Search Results - "Atzori, Cesare"
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1
Effect of Benzoic Acid as a Modulator in the Structure of UiO-66: An Experimental and Computational Study
Published in Journal of physical chemistry. C (04-05-2017)“…The identification and quantification of defects are undoubtedly thorough challenges in the characterization of “defect-engineered” metal–organic frameworks…”
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2
High‐Porosity Metal‐Organic Framework Glasses
Published in Angewandte Chemie International Edition (11-04-2023)“…We report a synthetic strategy to link titanium‐oxo (Ti‐oxo) clusters into metal‐organic framework (MOF) glasses with high porosity though the carboxylate…”
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3
Application of Metal-Organic Frameworks and Covalent Organic Frameworks as (Photo)Active Material in Hybrid Photovoltaic Technologies
Published in Energies (Basel) (26-10-2020)“…Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are two innovative classes of porous coordination polymers. MOFs are three-dimensional…”
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4
Adsorption Properties of Ce5(BDC)7.5(DMF)4 MOF
Published in Inorganics (01-01-2020)“…In this article we report on the spectroscopic and adsorptive studies done on Ce(III)-based MOF possessing, upon desolvation, open metal sites, and a discrete…”
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5
Engineering the Charge Density on an In2.77S4/Porous Organic Polymer Hybrid Photocatalyst for CO2‑to-Ethylene Conversion Reaction
Published in Journal of the American Chemical Society (11-01-2023)“…The development of an efficient photocatalyst for C2 product formation from CO2 is of urgent importance toward the deployment of solar-fuel production. Here,…”
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6
Reducibility of Cu-zeolites and stability of Cu+ monocarbonyl adducts: Qualitative and quantitative relationships from MCR-XAS and DFT
Published in Catalysis today (01-02-2024)“…A series of Cu-exchanged zeolites differing in framework topology and composition are studied through in situ X-ray Absorption Spectroscopy (XAS) to highlight…”
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7
Exact Stoichiometry of Ce x Zr 6- x Cornerstones in Mixed-Metal UiO-66 Metal-Organic Frameworks Revealed by Extended X-ray Absorption Fine Structure Spectroscopy
Published in Journal of the American Chemical Society (19-12-2018)“…Bimetallic Ce/Zr-UiO-66 metal-organic frameworks (MOFs) proved to be promising materials for various catalytic redox applications, representing, together with…”
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8
Quantification of Adsorbates by X‑ray Absorption Spectroscopy: Getting TGA-like Information for Free
Published in Journal of physical chemistry. C (24-03-2022)“…Hard X-ray absorption spectroscopy (XAS) is frequently applied in catalysis and gas sorption studies to monitor changes in oxidation states, coordination…”
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9
Disclosing the Properties of a New Ce(III)-Based MOF: Ce 2 (NDC) 3 (DMF) 2
Published in Crystal growth & design (06-02-2019)Get full text
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10
Solubility and Stability of Hexanuclear Ce(IV)–O Clusters
Published in Chemistry of materials (08-08-2023)“…Stable molecular clusters are of interest for targeted deposition in porous materials. In this work, we report the discovery of two new molecular Ce–O clusters…”
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11
Selective Carbon Dioxide versus Nitrous Oxide Adsorption in Cerium(IV) Bithiazole and Bipyridyl Metal‐Organic Frameworks
Published in Advanced functional materials (01-09-2024)“…The two CeIV MOFs [Ce6O4(OH)4(TzTz)6] (Ce_TzTz) and [Ce6O4(OH)4(TzTz)4(PyPy)2] (Ce_TzTz_PyPy; H2TzTz = [2,2′‐bithiazole]‐5,5′‐dicarboxylic acid, H2PyPy =…”
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12
Titration of Cu(I) Sites in Cu-ZSM‑5 by Volumetric CO Adsorption
Published in ACS applied materials & interfaces (11-05-2022)“…Cu-exchanged zeolites are widely studied materials because of their importance in industrial energetic and environmental processes. Cu redox speciation lies at…”
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13
Unravelling the Redox‐catalytic Behavior of Ce4+ Metal–Organic Frameworks by X‐ray Absorption Spectroscopy
Published in Chemphyschem (19-02-2018)“…The introduction of Ce4+ as a structural cation has been shown to be a promising route to redox active metal–organic frameworks (MOFs). However, the mechanism…”
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14
Tailoring novel polymer/UTSA-16 hybrid aerogels for efficient CH4/CO2 separation
Published in Microporous and mesoporous materials (01-08-2022)“…A significant number of industrially relevant separation processes involves the removal of carbon dioxide (CO2), as the purification of natural gas (CO2/CH4…”
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15
Engineering the Charge Density on an In 2.77 S 4 /Porous Organic Polymer Hybrid Photocatalyst for CO 2 -to-Ethylene Conversion Reaction
Published in Journal of the American Chemical Society (11-01-2023)“…The development of an efficient photocatalyst for C2 product formation from CO is of urgent importance toward the deployment of solar-fuel production. Here, we…”
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16
Comprehensive Study of Zr-Doped Ni-Rich Cathode Materials Upon Lithiation and Co-Precipitation Synthesis Steps
Published in ACS applied materials & interfaces (05-06-2024)“…Ni-rich layered oxides LiNi1–x–y Mn x Co y O2 (NMC811, x = 0.1 and y = 0.1) are considered promising cathode materials in lithium-ion batteries (LiBs) due to…”
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17
Metal–Organic Frameworks in Italy: From synthesis and advanced characterization to theoretical modeling and applications
Published in Coordination chemistry reviews (15-06-2021)“…[Display omitted] •This review summarizes the work of the Italian groups working in the field of MOFs•The document is a celebration of ICCC 2022 that will take…”
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18
Synthesis, Crystal Structure, and Photocatalytic Properties of Two Isoreticular Ce(IV)-MOFs with an Infinite Rod-Shaped Inorganic Building Unit
Published in Inorganic chemistry (03-04-2023)“…The use of the V-shaped linker molecules 4,4′-oxydibenzoic acid (H2ODB) and 4,4′-carbonyldibenzoic acid (H2CDB) led to the discovery of two isoreticular…”
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19
Discovery and In Situ Crystallization Studies of Cerium-Based Metal–Organic Frameworks with V‑Shaped Linker Molecules
Published in Inorganic chemistry (25-12-2023)“…We report the discovery and characterization of two porous Ce(III)-based metal–organic frameworks (MOFs) with the V-shaped linker molecules…”
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20
Modulator Effect in UiO-66-NDC (1,4-Naphthalenedicarboxylic Acid) Synthesis and Comparison with UiO-67-NDC Isoreticular Metal–Organic Frameworks
Published in Crystal growth & design (04-10-2017)“…A zirconium metal–organic framework with UiO-66 topology was synthesized using a 1,4-naphthalenedicarboxylic acid (NDC) linker (UiO-66-NDC). From synchrotron…”
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