Search Results - "Arce, Alejandro J"
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Synthesis and characterization of triosmium and triruthenium pyrene clusters
Published in Journal of organometallic chemistry (15-05-2009)“…As models for chemisorption of arenes on metal surfaces, [M 3(CO) 9(μ-H) 2(μ 3η 1:η 1:η 2-C 16H 8)] (M = Os, Ru) were obtained from the reaction of…”
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Two isomeric products [Os 3(μ-H)(C 14H 9N 4)(CO) 9] formed by orthometallation of the cluster [Os 3(C 14H 10N 4)(CO) 10] containing the chelating ligand 2,3-bis(2-pyridyl)pyrazine
Published in Journal of organometallic chemistry (01-01-2005)“…Thermolysis of complex [Os 3(C 14H 10N 4)(CO) 10] (1) yields two structural isomers formulated as [Os 3(μ-H)(μ,η 3-C 14H 9N 4)(CO) 9] ( 2) and ( 3). Isomer 2…”
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Incorporation of Thiophene Rings into Tri- and Tetraruthenium Clusters via Cyclometalation and C−P Bond Cleavage of the Ligand Diphenyl-2-thienylphosphine
Published in Organometallics (23-01-1996)“…Diphenyl-2-thienylphosphine, Ph2PC4H3S (1), reacts with [Ru3(CO)12] in refluxing toluene to give the compound [Ru3(μ2-H)(μ3-Ph2PC4H2S)(CO)9] (2) (59%),…”
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Reactions of Solid H2Os3(CO)10 with Gaseous CO, NH3, and H2S
Published in Organometallics (01-11-1994)Get full text
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Stereochemical Nonrigidity in (.mu.2-H)(H)Os3(CO)11. Evidence for the Occurrence of a Racemization Process at Low Temperature
Published in Organometallics (01-09-1994)Get full text
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Synthesis, Structures, Isomerism, and Dynamic Behavior of Metalated Derivatives of Methyl-Substituted Pyrroles in Triruthenium Clusters
Published in Organometallics (15-04-1997)“…Direct thermal reaction of [Ru3(CO)12] with 1-methylpyrrole leads to the cluster [Ru3(μ-H)(μ3,η3-C4H3NMe)(CO)9] (1), in which metalation has occurred at the…”
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Synthesis and Molecular Structure of Two Six-Membered Ru3C3 Rings Existing in Boat- and Chairlike Configurations Formed by Insertion of C9H6 Units into Metal−Metal Bonds of [Ru3(CO)12]
Published in Organometallics (02-04-1996)“…The reaction of diazoindene (C9H6N2) with [Ru3(CO)12] in THF leads to the formation of the clusters [Ru3(CO)10(η5:η1-C9H6)] (1), by the insertion of a C9H6…”
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Insertion of a phospholide unit into a metal–metal bond: Synthesis and X-ray structure of [Ru3(CO)9(μ:η1:η5-PC4H2Me2)(η1-C6H5)]
Published in Inorganica Chimica Acta (30-09-2012)“…Thermolysis of the 3,4-dimethyl-1-phenylphosphole monosubstituted triruthenium derivative [Ru3(CO)11(PhPC4H2Me2)] gives [Ru3(CO)9(μ:η1:η5-PC4H2Me2)(η1-C6H5)],…”
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Synthesis, reactivity, and ligand dynamics of Ru3(CO)9(.mu.-CO)(.mu.3-.eta.2-alkyne) compounds
Published in Organometallics (01-08-1991)Get full text
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Synthesis of [Re2(CO)8{μ-N2(C5H4)2}], Derived from the Reaction of [Re2(CO)8(MeCN)2] and Diazocyclopentadiene
Published in Organometallics (15-04-1997)“…The reaction of [Re2(CO)8(MeCN)2] with diazocyclopentadiene in refluxing tetrahydrofuran in a 1:1 molar ratio gave [Re(CO)3(C5H5)] (1), the…”
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Intramolecular [4 + 2] Diels-Alder Cycloadditions of 2-Substituted Phosphabenzene and Arsabenzene in Triosmium Clusters
Published in Organometallics (01-09-1994)Get full text
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Proton spin-lattice NMR relaxation studies of hydride carbonyl clusters: a method to evaluate distances involving hydrido ligands
Published in Inorganic chemistry (01-04-1991)Get full text
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Triosmium clusters formed by oxidative addition and decarbonylation of 2-formylpyrrole: crystal structures of three triosmium clusters containing aromatic or nonaromatic heterocyclic ligands derived from pyrrole
Published in Organometallics (01-01-1990)“…The {mu}-acyl cluster (Os{sub 3}H({mu}{sub 2}-NHCH=CHCH=CCO)(CO){sub 10}) (1) is formed by oxidative addition of 2-formylpyrrole to (Os{sub 3}(CO){sub…”
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Isomeric clusters [HOs3(CO)10(C18H11N6)] obtained from the reaction of [Os3(CO)10(CH3CN)2] with new tris-pyridyl-1,2,4-triazines
Published in Inorganica Chimica Acta (30-03-2012)“…Novel tris-pyridyl-1,2,4-triazines were prepared from the corresponding pyridyl-amidrazone and 2,2′-pyridyl in good yields. Reaction of the triazines with…”
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Reactivity of 2,3-bis(2-pyridyl)pyrazine with [Re 2(CO) 8(CH 3CN) 2]: Molecular structures of [Re 2(CO) 8(C 14H 10N 4)] and [Re 2(CO) 8(C 14H 10N 4)Re 2(CO) 8]
Published in Journal of organometallic chemistry (15-01-2007)“…A new tetranuclear rhenium derivative [Re 2(CO) 8(C 14H 10N 4)Re 2(CO) 8] was obtained from the reaction of [Re 2(CO) 8(CH 3 CN) 2] and…”
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Non-aromatic stabilised form of 3,4-difluoropyrrole at triosmium clusters: N–H and C–H versus C–F activation
Published in Inorganica Chimica Acta (2009)“…Triosmium cluster activation leads to cleavage of a C–F bond in 3,4-difluoropyrrole with concomitant C–H bond cleavage and H migration to the metal framework,…”
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Low temperature allene coupling and isomerization at triosmium clusters
Published in Inorganica Chimica Acta (10-09-2004)“…Coupling and isomerization of allene (CH 2CCH 2) has been found on its interaction with [H 2Os 3(CO) 10]. Compound 4 is the remarkable product of…”
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