Search Results - "BETTENCOURT DA SILVA, Ricardo J. N"
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Bottom-Up Evaluation of the Uncertainty of the Quantification of Microplastics Contamination in Sediment Samples
Published in Environmental science & technology (02-08-2022)“…The quantification and comparison of microplastic contamination of sediments are affected by sample heterogeneity and the systematic and random effects…”
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Determination of river water composition trends with uncertainty: Seasonal variation of nutrients concentration in Tagus river estuary in the dry 2017 year
Published in Marine pollution bulletin (01-09-2020)“…The assessment of long-term trends in river water composition is hampered by river composition heterogeneity, and sampling and sample analysis uncertainty…”
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Standard addition method with cumulative additions: Monte Carlo uncertainty evaluation
Published in Analytica chimica acta (20-06-2019)“…The cumulative standard addition method allows the calibration of an instrument affected by matrix effects when a small sample volume is available. Recently,…”
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4
Development and validation of a grouping method for pesticides analysed in foodstuffs
Published in Food chemistry (15-10-2012)“…► Selection of representative pesticides for the simplification of method validation. ► Grouping pesticide according to the equivalence of the pattern of their…”
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Designing valid and optimised standard addition calibrations: Application to the determination of anions in seawater
Published in Talanta (Oxford) (01-09-2015)“…A strategy for designing valid standard addition calibrations and for optimising their uncertainty is presented. The design of calibrations involves the…”
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Validated spreadsheet for the identification of PE, PET, PP and PS microplastics by micro-ATR-FTIR spectra with known uncertainty
Published in Talanta (Oxford) (01-11-2021)“…The monitoring of microplastics in the environment is crucial to determine the relevance and trends of this contamination necessary to plan environmental…”
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Optimization of the determination of chemical oxygen demand in wastewaters
Published in Analytica chimica acta (12-08-2011)“…Variation of the percentage contribution, P j , of the major uncertainty components, of the measurement expanded uncertainty ( U) and of the target measurement…”
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Microplastics contamination in sediments from Portuguese inland waters: Physical-chemical characterisation and distribution
Published in The Science of the total environment (01-08-2022)“…Plastics are the major constituent of waste accumulated in inland waters and subsequently transferred to the ocean. The smaller plastic particles, typically…”
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Compatibility of activity coefficients estimated experimentally and by Pitzer equations for the assessment of seawater pH
Published in Accreditation and quality assurance (01-02-2016)“…Calibration of pH meters is usually performed with reference pH buffer solutions of low ionic strength, I ≤ 0.1 mol kg −1 . For seawater pH measurements ( I…”
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Weighted calibration with reduced number of signals by weighing factor modelling: Application to the identification of explosives by ion chromatography
Published in Analytica chimica acta (04-12-2013)“…•Reliable linear weighted calibrations, based in reduced number of signal, are performed.•Simplification of weighted calibrations is based in prior models of…”
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Statistically sound identification of compounds by low-resolution GC-MS: Identification of tear agents in tear gas sprays
Published in Talanta (Oxford) (01-01-2025)“…Gas-chromatography hyphenated with low-resolution mass spectrometry is a very flexible tool for the cost-effective identification and quantification of…”
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Simplified and Detailed Evaluations of the Uncertainty of the Measurement of Microbiological Contamination of Pharmaceutical Products
Published in Journal of AOAC International (01-10-2024)“…The control of the microbial contamination of pharmaceutical products (PP) is crucial to ensure their safety and efficacy. The validity of the monitoring of…”
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Determination of microplastic contamination levels and trends in vast oceanic sediment areas with uncertainty
Published in The Science of the total environment (01-08-2023)“…Small plastic particles, designated as microplastics, are known vehicles of several contaminants desorbed from their surface after being ingested by marine…”
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Development and validation of statistically sound criteria for the match of unweathered GC-MS fingerprints in oil spill forensics
Published in Chemosphere (Oxford) (01-02-2022)“…The investigation of an oil spill's origin frequently relies on determining the equivalence of oil component patterns in samples from the contaminated…”
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Monte Carlo bottom-up evaluation of global instrumental quantification uncertainty: Flexible and user-friendly computational tool
Published in Chemosphere (Oxford) (01-11-2020)“…Many instrumental methods of analysis require the daily collection of calibrator signals to calibrate their response. The quality of quantifications based on…”
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Microplastics identification by infrared spectroscopy – Evaluation of identification criteria and uncertainty by the Bootstrap method
Published in Talanta (Oxford) (01-03-2021)“…The assessment of microplastic contamination in an environmental compartment involves identifying and counting microplastics in a representative fraction of…”
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Bottom-up uncertainty evaluation of complex measurements from correlated performance data: Determination of total Cr in yeast by ICP-MS after acid digestion
Published in Food chemistry (15-03-2023)“…[Display omitted] •Analyte recovery assessed from spiked yeast and certified reference material analyses.•Estimated recovery correlated from quantifications…”
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Risk of false conformity decisions of multicomponent items controlled by correlated measurement results due to the sharing of analytical steps
Published in Talanta (Oxford) (01-05-2019)“…The assessment of the conformity of some items, such as medicines, food products or drinking waters, with limits set for several of their components, involves…”
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Evaluation of seawater composition in a vast area from the Monte Carlo simulation of georeferenced information in a Bayesian framework
Published in Chemosphere (Oxford) (01-01-2021)“…The detection of composition or pollution trends of vast environmental water areas, from a river, lake or sea, requires the determination of the mean…”
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Statistically sound comparison of standardized and simulation methods for oil spill source identification in real spill scenarios
Published in The Science of the total environment (20-08-2023)“…The comparison of oil patterns of a spill (Sp) and suspected spill source (SS) samples is based on ratios between correlated GC–MS signals of…”
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