Search Results - "Balavoine, Gilbert G. A."

New Dihydroxy Bis(Oxazoline) Ligands for the Palladium-Catalyzed Asymmetric Allylic Alkylation: Experimental Investigations of the Origin of the Reversal of the Enantioselectivity by Aït-Haddou, Hassan, Hoarau, Olivier, Cramailére, Dimitri, Pezet, Frédéric, Daran, Jean-Claude, Balavoine, Gilbert G. A.

“…The origin of the reversal of the enantioselectivity in the palladium‐catalyzed allylic alkylation of rac‐1,3‐diphenyl‐2‐propenyl acetate with dimethyl…”
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Synthesis, Crystal Structures, and Second-Order Nonlinear Optical Properties of New Chiral Ferrocenyl Materials by Balavoine, Gilbert G. A, Daran, Jean-Claude, Iftime, Gabriel, Lacroix, Pascal G, Manoury, Eric, Delaire, Jacques A, Maltey-Fanton, Isabelle, Nakatani, Keitaro, Di Bella, Santo

“…A series of chiral enantiomerically pure analogues of (E)-(2-(4-nitrophenyl)ethenyl)ferrocene (2), substituted by R (3, R = Me; 4, R = CH2OH; 5, R = SiMe3), in…”
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Highly Diastereoselective Preparation of Ruthenium Bis(diimine) Sulfoxide Complexes:  New Concept in the Preparation of Optically Active Octahedral Ruthenium Complexes by Pezet, Frédéric, Daran, Jean-Claude, Sasaki, Isabelle, Aït-Haddou, Hassan, Balavoine, Gilbert G. A

“…Microwave irradiation of racemic cis-[Ru(bpy)2(Cl)2] (bpy = 2,2‘-bipyridine) or racemic cis-[Ru(phen)2(Cl)2] (phen = phenanthroline) with either (R)-(+)- or…”
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Highly Enantioselective One-Pot Synthesis of Chiral Tri- and Tetrasubstituted Ferrocenes from 1,1′-Ferrocenedicarbaldehyde by Iftime, Gabriel, Daran, Jean-Claude, Manoury, Eric, Balavoine, Gilbert G. A.

“…Exclusively planar chirality is exhibited by the ferrocenes obtained in a highly enantioselective synthesis in which a chiral aminoamide acts as a temporary…”
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Chiral 1,2,1‘-Trisubstituted Ferrocenes:  Access to Chiral Oxaferrocenophanes by Iftime, Gabriel, Daran, Jean-Claude, Manoury, Eric, Balavoine, Gilbert G. A

“…Combining the Kagan method for synthesis of chiral 2-substituted ferrocenecarbaldehydes with our recent method for synthesis of 1‘-substituted…”
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Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands by Brookhart, M, Wagner, Mark I, Balavoine, Gilbert G. A, Haddou, Hassan Ait

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The Combination of Spontaneous Resolution and Asymmetric Catalysis: A Model for the Generation of Optical Activity from a Fully Racemic System by Tissot, Olivier, Gouygou, Maryse, Dallemer, Frédéric, Daran, Jean-Claude, Balavoine, Gilbert G. A.

“…Enantiomerically pure BIPHOS was obtained by spontaneous resolution through the crystallization of a racemic mixture, without the use of chemical or physical…”
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Asymmetric Palladium-Catalyzed Allylic Alkylation Using Bis(Oxazoline) Ligands:  Phenomenal Reversal of Enantioselectivity with a Single Chiral Backbone by Hoarau, Olivier, Aït-Haddou, Hassan, Daran, Jean-Claude, Cramailère, Dimitri, Balavoine, Gilbert G. A

“…Chiral bis(oxazoline) ligands with four stereogenic centers were tested in the asymmetric palladium-catalyzed allylic alkylation of the…”
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New Ferrocenyloxazoline for the Preparation of Ferrocenes with Planar Chirality by Manoury, Eric, Fossey, John S, Aït-Haddou, Hassan, Daran, Jean-Claude, Balavoine, Gilbert G. A

“…New ferrocenyloxazolines with two stereogenic centers were prepared with excellent yields starting from the (1S,2S)-(+)-2-amino-3-phenyl-1,3-propanediol. They…”
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Selective Functionalization of Chiral Ferrocenyl Acetals. Easy Access to Various Tri- and Tetrasubstituted Ferrocenes with Controlled Geometry by Chiffre, Jérôme, Coppel, Yannick, Balavoine, Gilbert G. A, Daran, Jean-Claude, Manoury, Eric

“…The lithiation of 2-substituted chiral dioxane 2, followed by electrophilic trapping of the lithiated intermediate, yields various 1,5-disubstitued acetals…”
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A Novel and Perfectly Aligned Crystal of a Ferrocenyl Chromophore Displaying High Quadratic Nonlinear Optical Bulk Efficiency by Chiffre, Jérome, Averseng, Frédéric, Balavoine, Gilbert G. A., Daran, Jean-Claude, Iftime, Gabriel, Lacroix, Pascal G., Manoury, Eric, Nakatani, Keitaro

“…The highest nonlinear optical bulk efficiency for a 2‐(4‐nitrophenyl)ethenylferrocene (140 times that of urea) has been achieved for E‐4 owing to a favourable…”
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Biphosphole:  A C 2 Symmetry Chiral Bidentate Ligand. Synthesis and Characterization Of Nickel, Palladium, Platinum, and Rhodium Complexes by Gouygou, Maryse, Tissot, Olivier, Daran, Jean-Claude, Balavoine, Gilbert G. A

“…Owing to the C 2 symmetry structure of 1,1‘-diphenyl-3,3‘,4,4‘-tetramethyl-2,2‘-biphosphole, 1 (BIPHOS), we investigated the coordination of this chiral…”
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New Bis-biphosphole−Transition-Metal Complexes:  Spontaneous Isomerization of trans- m eso- into cis-(±)-[Ru(trifluoroacetate)2(1,1‘-diphenyl-3,3‘,4,4‘- tetramethyl-2,2‘-biphosphole)2] by Tissot, Olivier, Gouygou, Maryse, Daran, Jean-Claude, Balavoine, Gilbert G. A

“…The reaction of [Ru2(O2CCF3)2(μ-O2CCF3)2(COD)2(μ-H2O)] with 1,1‘-diphenyl-3,3‘,4,4‘-tetramethyl-2,2‘-biphosphole (1) provides…”
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The Combination of Spontaneous Resolution and Asymmetric Catalysis: A Model for the Generation of Optical Activity from a Fully Racemic System We thank the Centre National de la Recherche Scientifique and Rhodia for financial support, Prof. H. B. Kagan for helpful discussions, and H. Aït-Haddou and O. Hoarau for assistance in catalytic tests by Tissot, Olivier, Gouygou, Maryse, Dallemer, Frédéric, Daran, Jean-Claude, Balavoine, Gilbert G. A.

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Preparation of electron-rich cationic ruthenium complexes of the type [(.eta.5-C5Me5)Ru(bipyridine)L] by Balavoine, Gilbert G. A, Boyer, Thierry, Livage, Carine

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The Combination of Spontaneous Resolution and Asymmetric Catalysis: A Model for the Generation of Optical Activity from a Fully Racemic System by Tissot, Olivier, Gouygou, Maryse, Dallemer, Frédéric, Daran, Jean-Claude, Balavoine, Gilbert G. A.

“…Enantiomerenreines BIPHOS wurde durch spontane Enantiomerentrennung bei der Kristallisation einer racemischen Mischung erhalten – ohne ein chemisches oder…”
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New Rhodium(I) and Iridium(I) Complexes of the Chiral 1,1′-Diphenyl-3,3′,4,4′-tetramethyl-2,2′-biphosphole Ligand − Synthesis and Applications to Catalytic Hydrogenation and Hydroformylation Reactions by Tissot, Olivier, Gouygou, Maryse, Dallemer, Frédéric, Daran, Jean-Claude, Balavoine, Gilbert G. A.

“…A convenient method for the synthesis of new racemic RhI and IrI complexes [M(BIPHOS)(COD)]BF4 have been developed from the BIPHOS ligand and [M(COD)Cl]2…”
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A Convenient Procedure for the Preparation of 1-(Diisopropylamino)phospholes − Application to the Synthesis of New 2,2′-Biphosphole Disulfides by Hydrio, Jérôme, Gouygou, Maryse, Dallemer, Frédéric, Balavoine, Gilbert G. A., Daran, Jean-Claude

“…A convenient one‐pot procedure for the preparation of 1‐(diisopropylamino)phospholes has been developed. These phospholes have been used in a multistep…”
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Enaminones in the Synthesis of New Polyaza Heterocycles by Bejan, Elena, Aït-Haddou, Hassan, Daran, Jean-Claude, Balavoine, Gilbert G. A.

“…A simple and efficient method for the synthesis of larger polyaza heterocyclic structures 6a, 6b and 8 with 1,3‐pyrimidine units has been developed, based on…”
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Evaluation of antioxidant activity using peroxynitrite as a source of radicals by Geletii, Yurii V, Balavoine, Gilbert G A

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