Search Results - "Armstrong, Daniel W"
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Advances in high-throughput and high-efficiency chiral liquid chromatographic separations
Published in Journal of Chromatography A (07-10-2016)“…•High throughput and high efficiency chiral separations are reviewed.•The date range covers 21st century advances in chiral separations.•High throughput…”
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Fundamental and Practical Insights on the Packing of Modern High-Efficiency Analytical and Capillary Columns
Published in Analytical chemistry (Washington) (15-08-2017)“…New stationary phases are continuously developed for achieving higher efficiencies and unique selectivities. The performance of any new phase can only be…”
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Detection and analysis of chiral molecules as disease biomarkers
Published in Nature reviews. Chemistry (01-05-2023)“…The chirality of small metabolic molecules is important in controlling physiological processes and indicating the health status of humans. Abnormal…”
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Ramifications and Insights on the Role of Water in Chiral Sub/Supercritical Fluid Chromatography
Published in Analytical chemistry (Washington) (19-11-2019)“…More than 40 cosolvents have been used with carbon dioxide to alter its solvation strength. Among the most interesting systems is the subcritical/supercritical…”
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Use of CE for the determination of binding constants
Published in Electrophoresis (01-01-2010)“…In the past two decades, CE has been used frequently for the measurement of apparent binding/association constants. CE has numerous advantages, including short…”
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Highly Efficient Asymmetric Direct Stoichiometric Aldol Reactions on/in Water
Published in Angewandte Chemie (International ed.) (01-01-2007)“…Hydrophobic pocket pleaser: A novel asymmetric catalytic system in water mediated by sulfated β‐cyclodextrin (see picture) can bind the organocatalyst…”
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Chiral ionic liquids: A compendium of syntheses and applications (2005-2012)
Published in Chirality (New York, N.Y.) (01-01-2012)“…In recent years, the field of chiral ionic liquids (CILs) has undergone exponential growth. As the technology has advanced, new ways of synthesizing stable and…”
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Comparison of core‐shell versus fully porous particle packings for chiral liquid chromatography productivity
Published in Journal of separation science (01-04-2023)“…A loading and productivity study was done using three racemates on vancomycin and teicoplanin‐bonded chiral stationary phases of different particle formats…”
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Synthesis of Thermally Stable Geminal Dicationic Ionic Liquids and Related Ionic Compounds: An Examination of Physicochemical Properties by Structural Modification
Published in Chemistry of materials (28-06-2016)“…Geminal dicationic ionic liquids (ILs) often display higher thermal stabilities, viscosities, and densities compared to traditional monocationic ILs. Also,…”
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Degradation Study of Carnosic Acid, Carnosol, Rosmarinic Acid, and Rosemary Extract (Rosmarinus officinalis L.) Assessed Using HPLC
Published in Journal of agricultural and food chemistry (12-09-2012)“…Rosemary, whose major caffeoyl-derived and diterpenoid ingredients are rosmarinic acid, carnosol, and carnosic acid, is an important source of natural…”
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Two-dimensional high performance liquid chromatography for determination of homocysteine, methionine and cysteine enantiomers in human serum
Published in Journal of Chromatography A (21-08-2015)“…•On line system with two columns.•Determination of amino acid enantiomers without derivatization.•Application of the method to the real samples analysis. A…”
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Immobilized Ionic Liquids as High-Selectivity/High-Temperature/High-Stability Gas Chromatography Stationary Phases
Published in Analytical chemistry (Washington) (01-10-2005)“…Ionic liquids (ILs) are a class of nonmolecular solvents in which the cation/anion combination can be easily tuned to provide desired chemical and physical…”
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Variations of l- and d-amino acid levels in the brain of wild-type and mutant mice lacking d-amino acid oxidase activity
Published in Analytical and bioanalytical chemistry (01-05-2018)“…d -amino acids are now recognized to be widely present in organisms and play essential roles in biological processes. Some d -amino acids are metabolized by d…”
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Enzyme-Catalyzed Hydrolysis of Cellulose in Ionic Liquids: A Green Approach Toward the Production of Biofuels
Published in The journal of physical chemistry. B (24-06-2010)“…We investigated the reactivity and stability of a commercial mixture of cellulases in eight ionic liquids by optical and calorimetric techniques. First,…”
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Antibody binding of amyloid beta peptide epimers/isomers and ramifications for immunotherapies and drug development
Published in Scientific reports (31-07-2023)“…Extracellular deposition of amyloid beta (Aβ) peptide is a contributing factor of Alzheimer’s disease (AD). Considerable effort has been expended to create…”
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Structure and Properties of High Stability Geminal Dicationic Ionic Liquids
Published in Journal of the American Chemical Society (19-01-2005)“…Thirty-nine geminal dicationic ILs were synthesized and characterized in terms of their surface tensions, densities, melting points, refractive indices,…”
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Quinine bonded to superficially porous particles for high-efficiency and ultrafast liquid and supercritical fluid chromatography
Published in Analytica chimica acta (22-04-2017)“…Two new anion-exchange columns were prepared by bonding tert-butyl carbamoylated quinine to 2.7 μm superficially porous particle (SPP) silica to create chiral…”
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Macrocyclic glycopeptide chiral selectors bonded to core-shell particles enables enantiopurity analysis of the entire verubecestat synthetic route
Published in Journal of Chromatography A (02-03-2018)“…•Macrocyclic glycopeptide chiral selectors bonded to core-shell particles for enantiopurity analysis of pharmaceutical drugs and synthetic intermediates.•A…”
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Development of New HPLC Chiral Stationary Phases Based on Native and Derivatized Cyclofructans
Published in Analytical chemistry (Washington) (15-12-2009)“…An unusual class of chiral selectors, cyclofructans, is introduced for the first time as bonded chiral stationary phases. Compared to native cyclofructans…”
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Altered profiles and metabolism of l- and d-amino acids in cultured human breast cancer cells vs. non-tumorigenic human breast epithelial cells
Published in Journal of pharmaceutical and biomedical analysis (05-02-2019)“…•Free l-and d-amino acid profiles in MCF-7 breast cancer cells vs. MCF-10A non-tumorigenic breast cells were determined for the first time.•Free L-and D-amino…”
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