Search Results - "BROWN, Gordon E"
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Environmental Speciation of Actinides
Published in Inorganic chemistry (01-04-2013)“…Although minor in abundance in Earth’s crust (U, 2–4 ppm; Th, 10–15 ppm) and in seawater (U, 0.003 ppm; Th, 0.0007 ppm), light actinides (Th, Pa, U, Np, Pu,…”
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Kinetics and Products of Chromium(VI) Reduction by Iron(II/III)-Bearing Clay Minerals
Published in Environmental science & technology (05-09-2017)“…Hexavalent chromium is a water-soluble pollutant, the mobility of which can be controlled by reduction of Cr(VI) to less soluble, environmentally benign…”
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Environmental Transformations of Silver Nanoparticles: Impact on Stability and Toxicity
Published in Environmental science & technology (03-07-2012)“…Silver nanoparticles (Ag-NPs) readily transform in the environment, which modifies their properties and alters their transport, fate, and toxicity. It is…”
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Ordered ferrimagnetic form of ferrihydrite reveals links among structure, composition, and magnetism
Published in Proceedings of the National Academy of Sciences - PNAS (16-02-2010)“…The natural nanomineral ferrihydrite is an important component of many environmental and soil systems and has been implicated as the inorganic core of ferritin…”
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Effect of Chloride on the Dissolution Rate of Silver Nanoparticles and Toxicity to E. coli
Published in Environmental science & technology (04-06-2013)“…Pristine silver nanoparticles (AgNPs) are not chemically stable in the environment and react strongly with inorganic ligands such as sulfide and chloride once…”
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Size-Controlled Dissolution of Organic-Coated Silver Nanoparticles
Published in Environmental science & technology (17-01-2012)“…The solubility of Ag NPs can affect their toxicity and persistence in the environment. We measured the solubility of organic-coated silver nanoparticles (Ag…”
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Arsenic(III) and Arsenic(V) Speciation during Transformation of Lepidocrocite to Magnetite
Published in Environmental science & technology (16-12-2014)“…Bioreduction of As(V) and As-bearing iron oxides is considered to be one of the key processes leading to arsenic pollution in groundwaters in South and…”
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Properties of impurity-bearing ferrihydrite II: Insights into the surface structure and composition of pure, Al- and Si-bearing ferrihydrite from Zn(II) sorption experiments and Zn K-edge X-ray absorption spectroscopy
Published in Geochimica et cosmochimica acta (01-10-2013)“…Naturally occurring ferrihydrite often contains impurities such as Al and Si, which can impact its chemical reactivity with respect to metal(loid) adsorption…”
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Sulfidation Mechanism for Zinc Oxide Nanoparticles and the Effect of Sulfidation on Their Solubility
Published in Environmental science & technology (19-03-2013)“…Environmental transformations of nanoparticles (NPs) affect their properties and toxicity potential. Sulfidation is an important transformation process…”
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EXAFS Analysis of Arsenite Adsorption onto Two-Line Ferrihydrite, Hematite, Goethite, and Lepidocrocite
Published in Environmental science & technology (01-12-2005)“…The modes of As(III) sorption onto two-line ferrihydrite (Fh), hematite (Hm), goethite (Gt), and lepidocrocite (Lp) have been investigated under anoxic…”
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11
An Early-Branching Microbialite Cyanobacterium Forms Intracellular Carbonates
Published in Science (American Association for the Advancement of Science) (27-04-2012)“…Cyanobacteria have affected major geochemical cycles (carbon, nitrogen, and oxygen) on Earth for billions of years. In particular, they have played a major…”
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Sulfidation Processes of PVP-Coated Silver Nanoparticles in Aqueous Solution: Impact on Dissolution Rate
Published in Environmental science & technology (15-06-2011)“…Despite the increasing use of silver nanoparticles (Ag-NPs) in nanotechnology and their toxicity to invertebrates, the transformations and fate of Ag-NPs in…”
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13
Ni speciation in a New Caledonian lateritic regolith: A quantitative X-ray absorption spectroscopy investigation
Published in Geochimica et cosmochimica acta (15-10-2012)“…Changes in Ni speciation in a 64m vertical profile of a New Caledonian saprolitic–lateritic regolith developed over ultramafic rocks under tropical weathering…”
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Properties of impurity-bearing ferrihydrite I. Effects of Al content and precipitation rate on the structure of 2-line ferrihydrite
Published in Geochimica et cosmochimica acta (01-09-2012)“…The association of Al with ferrihydrite (Fh) may have a considerable effect on the composition, structure, and surface properties of Fh nanoparticles, and thus…”
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Properties of impurity-bearing ferrihydrite III. Effects of Si on the structure of 2-line ferrihydrite
Published in Geochimica et cosmochimica acta (15-05-2014)“…Siliceous ferrihydrites are abundant nanoparticles in natural environments. Although it is well known that the physical properties of ferrihydrite are affected…”
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Distinctive Arsenic(V) Trapping Modes by Magnetite Nanoparticles Induced by Different Sorption Processes
Published in Environmental science & technology (01-09-2011)“…Arsenic sorption onto iron oxide spinels such as magnetite may contribute to arsenic immobilization at redox fronts in soils, sediments, and aquifers, as well…”
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XANES Evidence for Oxidation of Cr(III) to Cr(VI) by Mn-Oxides in a Lateritic Regolith Developed on Serpentinized Ultramafic Rocks of New Caledonia
Published in Environmental science & technology (01-10-2009)“…Although several laboratory studies showed that Mn-oxides are capable of oxidizing Cr(III) to Cr(VI), very few have reported evidence for such a reaction in…”
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Uranium Speciation As a Function of Depth in Contaminated Hanford Sediments - A Micro-XRF, Micro-XRD, and Micro- And Bulk-XAFS Study
Published in Environmental science & technology (01-02-2009)“…The distribution and speciation of U and Cu in contaminated vadose zone and aquifer sediments from the U.S. DOE Hanford site (300 Area) were determined using a…”
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Molecular-level modes of As binding to Fe(III) (oxyhydr)oxides precipitated by the anaerobic nitrate-reducing Fe(II)-oxidizing Acidovorax sp. strain BoFeN1
Published in Geochimica et cosmochimica acta (01-09-2011)“…Sorption of contaminants such as arsenic (As) to natural Fe(III) (oxyhydr)oxides is very common and has been demonstrated to occur during abiotic and biotic…”
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Chemical and Reactive Transport Processes Associated with Hydraulic Fracturing of Unconventional Oil/Gas Shales
Published in Chemical reviews (11-05-2022)“…Hydraulic fracturing of unconventional oil/gas shales has changed the energy landscape of the U.S. Recovery of hydrocarbons from tight, hydraulically fractured…”
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