Search Results - "Avent, A. G."
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1
Isolation, characterization, and chemical reactions of fullerenes
Published in Pure and applied chemistry (01-01-1993)“…Abstract…”
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2
The fullerenes: Precursors for 21st century materials
Published in Pure and applied chemistry (01-01-1994)“…Abstract…”
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3
Studies toward the synthesis of natural and unnatural dienediynes 1. Approaches to a functionalised bicyclic ring system
Published in Tetrahedron (26-02-1999)“…The synthesis of a functionalised bicyclic ring system related to the naturally occurring dienediynes, NCS and Kedarcidin Chromophores is presented. Key steps…”
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4
The first high resolution direct NMR observation of an f-block element
Published in Journal of the American Chemical Society (01-04-1989)“…The last decade has seen a dramatic increase in the importance of the organometallic chemistry of the lanthanide elements. In particular, iodides,…”
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5
The structure of fullerene compounds
Published in Journal of molecular structure (15-12-1997)“…This account reviews fullerene chemistry research at Sussex. C 60Ph 2 and C 60Ph 4 have been isolated as minor products from the reaction of C 60Cl 6 with C 6H…”
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6
DISSOLUTION OF Ag-SODIUM-CALCIUM-PHOSPHATE GLASSES FOR THE CONTROL OF URINARY TRACT INFECTIONS
Published in Journal of non-crystalline solids (01-01-2003)“…Cast tubes of Ag-Na-Ca-phosphate controlled release glasses have been developed for the delivery of a constant concentration of Ag ion in aqueous flow systems…”
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7
Isolation and characterization of unsymmetrical C(60)Me(5)O(3)H, a cage-opened bisepoxide ketone: tautomerism involving a fullerene cage bond
Published in Organic letters (31-05-2001)“…Bisepoxide ketone C(60)Me(5)O(3)H, possessing a nine-membered hole in the cage, has been isolated from the reaction of C(60)Cl(6) with methyllithium followed…”
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8
Dimerization of β-Diketiminato Calcium Complexes through Dihapto-Acetylide Ligation
Published in Organometallics (14-03-2005)“…The “selective” protonolysis of the β-diketiminato calcium derivative [Ca{(NDippCMe)2CH}{N(SiMe3)2}(THF)] (Dipp = C6H3 iPr2-2,6) with a selection of terminal…”
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9
Synthesis, Structures, Characterization, Dynamic Behavior, and Reactions of Novel Late Transition Metal(II) 1-Azaallyls
Published in Organometallics (24-05-2004)“…A series of homoleptic late transition metal(II) 1-azaallyl compounds ([M(L)2] {L = η3-N(SiMe3)C(tBu)CH(C6H4Me-4), M = Fe (5), Co (6), or Ni (7)}, [M(L1)2] {L1…”
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10
C 1 C70F38 Contains Four Planar Aromatic Hexagons; The Parallel between Fluorination of [60]- and [70]Fullerenes
Published in Organic letters (12-05-2005)“…The main C 1 isomer of C70F38 is shown by single-crystal X-ray analysis to contain four planar aromatic hexagons and four isolated CC bonds, has two fluorines…”
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11
Self-organisation in P-substituted guanidines leading to solution-state isomerisation
Published in Chemical communications (Cambridge, England) (07-11-2004)“…Different isomeric forms of the amidine unit have been identified in Ph2P(E)C[NR'][NHR'] (E = S, Se; R' = iPr, Cy), using both solid- and solution-state…”
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12
Unusual addition patterns in trifluoromethylation of [60]fullerene
Published in Organic & biomolecular chemistry (07-09-2003)“…From pyrolytic trifluoromethylation of [60]fullerene with CF3CO2Ag at 300 degrees C we have isolated ca. sixty C60(CF3)n isomers (numbers in parentheses) as…”
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13
Palladium-mediated fragmentation of meta photocycloadducts using carbon based electrophiles. Part 1
Published in Tetrahedron (03-04-2006)“…Substituted benzene derived meta photocycloadducts have been shown to undergo a fragmentation/arylation reaction under Heck reaction conditions to give bridged…”
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14
Isolation and Characterization of Unsymmetrical C60Me5O3H, a Cage-Opened Bisepoxide Ketone: Tautomerism Involving a Fullerene Cage Bond
Published in Organic letters (31-05-2001)“…Bisepoxide ketone C60Me5O3H, possessing a nine-membered hole in the cage, has been isolated from the reaction of C60Cl6 with methyllithium followed by…”
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15
Novel addition in trifluoromethylation of [70]fullerene
Published in Journal of fluorine chemistry (01-09-2004)“…Graphic Pyrolytic trifluoromethylation of [70]fullerene with CF 3CO 2Ag at 300 °C results in the addition of up to 12 CF 3 groups to the fullerene cage…”
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16
Electrophilic Aromatic Substitution by the Fluorofullerene C60F18
Published in Chemistry : a European journal (20-09-2004)“…The FeCl3‐catalysed arylation of C60F18 gives tri‐substituted compounds C60F15Ar3, where Ar=phenyl, 4‐tolyl, 4‐methoxyphenyl, 4‐phenoxyphenyl, 4‐chlorophenyl,…”
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17
The dissolution of silver–sodium–calcium–phosphate glasses for the control of urinary tract infections
Published in Journal of non-crystalline solids (15-10-2003)“…Cast tubes of silver–sodium–calcium–phosphate controlled release glasses have been developed for the delivery of a constant concentration of silver ion in…”
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18
Synthesis and molecular structures of uranium and thorium diamidoamine complexes
Published in Inorganica Chimica Acta (10-03-2003)“…Treatment of UCl 4 or ThCl 4 with Li 2[Me 3SiN{CH 2CH 2NSiMe 3} 2] affords the mono-diamidoamine complexes [M(Me 3SiN{CH 2CH 2NSiMe 3} 2)Cl 2(THF)] (M=U, Th),…”
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19
Carbon–carbon coupling on tetrahedral iridium clusters: X-ray molecular structures and multinuclear NMR studies of the two isomeric forms of [Ir 4(CO) 6(μ 3-η 2-HCCPh)(μ 2-η 4-C 4H 2Ph 2)(μ-PPh 2) 2]
Published in Journal of organometallic chemistry (01-11-2004)“…Clusters [HIr 4(CO) 9(Ph 2PC CPh)(μ-PPh 2)] ( 1) and [Ir 4(CO) 8(μ 3-η 2-HCCPh)(μ-PPh 2) 2] ( 2) react with HC CPh gave two isomeric forms of [Ir 4(CO) 6(μ 3-η…”
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The lithiation of arylamines and the preparation of cyclopentadienyltitanium(IV) arylaminate complexes
Published in Journal of organometallic chemistry (03-03-2003)“…The 2-lithio-derivatives of a range of aryl-substituted amines were prepared, generally from the 2-bromo-compounds and butyllithium. These compounds cause…”
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