Silver recycling from defective GdBCO/Ag high-temperature superconducting bulks

Silver recycling from defective GdBCO/Ag high-temperature superconducting bulks

The silver used as a mechanical reinforcement in REBCO bulks accounts for approximately half of the total material costs. Despite this, no viable recycling techniques have yet been published. Thus, we have developed a simple method for silver recycling from end-of-life and failed REBCO bulks based o...

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Bibliographic Details
Published in:IEEE transactions on applied superconductivity Vol. 33; no. 5; pp. 1 - 5
Main Authors: Antoncik, F., Lojka, M., Hlasek, T., Sklenka, J., Jankovsky, O., Sedmidubsky, D.
Format: Journal Article
Language:English
Published: New York IEEE 01-08-2023
The Institute of Electrical and Electronics Engineers, Inc. (IEEE)
Subjects:
Costs
End of life
High temperature
high-temperature superconductors (HTS)
Microstructure
Nitric acid
Phase composition
Powders
rare-earth-barium-copper-oxides (REBCO)
Recycling
Scanning electron microscopy
Silver
Superconductivity
X-ray scattering
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Summary:The silver used as a mechanical reinforcement in REBCO bulks accounts for approximately half of the total material costs. Despite this, no viable recycling techniques have yet been published. Thus, we have developed a simple method for silver recycling from end-of-life and failed REBCO bulks based on their dissolution in azeotropic nitric acid and subsequent selective precipitation. The phase compositions of the REBCOwaste, intermediates andfinal product were studied by XRD, which confirmed the preparation of pure metallic silver. The recycled silver was then used to manufacture 28 mm EuBCOsingle-domainbulks, whosesuperconductingproperties showed no significant differences from reference bulks containing commercial Ag 2 O. SEM confirmed that the microstructure of the cut bulks was also typical of REBCO bulks. Thus, it appears that the implementation of silver recycling within the REBCO production chain can increase the cost-competitiveness and adoption of REBCO/Ag products while maintaining their properties and microstructure.
ISSN:1051-8223
1558-2515
DOI:10.1109/TASC.2023.3251285