Search Results - "Auner, Norbert"
-
1
Thermal Synthesis of Perchlorinated Oligosilanes: A Fresh Look at an Old Reaction
Published in Chemistry : a European journal (07-09-2017)“…A combined experimental and theoretical study of the high‐temperature reaction of SiCl4 and elemental silicon is presented. The nature and reactivity of the…”
Get full text
Journal Article -
2
The Perchlorinated Silanes Si2Cl6 and Si3Cl8 as Sources of SiCl2
Published in Chemistry : a European journal (18-04-2011)“…Trapped in action: The amine‐induced disproportionation of Si2Cl6 or Si3Cl8 to neo‐Si5Cl12 and SiCl4 involves a SiCl2–base adduct as a key intermediate (see…”
Get full text
Journal Article -
3
Crystal structure of 1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium bromide dichloromethane disolvate
Published in Acta crystallographica. Section E, Structure reports online (01-11-2014)“…The title solvated salt, C29H41N2+·Br−·2CH2Cl2 was obtained from the reaction of the Arduengo-type carbene…”
Get full text
Journal Article -
4
Synthesis, structure, and photoluminescence of organosilicon based compounds containing stilbene, butadiene or styrene subunits
Published in Journal of organometallic chemistry (15-03-2008)“…A series of novel organosilicon based compounds (such as 2, 3, 6– 8) was synthesized by basic organic and organometallic reaction routes. The compounds were…”
Get full text
Journal Article -
5
1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium bromide dichloromethane disolvate
Published in Acta crystallographica. Section E, Structure reports online (01-06-2012)“…In the title compound, C27H37N2+·Br−·2CH2Cl2, both the cation and the anion are located on a crystallographic mirror plane. Both of the…”
Get full text
Journal Article -
6
Molecular Optical Switches: Synthesis, Structure, and Photoluminescence of Spirosila Compounds
Published in Chemistry : a European journal (01-01-2007)“…Starting from a silicon dichloro substituted silole and a silacyclobutene, a series of new organosilicon‐based spiro compounds was synthesized by using…”
Get full text
Journal Article -
7
1,3-Bis(2,6-diisopropylphenyl)-1H-imidazol-3-ium chloride dichloromethane disolvate
Published in Acta crystallographica. Section E, Structure reports online (01-06-2012)“…In the title compound, C27H37N2+·Cl−·2CH2Cl2, the cation and the anion are each located on a crystallographic mirror plane. Both of the…”
Get full text
Journal Article -
8
Synthesis and electrical characterization of intrinsic and in situ doped Si nanowires using a novel precursor
Published in Beilstein journal of nanotechnology (31-07-2012)“…Perchlorinated polysilanes were synthesized by polymerization of tetrachlorosilane under cold plasma conditions with hydrogen as a reducing agent. Subsequent…”
Get full text
Journal Article -
9
Synthesis, Structure, Photoluminescence and Photoreactivity of 2,3‐Diphenyl‐4‐neopentyl‐1‐silacyclobut‐2‐enes
Published in Chemistry : a European journal (24-08-2009)“…A series of six 2,3‐diphenyl‐4‐neopentyl‐1‐silacyclobut‐2‐enes with different 1,1‐substituents has been prepared and characterized by single‐crystal X‐ray…”
Get full text
Journal Article -
10
N-(2,6-Diisopropyl-phen-yl)formamide toluene 0.33-solvate
Published in Acta crystallographica. Section E, Structure reports online (01-05-2012)“…The crystal packing of the title compound, C(13)H(19)NO·0.33C(7)H(8), shows a channel at [001], which contains grossly disordered toluene solvent mol-ecules…”
Get full text
Journal Article -
11
Directed deposition of silicon nanowires using neopentasilane as precursor and gold as catalyst
Published in Beilstein journal of nanotechnology (25-07-2012)“…In this work the applicability of neopentasilane (Si(SiH(3))(4)) as a precursor for the formation of silicon nanowires by using gold nanoparticles as a…”
Get full text
Journal Article -
12
Characterization and Some Insights into the Reaction Chemistry of Polymethylsilsesquioxane or Methyl Silicone Resins
Published in International journal of polymer science (2012)“…Structural characterization of a polymethylsilsesquioxane (PMSQ) and a DT-type methyl silicone resin (MeDT) has been carried out by various instrumental…”
Get full text
Journal Article -
13
One-Step Synthesis of Siloxanes from the Direct Process Disilane Residue
Published in Chemistry : a European journal (21-11-2016)“…The well‐established Müller–Rochow Direct Process for the chloromethylsilane synthesis produces a disilane residue (DPR) consisting of compounds MenSi2Cl6−n…”
Get full text
Journal Article -
14
Synthesis and Properties of Stereoregular Cyclic Polysilanols: cis-[PhSi(O)OH]4, cis-[PhSi(O)OH]6, and Tris-cis-tris-trans-[PhSi(O)OH]12
Published in Inorganic chemistry (16-12-2002)“…New stereoregular cyclic polysilanols of the general formula [PhSi(O)OH]n (n = 6 and 12) have been selectively obtained in high yields by the reaction of…”
Get full text
Journal Article -
15
Synthesis, Structure and Magnetic Properties of a Novel Hexanuclear Copper Methylsiloxane Complex
Published in European Journal of Inorganic Chemistry (01-10-2007)“…A new hexanuclear copper(II) sandwich complex based on two 12‐membered macrocyclic methylsiloxanolate ligands, [Cu6{(MeSiO2)6}2]·6DMF, was synthesized and…”
Get full text
Book Review Journal Article -
16
Alkali-Metal-Directed Hydrolytic Condensation of Trifunctional Phenylalkoxysilanes
Published in European journal of inorganic chemistry (01-03-2004)“…The alkali‐metal‐directed hydrolysis of phenyltrialkoxysilanes, PhSi(OR)3 (R = Me, Et, nBu), was performed under various reaction conditions. The alkali metal…”
Get full text
Journal Article -
17
Synthesis and Structure of Sodium Phenylsiloxanolate
Published in Organometallics (20-03-2000)“…Two different synthetic routes for the formation of sodium phenylsiloxanolate (SPS) have been developed: (i) the cleavage of oligo(phenylsilsesquioxane),…”
Get full text
Journal Article -
18
Müller–Rochow Reloaded: Single-Step Synthesis of Bifunctional Monosilanes
Published in Organometallics (08-08-2022)Get full text
Journal Article -
19
Müller–Rochow Reloaded: Single-Step Synthesis of Bifunctional Monosilanes
Published in Organometallics (08-08-2022)“…A convenient single-step process is reported that provides efficient access to the most valuable bifunctional hydridochlorosilane Me2SiHCl from the crude…”
Get full text
Journal Article -
20
The 2-Silanorbornyl Cation: An Internally Stabilized Silyl Cation
Published in Angewandte Chemie International Edition (04-04-1997)“…The Si analog of the norbornyl cation is a free but internally π‐stabilized silyl cation (1) prepared by a hydride transfer reaction [Eq. (a)]. Ab initio…”
Get full text
Journal Article