Search Results - "Appleby, Kate M."
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Fine-tuning the efficiency of para-hydrogen-induced hyperpolarization by rational N-heterocyclic carbene design
Published in Nature communications (12-10-2018)“…Iridium N -heterocyclic carbene (NHC) complexes catalyse the para -hydrogen-induced hyperpolarization process, Signal Amplification by Reversible Exchange…”
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Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination
Published in Angewandte Chemie International Edition (26-09-2016)“…Manganese‐catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive…”
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SABRE-Relay: A Versatile Route to Hyperpolarization
Published in The journal of physical chemistry letters (01-03-2018)“…Signal Amplification by Reversible Exchange (SABRE) is used to switch on the latent singlet spin order of para-hydrogen (p-H2) so that it can hyperpolarize a…”
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Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para -hydrogen
Published in Chemical science (Cambridge) (01-07-2015)“…The reaction of [Ir(IMes)(COD)Cl], [IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, COD = 1,5-cyclooctadiene] with pyridazine (pdz) and phthalazine…”
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Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination
Published in Angewandte Chemie (26-09-2016)“…Manganese‐catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive…”
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Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalytic Species for Suzuki–Miyaura Couplings (X = P, As)
Published in Organometallics (08-11-2021)“…Tripalladium clusters of the type [Pd3(PPh3)4]2+, wherein three linearly connected Pd atoms are stabilized by phosphine and arsine ligands, have been detected…”
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Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogenElectronic supplementary information (ESI) available: Synthesis, Characterisation, kinetic and hyperpolarisation data with the kinetic model is available here. See DOI: 10.1039/c5sc00756a
Published 15-06-2015“…The reaction of [Ir(IMes)(COD)Cl], [IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene, COD = 1,5-cyclooctadiene] with pyridazine (pdz) and phthalazine…”
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Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen† †Electronic supplementary information (ESI) available: Synthesis, Characterisation, kinetic and hyperpolarisation data with the kinetic model is available here. See DOI: 10.1039/c5sc00756a
Published in Chemical science (Cambridge) (28-04-2015)“…Reaction of [Ir(IMes)(COD)Cl] with pyridazine (pdz) or phthalazine (phth) and H 2 results in the formation of the para -hydrogen magnetisation transfer…”
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