Search Results - "Babu, Varghese"
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A Series of Oxyimine-Based Macrocyclic Dinuclear Zinc(II) Complexes Enhances Phosphate Ester Hydrolysis, DNA Binding, DNA Hydrolysis, and Lactate Dehydrogenase Inhibition and Induces Apoptosis
Published in Inorganic chemistry (21-05-2012)“…A symmetrical macrocyclic dizinc(II) complex (1) has been synthesized by using the ligand (L 1 )…”
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Camouflaging Structural Diversity: Co‐crystallization of Two Different Nanoparticles Having Different Cores But the Same Shell
Published in Angewandte Chemie International Edition (02-01-2019)“…Two ligand‐protected nanoscale silver moieties, [Ag46(SPhMe2)24(PPh3)8](NO3)2 and [Ag40(SPhMe2)24(PPh3)8](NO3)2 (abbreviated as Ag46 and Ag40, respectively)…”
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A Dicationic Bismuth(III) Lewis Acid: Catalytic Hydrosilylation of Olefins
Published in European journal of inorganic chemistry (31-07-2019)“…Lewis acid promoted activation of inert chemical bonds is central to catalysis. The presence of a highly electrophilic central atom having minimum interactions…”
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From Metallaborane to Borylene Complexes: Syntheses and Structures of Triply Bridged Ruthenium and Tantalum Borylene Complexes
Published in Chemistry : a European journal (04-10-2010)“…Reaction of [1,2‐(Cp*RuH)2B3H7] (1; Cp*=η5‐C5Me5) with [Mo(CO)3(CH3CN)3] yielded arachno‐[(Cp*RuCO)2B2H6] (2), which exhibits a butterfly structure,…”
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Improved Merkle Hash Tree-Based One-Time Signature Scheme for Capability-Enhanced Security Enforcing Architecture for Named Data Networking
Published in Wireless personal communications (01-11-2020)“…The concept of network caching is determined to be the potential requirement of named data networks (NDN) for enhancing the capabilities of the traditional IP…”
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Dynamic forest of random subsets-based one-time signature-based capability enhancing security architecture for named data networking
Published in International journal of information technology (Singapore. Online) (2023)“…Network caching in named data networks (NDN) is essential for improving the potentialities of the conventional IP networking. The concept of network caching is…”
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Cluster Expansion Reactions of Group 6 and 8 Metallaboranes Using Transition Metal Carbonyl Compounds of Groups 7–9
Published in Inorganic chemistry (20-06-2011)“…The reinvestigation of an early synthesis of heterometallic cubane-type clusters has led to the isolation of a number of new clusters which have been…”
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Synthesis of electron-deficient fluorinated porphyrins through scrambling: Characterization and quantitative crystal structure analysis
Published in Journal of fluorine chemistry (01-02-2015)“…A-DPM with B-CHO and its complimentary reaction in BF3·OEt2 results scrambling while TFA leads to non-scrambling condition, yields trans-A2B2 porphyrin. •We…”
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Sensitive Skin: Assessment of the Skin Barrier Using Confocal Raman Microspectroscopy
Published in Skin pharmacology and physiology (2017)“…Sensitive skin (SS), a frequently reported condition in the Western world, has been suggested to be underlined by an impaired skin barrier. The aim of this…”
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Minimally invasive non-thermal laser technology using laser-induced optical breakdown for skin rejuvenation
Published in Journal of biophotonics (01-02-2012)“…We describe a novel, minimally invasive laser technology for skin rejuvenation by creating isolated microscopic lesions within tissue below the epidermis using…”
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Influence of absorption induced thermal initiation pathway on irradiance threshold for laser induced breakdown
Published in Biomedical optics express (01-04-2015)“…We investigated the influence of thermal initiation pathway on the irradiance threshold for laser induced breakdown in transparent, absorbing and scattering…”
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12
A Lewis Acid Mediated Schmidt Reaction of Benzylic Azide: Synthesis of Sterically Crowded Aromatic Tertiary Amines
Published in European Journal of Organic Chemistry (01-09-2011)“…An efficient one‐pot synthesis of sterically hindered aromatic tertiary amines through Lewis acid induced intermolecular Schmidt reaction of benzylic azides is…”
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Self-Assembly of Manganese(I)-Based Molecular Squares: Synthesis and Spectroscopic and Structural Characterization
Published in Organometallics (12-03-2012)“…Syntheses of manganese(I)-based molecular squares have been accomplished in facile one-pot reaction conditions at room temperature. Self-assembly of eight…”
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Fractional laser photothermolysis using Bessel beams
Published in Biomedical optics express (01-12-2016)“…Fractional photothermolysis uses lasers to generate a pattern of microscopic columnar thermal lesions within the skin stimulating collagen remodeling. In this…”
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Synthesis, Characterization, and Electronic Structure of New Type of Heterometallic Boride Clusters
Published in Inorganic chemistry (03-10-2011)“…The reaction of [Cp*TaCl4], 1 (Cp* = η5-C5Me5), with [LiBH4·THF] at −78 °C, followed by thermolysis in the presence of excess [BH3·THF], results in the…”
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Synthesis and X-ray crystallographic investigation of N-(α-d-arabinopyranosyl)alkanamides as N-glycoprotein linkage region analogs
Published in Carbohydrate research (18-10-2013)“…•Effect of pentopyranosyl structures on the N-glycosidic torsions is studied.•Greater rotational freedom around the C1–N1 bond is seen in the arabinosyl…”
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Conformational Isomers from Rotation of Diacetylenic Bond in an Ethynylpyrene-Substituted Molecular Hinge
Published in Journal of organic chemistry (21-03-2008)“…The first example of isolation and X-ray crystallographic structural characterization of two conformers arising from rotation along a diacetylenic bond is…”
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Synthesis and structure of trans-bis(1,4-dimesityl-3-methyl-1,2,3-triazol-5-ylidene)palladium(II) dichloride and diacetate. Suzuki-Miyaura coupling of polybromoarenes with high catalytic turnover efficiencies
Published in Beilstein journal of organic chemistry (10-04-2013)“…trans-Bis(1,4-dimesityl-3-methyl-1,2,3-triazol-5-ylidene)palladium(II) dichloride has been shown to be an excellent catalyst for the multiple Suzuki-Miyaura…”
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First Asymmetric Synthesis of Quinoline Derivatives by Inverse Electron Demand (IED) Diels−Alder Reaction Using Chiral Ti(IV) Complex
Published in Organic letters (28-06-2001)“…(R,R)-3-Aza-3-benzyl-1,5-dihydroxy-1,5-diphenylpentane (1) ligated Ti(IV) complex (1-TiCl2) is used as a chiral Lewis acid catalyst for promoting asymmetric…”
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Synthesis and Characterization of Bis(sigma)borate and Bis–zwitterionic Complexes of Rhodium and Iridium
Published in ChemistrySelect (Weinheim) (16-08-2016)“…Building upon the chemistry of Rh–N,S‐heterocyclic carbene complex, [(Cp*Rh)(L2)(1‐benzothiazol‐2‐ylidene)], 2 (Cp*=η5‐C5Me5; L=C7H4NS2) with various…”
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