Search Results - "Avila, David V"

Dramatic Solvent Effects on the Absolute Rate Constants for Abstraction of the Hydroxylic Hydrogen Atom from tert-Butyl Hydroperoxide and Phenol by the Cumyloxyl Radical. The Role of Hydrogen Bonding by Avila, David V, Ingold, K. U, Lusztyk, J, Green, W. H, Procopio, D. R

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Absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solution by Avila, David V, Ingold, K. U, Lusztyk, Janusz, Dolbier, W. R, Pan, H. Q, Muir, M

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Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals1 by Avila, David V, Ingold, K. U, Lusztyk, J, Dolbier, W. R, Pan, H.-Q

“…Laser flash photolysis has been used to determine the absolute rate constants for addition of several partially fluorinated n-alkyl radicals to three styrenes…”
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Electronic Absorption Spectra of Some Alkoxyl Radicals. An Experimental and Theoretical Study by Avila, David V, Ingold, K. U, Di Nardo, Ariel A, Zerbetto, Francesco, Zgierski, Marek Z, Lusztyk, Janusz

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Reaction of Phenyl-Substituted o-Quinodimethanes with Nitric Oxide. Are Benzocyclobutenes Suitable Precursors for Nitric Oxide Cheletropic Traps? by Paul, Thomas, Hassan, Mohammed A, Korth, Hans-Gert, Sustmann, Reiner, Avila, David V

“…In order to elucidate the potential of substituted o-quinodimethanes as reagents for the trapping of nitric oxide (NO) in biological systems, the reaction of…”
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Alkene reactivities toward a strongly electrophilic radical. First absolute rate constants for some reactions of perfluoro-n-alkyl radicals in solution by Avila, David V, Ingold, K. U, Lusztyk, J, Dolbier, W. R, Pan, H. Q

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Perfluoro- tert-butyl, a reactive, neutral, electrophilic carbon-centered radical par excellence by Avila, David V, Ingold, Keith U, Lusztyk, J, Dolbier, William R, Pan, H.-Q

“…Absolute rate constants for (CF 3) 3C • addition to terminal olefins increase by roughly a factor of 30 for every 1 eV decrease in the ionization potential…”
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Absolute Rate Constants for Radical Additions to Alkenes in Solution. The Synergistic Effect of Perfluorination on the Reactivities of n-Alkyl Radicals 1 by Avila, David V, Ingold, K U, Lusztyk, J, Dolbier, Jr, W R, Pan, H-Q

“…Laser flash photolysis has been used to determine the absolute rate constants for addition of several partially fluorinated n-alkyl radicals to three styrenes…”
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Rate of reaction of phenyl radicals with oxygen in solution and in the gas phase by Sommeling, Paul M, Mulder, Peter, Louw, Robert, Avila, David V, Lusztyk, Janusz, Ingold, K. U

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Solvent effects on the competitive .beta.-scission and hydrogen atom abstraction reactions of the cumyloxyl radical. Resolution of a long-standing problem by Avila, D. V, Brown, C. E, Ingold, K. U, Lusztyk, J

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Color benzyloxyl and cumyloxyl orange and 4-methoxycumyloxyl blue. Unexpected discovery that arylcarbinyloxyl radicals have strong absorptions in the visible by Avila, D. V, Lusztyk, J, Ingold, K. U

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