Search Results - "Bakulin, A."
-
1
Direct observation of ultrafast exciton localization in an organic semiconductor with soft X-ray transient absorption spectroscopy
Published in Nature communications (14-06-2022)“…The localization dynamics of excitons in organic semiconductors influence the efficiency of charge transfer and separation in these materials. Here we apply…”
Get full text
Journal Article -
2
Fine‐Tuning the Energy Levels of a Nonfullerene Small‐Molecule Acceptor to Achieve a High Short‐Circuit Current and a Power Conversion Efficiency over 12% in Organic Solar Cells
Published in Advanced materials (Weinheim) (01-01-2018)“…Organic solar cell optimization requires careful balancing of current–voltage output of the materials system. Here, such optimization using ultrafast…”
Get full text
Journal Article -
3
In situ observation of picosecond polaron self-localisation in α-Fe2O3 photoelectrochemical cells
Published in Nature communications (03-09-2019)“…Hematite (α-Fe 2 O 3 ) is the most studied artificial oxygen-evolving photo-anode and yet its efficiency limitations and their origin remain unknown. A…”
Get full text
Journal Article -
4
Real-time observation of multiexcitonic states in ultrafast singlet fission using coherent 2D electronic spectroscopy
Published in Nature chemistry (01-01-2016)“…Singlet fission is the spin-allowed conversion of a spin-singlet exciton into a pair of spin-triplet excitons residing on neighbouring molecules. To…”
Get full text
Journal Article -
5
Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes
Published in Journal of the American Chemical Society (27-11-2019)“…Oxygen vacancies are ubiquitous in metal oxides and critical to performance, yet the impact of these states upon charge carrier dynamics important for…”
Get full text
Journal Article -
6
What Controls the Rate of Ultrafast Charge Transfer and Charge Separation Efficiency in Organic Photovoltaic Blends
Published in Journal of the American Chemical Society (14-09-2016)“…In solar energy harvesting devices based on molecular semiconductors, such as organic photovoltaics (OPVs) and artificial photosynthetic systems, Frenkel…”
Get full text
Journal Article -
7
Water Infiltration in Methylammonium Lead Iodide Perovskite: Fast and Inconspicuous
Published in Chemistry of materials (24-11-2015)“…While the susceptibility of CH3NH3PbI3 to water is well-documented, the influence of water on device performance is not well-understood. Herein, we use…”
Get full text
Journal Article -
8
The Role of Driving Energy and Delocalized States for Charge Separation in Organic Semiconductors
Published in Science (American Association for the Advancement of Science) (16-03-2012)“…The electron-hole pair created via photon absorption in organic photoconversion systems must overcome the Coulomb attraction to achieve long-range charge…”
Get full text
Journal Article -
9
Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites
Published in The journal of physical chemistry letters (17-09-2015)“…The introduction of a mobile and polarized organic moiety as a cation in 3D lead-iodide perovskites brings fascinating optoelectronic properties to these…”
Get full text
Journal Article -
10
Unequal Partnership: Asymmetric Roles of Polymeric Donor and Fullerene Acceptor in Generating Free Charge
Published in Journal of the American Chemical Society (19-02-2014)“…Natural photosynthetic complexes accomplish the rapid conversion of photoexcitations into spatially separated electrons and holes through precise hierarchical…”
Get full text
Journal Article -
11
Study of the Diffusion Properties of Oxygen in TiO2
Published in Journal of experimental and theoretical physics (01-08-2021)“…The formation energies of oxygen vacancies and the migration barriers of oxygen in TiO 2 with a rutile structure have been calculated by the projector…”
Get full text
Journal Article -
12
Electronic Structure and Mechanical Properties of Ti5Si3
Published in Journal of experimental and theoretical physics (01-06-2022)“…The atomic and electronic structures, the elastic moduli, the vibrational frequencies, and the thermodynamic characteristics of the Ti 5 Si 3 titanium silicide…”
Get full text
Journal Article -
13
Organic Cation Rotation and Immobilization in Pure and Mixed Methylammonium Lead-Halide Perovskites
Published in Journal of the American Chemical Society (22-03-2017)“…Three-dimensional lead-halide perovskites have attracted a lot of attention due to their ability to combine solution processing with outstanding optoelectronic…”
Get full text
Journal Article -
14
First-Principle Investigation of the (001) Surface Reconstructions of GaSb and InSb Semiconductors
Published in Semiconductors (Woodbury, N.Y.) (01-07-2020)“…The atomic and electronic structures of reconstructions with the symmetry (2 × 4), (4 × 2), c (4 × 4), and (4 × 3) on the (001) surface of GaSb and InSb…”
Get full text
Journal Article -
15
On the Energetic Dependence of Charge Separation in Low-Band-Gap Polymer/Fullerene Blends
Published in Journal of the American Chemical Society (07-11-2012)“…The energetic driving force required to drive charge separation across donor/acceptor heterojunctions is a key consideration for organic optoelectronic…”
Get full text
Journal Article -
16
Exciton and Charge Carrier Dynamics in Highly Crystalline PTQ10:IDIC Organic Solar Cells
Published in Advanced energy materials (01-10-2020)“…Herein the morphology and exciton/charge carrier dynamics in bulk heterojunctions (BHJs) of the donor polymer PTQ10 and molecular acceptor IDIC are…”
Get full text
Journal Article -
17
Charge Separation, Band-Bending, and Recombination in WO3 Photoanodes
Published in The journal of physical chemistry letters (19-09-2019)“…In metal oxide-based photoelectrochemical devices, the spatial separation of photogenerated electrons and holes is typically attributed to band-bending at the…”
Get full text
Journal Article -
18
Field-Assisted Exciton Dissociation in Highly Efficient PffBT4T-2OD:Fullerene Organic Solar Cells
Published in Chemistry of materials (24-04-2018)“…Understanding the photophysics of charge generation in organic semiconductors is a critical step toward the further optimization of organic solar cells. The…”
Get full text
Journal Article -
19
Hot Carrier Dynamics in Perovskite Nanocrystal Solids: Role of the Cold Carriers, Nanoconfinement, and the Surface
Published in Nano letters (08-04-2020)“…Carrier cooling is of widespread interest in the field of semiconductor science. It is linked to carrier–carrier and carrier–phonon coupling and has profound…”
Get full text
Journal Article -
20
Orientation dependent molecular electrostatics drives efficient charge generation in homojunction organic solar cells
Published in Nature communications (15-09-2020)“…Organic solar cells usually utilise a heterojunction between electron-donating (D) and electron-accepting (A) materials to split excitons into charges…”
Get full text
Journal Article