Search Results - "Asakawa, Masumi"
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Boroxine Nanotubes: Moisture-Sensitive Morphological Transformation and Guest Release
Published in Advanced functional materials (01-02-2014)“…Boroxines, (R‐BO)3, which can be easily synthesized via a dehydration reaction of boronic acids, R–B(OH)2, selectively self‐assemble in toluene into…”
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Rotational Libration of a Double-Decker Porphyrin Visualized
Published in Journal of the American Chemical Society (26-05-2010)“…Scanning tunneling microscopy has revealed the reorientation of one of the macrocyclic rings of the double-decker porphyrin complex [Ce(TPP-Fc)(C22OPP)]…”
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3
Molecular Motion of Surface-Immobilized Double-Decker Phthalocyanine Complexes
Published in Journal of the American Chemical Society (16-12-2009)“…The molecular motion of surface-immobilized double-decker phthalocyanine complexes was examined using STM. (C8OPc)2Ce (1), (C12OPc)2Ce (2), and (C8OPc)Ce(Pc)…”
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4
Arrays of Double-Decker Porphyrins on Highly Oriented Pyrolytic Graphite
Published in Langmuir (20-06-2006)“…Three double-decker complexes of cerium(IV) were synthesized, which commonly have a 5,10,15,20-tetrakis(4-docosyloxyphenyl)porphyrin (C22OPP) moiety as one of…”
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5
Antimicrobial Nanotubes Consisting of Ag‐Embedded Peptidic Lipid‐Bilayer Membranes as Delivery Vehicles
Published in Advanced materials (Weinheim) (04-05-2009)“…Functional drug‐delivery vehicles consisting of Ag‐embedded bilayer membranes of a peptidic lipid nanotube (LNT) are synthesized. The Ag–LNTs possess…”
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6
Semisolid Phase Synthesis of Metal-complexed Organic Nanotubes
Published in Chemistry letters (05-08-2010)“…The first semisolid phase synthesis of organic nanotubes was achieved by mixing an aqueous solution of metal salt with an alcoholic dispersion of glycylglycine…”
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Copper(II)-coordinated organic nanotube: A novel heterogeneous catalyst for various oxidation reactions
Published in Catalysis communications (25-10-2010)“…Copper(II)-coordinated organic nanotube can function as a heterogeneous catalyst for oxidation of a variety of organic compounds in the presence of hydrogen…”
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8
Alkyl Chain Length Dependence of the Self-Organized Structure of Alkyl-Substituted Phthalocyanines
Published in Langmuir (06-05-2008)“…The alkyl chain length on alkyl-substituted phthalocyanines (C n OPc) dependence of their self-organized structures was examined in this study. STM results…”
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Effective Synthesis of Polymer Catenanes by Cooperative Electrostatic/Hydrogen-Bonding Self-Assembly and Covalent Fixation
Published in Macromolecules (12-01-2010)“…The cooperative electrostatic and hydrogen-bonding self-assembly of polymer precursors and the subsequent covalent conversion have been demonstrated as an…”
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10
Threading-Followed-by-Shrinking Protocol for the Synthesis of a [2]Rotaxane Incorporating a Pd(II)−Salophen Moiety
Published in Journal of the American Chemical Society (29-12-2004)“…This communication describes a new protocol for the construction of [2]rotaxanes: “threading-followed-by-shrinking”. This approach involves the threading of a…”
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11
Facile Fabrication and Magnetic Properties of a One-Dimensional Magnetite Peapod in a Lipid Nanotube
Published in ACS applied materials & interfaces (23-05-2012)“…Magnetite nanoclusters (MNCs) were aligned one-dimensionally in the hollow cavity of a lipid nanotube (LNT) as a peapod using a simple mixing method in an…”
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12
Scanning Tunneling Microscopy Observation of Self-Assembled Monolayers of Strapped Porphyrins
Published in Langmuir (18-11-2008)“…In this paper, we reveal that the free-base and zinc strapped porphyrins possessing long alkyl chains, C24OPP-HQ and Zn(C24OPP-HQ), respectively, can be…”
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A Simple N-Acyl-L-amino Acid Constructed Metal-complexed Organic Nanotube Having an Inner Diameter below 10 nm
Published in Chemistry letters (05-02-2011)“…A novel metal-complexed organic nanotube (M–ONT) having an inner diameter below 10 nm was readily prepared from simple N-acyl-L-phenylalanine and nickel(II)…”
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14
Supramolecular nanofiber formation from commercially available arginine and a bola-type diacetylenic diacid via hydrogelation
Published in Polymer journal (01-06-2012)“…A diacetylenic-acid arginine salt gelated water. The supramolecular structure and optical properties of the resultant hydrogel were examined by optical…”
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STM Observation of Alkyl-Chain-Assisted Self-Assembled Monolayers of Pyridine-Coordinated Porphyrin Rhodium Chlorides
Published in Langmuir (22-06-2004)“…Alkyl-chain-assisted self-assembled monolayers of pyridine-coordinated porphyrin rhodium chlorides were observed at the solid−liquid interface by scanning…”
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STM Observation of Labile Axial Ligands to Zinc Porphyrin at Liquid/Solid Interface
Published in Chemistry letters (05-06-2007)“…Observation of labile axial ligand coordination to zinc porphyrins on a graphite surface at liquid/solid interface was achieved by scanning tunneling…”
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Synthesis of a [2]Rotaxane Incorporating a Ni(II)−Salen Moiety: Evidence of Ring-Opening-and-Closing Protocol
Published in Organic letters (25-05-2006)“…We have synthesized a [2]rotaxane from a crown-ether-like macrocycle that undergoes ring opening and closing through cleavage and formation of imino bonds of a…”
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18
Transition Metal(II)-Salen and -Salophen Macrocyclic Complexes for Rotaxane Formation: Syntheses and Crystal Structures
Published in European Journal of Inorganic Chemistry (01-09-2007)“…We used a “threading‐followed‐by‐shrinking” approachto prepare [2]rotaxanes possessing nickel(II)–salen and–salophen moieties. Reactions of macrocycles…”
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A Chemically and Electrochemically Switchable [2]Catenane Incorporating a Tetrathiafulvalene Unit
Published in Angewandte Chemie International Edition (16-02-1998)“…A mechanical switch in a [2]catenane, made up of a cyclobis(paraquat‐p‐phenylene) tetracation interlocked with a macrocyclic polyether containing a…”
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20
Switching “On” and “Off” the Expression of Chirality in Peptide Rotaxanes
Published in Journal of the American Chemical Society (27-03-2002)“…The hydrogen-bond-directed synthesis, X-ray crystal structures, and optical properties of the first chiral peptide rotaxanes are reported. Collectively these…”
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