Search Results - "BIBAL, Christine"

A Route to a Germanium-Carbon Triple Bond: First Chemical Evidence for a Germyne by Bibal, Christine, Mazières, Stéphane, Gornitzka, Heinz, Couret, Claude

“…Photolysis of a diazogermylene generates a germylene–carbene species, a resonance form of a germyne (see scheme). Support for the intermediacy of the triply…”
Get full text

A Synthetic Equivalent of a Germanone Derivative by Bonnefille, Eric, Mazières, Stéphane, Bibal, Christine, Saffon, Nathalie, Gornitzka, Heinz, Couret, Claude

“…Reaction of two molar equivalents of 2,6‐bis(diisopropylaminomethyl)phenyllithium (ArLi) with tetramethoxygermane afforded the colourless crystalline dimethoxy…”
Get full text

Ionic Schiff base dioxidomolybdenum(VI) complexes as catalysts in ionic liquid media for cyclooctene epoxidation by Bibal, Christine, Daran, Jean-Claude, Deroover, Simon, Poli, Rinaldo

“…Dioxidomolybdenum(VI) complexes derived from sulfonato iminophenolate Schiff base ligands have been synthesized and engaged in cyclooctene epoxidation with…”
Get full text

Investigation of the Reactivity of Hydroxyborate Salts with Group IV Metal Complexes: Synthesis and Structural Characterization of the Zirconium and Hafnium Ionic Complexes [PPN]+[Cp2MMe(OB(C6F5)3)] by Kelsen, Vinciane, Vallée, Christophe, Jeanneau, Erwann, Bibal, Christine, Santini, Catherine C, Chauvin, Yves, Olivier-Bourbigou, Hélène

“…The syntheses of some novel fluorinated and nonfluorinated hydroxyborate salts, [Q]+[HOB(C6F5)3]− and [Q]+[HOBPh3]− ([Q]+ = aprotic cation), are reported. The…”
Get full text

Structural Characterization and Theoretical Calculations of cis-Dioxo(N-salicylidene-2-aminophenolato)(ethanol)molybdenum(VI) Complexes MoO2(SAP)(EtOH) (SAP = N-salicylidene-2 aminophenolato) by Agustin, Dominique, Bibal, Christine, Neveux, Benjamin, Daran, Jean-Claude, Poli, Rinaldo

“…The crystal structure of MoO2(SAP)(EtOH) is reported for the first time. The compound crystallizes in the monoclinic crystallographic system (P21/n, a =…”
Get full text

A selective synthesis of hydroxyborate anions as novel anchors for zirconocene catalysts by Bibal, Christine, Santini, Catherine C, Chauvin, Yves, Vallée, Christophe, Olivier-Bourbigou, Hélène

“…A new family of hydroxytris(pentafluorophenyl)borate anions [B(C6F5)3OH](-) associated with organic and aprotic cations c+ (imidazolium, pyrrolidinium and…”
Get more information

New Features of Bis(phosphinimine)-“carbene” Binding to RuII by Smurnyy, Yegor, Bibal, Christine, Pink, Maren, Caulton, Kenneth G

“…Analysis of the results of DFT(PBE) calculations on a variety of species containing a “RuC(PPh2NPh)2” subunit led to the proposal that this should be…”
Get full text

Exceptionally Facile CO Addition to a Saturated Ruthenium Complex by Bibal, Christine, Smurnyy, Yegor D, Pink, Maren, Caulton, Kenneth G

“…Synthesis and characterization of Cp*Ru[η3-HC(PPh2NPh)2], 1, reveals it to have a “piano stool” structure with the ligand bound to Ru(II) via two N and the…”
Get full text

Structural Characterization and Theoretical Calculations of cis ‐Dioxo(N‐salicylidene‐2‐aminophenolato)(ethanol)molybdenum(VI) Complexes MoO 2 (SAP)(EtOH) (SAP = N‐salicylidene‐2 aminophenolato) by Agustin, Dominique, Bibal, Christine, Neveux, Benjamin, Daran, Jean‐Claude, Poli, Rinaldo

“…The crystal structure of MoO 2 (SAP)(EtOH) is reported for the first time. The compound crystallizes in the monoclinic crystallographic system ( P 2 1 / n , a…”
Get full text

New Features of Bis(phosphinimine)-“carbene” Binding to Ru II by Smurnyy, Yegor, Bibal, Christine, Pink, Maren, Caulton, Kenneth G.

Get full text

From Chlorogermylenes to Stable Hydroxy- and Siloxy-Germylene−Tungsten Complexes by Bibal, Christine, Mazières, Stéphane, Gornitzka, Heinz, Couret, Claude

“…Reaction of the chlorogermylene ArGeCl [Ar = 2,6-bis((diethylamino)methyl)phenyl] with lithium amides afforded the aminogermylenes ArGeNR2 1 (1a, R = SiMe3;…”
Get full text

Multifunctional behavior by a Bis-(phosphinimino)methanide ligand: eta 2- vs eta 3-coordination vs Bronsted basicity by Bibal, Christine, Pink, Maren, Smurnyy, Yegor D, Tomaszewski, John, Caulton, Kenneth G

“…The reaction of [(Cymene)RuCl2]2 with the chelate LiHC(PPh2NPh)2 occurs to remove both chloride ligands, to furnish a cationic Ru(II) complex with the…”
Get full text

Multifunctional Behavior by a Bis-(phosphinimino)methanide Ligand:  η2- vs η3-coordination vs Bronsted Basicity by Bibal, Christine, Pink, Maren, Smurnyy, Yegor D, Tomaszewski, John, Caulton, Kenneth G

“…The reaction of [(Cymene)RuCl2]2 with the chelate LiHC(PPh2NPh)2 occurs to remove both chloride ligands, to furnish a cationic Ru(II) complex with the…”
Get full text

Exceptionally facile CO addition to a saturated ruthenium complex by BIBAL, Christine, SMURNYY, Yegor D, PINK, Maren, CAULTON, Kenneth G

Get full text

Multifunctional behavior by a bis-(phosphinimino)methanide ligand: η2- vs η3-coordination vs bronsted basicity by BIBAL, Christine, PINK, Maren, SMURNVV, Yegor D, TOMASZEWSKI, John, CAULTON, Kenneth G

Get full text

A Route to a Germanium-Carbon Triple Bond: First Chemical Evidence for a Germyne We thank Prof. Dr. Josef Michl (University of Colorado at Boulder, USA) for helpful discussions by Bibal, Christine, Mazières, Stéphane, Gornitzka, Heinz, Couret, Claude

Get full text

A Route to a Germanium-Carbon Triple Bond: First Chemical Evidence for a Germyne by Bibal, Christine, Mazières, Stéphane, Gornitzka, Heinz, Couret, Claude

“…Die Photolyse eines Diazogermylens liefert eine Germylen‐Carben‐Spezies, eine Resonanzstruktur eines Germins (siehe Schema). Belege dafür, dass die dreifach…”
Get full text

A Route to a Germanium-Carbon Triple Bond: First Chemical Evidence for a Germyne by Bibal, Christine, Mazières, Stéphane, Gornitzka, Heinz, Couret, Claude

Get full text