Search Results - "Audras, Matthieu"
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Third phase inversion, red oil formation, and multinuclear speciation of tetravalent cerium in the tri-n-butyl phosphate-n-dodecane solvent extraction system
Published in Separation science and technology (13-08-2018)“…The extraction of tetravalent cerium, Ce(IV), from aqueous nitric acid with tri-n-butyl phosphate (TBP) in n-dodecane was studied by varying the aqueous,…”
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Mesoscopic Aspects of Phase Transitions in a Solvent Extraction System
Published in Langmuir (06-11-2012)“…In liquid–liquid extraction, organic phase splitting arises when high concentrations of polar solutes (acids/metal ions) are extracted. Herein, we investigate…”
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Structural Characterization of Am(III)- and Pu(III)-DOTA Complexes
Published in Inorganic chemistry (16-10-2017)“…The complexation of 1,4,7,10-tetrazacyclodecane-1,4,7,10-tetraacetic acid (DOTA) ligand with two trivalent actinides (Am3+ and Pu3+) was investigated by…”
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4
Spectroscopic, electrochemical, and structural aspects of the Ce(IV)/Ce(III) DOTA redox couple chemistry in aqueous solutions
Published in Journal of coordination chemistry (01-10-2016)“…The redox potential of the Ce(IV)/Ce(III) DOTA is determined to be 0.65 V versus SCE, pointing out a stabilization of ~13 orders of magnitude for the…”
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