Chemometric tools applied to silver nanoparticles electrodeposition in 3D-printed disposable device for the determination of sulfamethoxazole in different samples by voltammetry

[Display omitted] •Disposable electrochemical sensor for sulfamethoxazole monitoring.•Simple and economical composite material based on graphite and nail polish.•Simple and fast voltammetric technique for antibiotic monitoring.•Food, environmental, pharmaceutical, and biological interest samples.•Ch...

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Bibliographic Details
Published in:	Microchemical journal Vol. 193; p. 109091
Main Authors:	B. V. de Oliveira, Wallace, Lisboa, Thalles P., da Silva, Gabriela C., Oliveira, Raylla S., de Souza, Cassiano C., A. C. Matos, Maria, A. L. de Oliveira, Marcone, Matos, Renato C.
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 01-10-2023
Subjects:	3D-printed electrode Box-Behnken design Composite material Silver electrodeposition Sulfamethoxazole Sulfamethoxazole Box-Behnken design Silver electrodeposition Composite material 3D-printed electrode
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Summary:	[Display omitted] •Disposable electrochemical sensor for sulfamethoxazole monitoring.•Simple and economical composite material based on graphite and nail polish.•Simple and fast voltammetric technique for antibiotic monitoring.•Food, environmental, pharmaceutical, and biological interest samples.•Chemometric tools applied to silver nanoparticles electrodeposition. In this paper, a disposable electrode, of low cost (US$ 0.06), easy production, and adequate properties was developed using composite material (CM) modified with silver nanoparticles, immobilized on 3D acrylonitrile butadiene styrene (ABS) support (3Ds-CME/AgNP) for the determination of sulfamethoxazole (SMX) in tap water, synthetic urine, drugs samples, cow milk, goat milk, breast milk, and honey samples. The silver nanoparticles electrodeposition was optimized using 33 Box-Behnken design with triplicate in the central point. The electrode had its surface data characterized by the scanning electron microscopy technique. The bare and modified sensor was compared for the electrochemical response for SMX, where a 30% increase in current signal response was observed. Then, the determination of SMX by differential pulse voltammetry (DPV) using a multivariate calibration optimized method by central composite design (CCD) model 22 was optimized. The results by DPV using 3Ds-CME/AgNP showed a good linear range from 10 to 50 µmol/L, adequate detectability (0.96 µmol/L), good precision (relative standard deviation (RSD) < 5.8 %), and satisfactory recovery ranging from 93 to 115 %. The 3Ds-CME/AgNP device has been shown to be effective for the determination of SMX in different samples using a simple dilution of the sample.
ISSN:	0026-265X 1095-9149
DOI:	10.1016/j.microc.2023.109091