstrated that Ni complexes bearing a bidentate- or tridentate-bipyridine-based ligand can be used to activate…”
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Unraveling Atomic Contributions to the London Dispersion Energy: Insights into Molecular Recognition and Reactivity
Published in Journal of chemical theory and computation (12-03-2024)“…We present a general framework that enables quantification with atomic resolution of the overall London dispersion energy, which can be readily integrated with…”
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Design of a new photochromic oscillator: towards dynamical models of pacemaker neurons
Published in Reaction kinetics, mechanisms and catalysis (01-06-2022)“…A brand-new photochemical oscillator is designed in this work. It consists of two thermally reversible photochromic compounds. One photochrome is inverse and…”
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Taming secondary benzylic cations in catalytic asymmetric SN1 reactions
Published in Science (American Association for the Advancement of Science) (20-10-2023)“…Editor’s summaryNucleophilic substitution reactions are widely used to form bonds to carbon. In many cases, the reactions occur with precisely predictable…”
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Taming secondary benzylic cations in catalytic asymmetric S N 1 reactions
Published in Science (American Association for the Advancement of Science) (20-10-2023)“…Benzylic stereogenic centers are ubiquitous in natural products and pharmaceuticals. A potentially general, though challenging, approach toward their selective…”
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In Situ Observation of Elusive Dirhodium Carbenes and Studies on the Innate Role of Carboxamidate Ligands in Dirhodium Paddlewheel Complexes: A Combined Experimental and Computational Approach
Published in Journal of the American Chemical Society (25-09-2024)“…Carboxamidates as equatorial ligands in dirhodium paddlewheel catalysts are widely believed to increase selectivity at the expense of reactivity. The results…”
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Harnessing the electronic structure of active metals to lower the overpotential of the electrocatalytic oxygen evolution reaction
Published in Chemical science (Cambridge) (24-01-2024)“…Despite substantial advancements in the field of the electrocatalytic oxygen evolution reaction (OER), the efficiency of earth-abundant electrocatalysts…”
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Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests
Published in Nature energy (2024)“…The stabilization of grain boundaries and surfaces of the perovskite layer is critical to extend the durability of perovskite solar cells. Here we introduced a…”
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