Search Results - "Angamuthu, Venkatachalam"
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Synthesis of Natural (-)-Antrocin and its Enantiomer via Stereoselective Aldol Reaction
Published in Molecules (Basel, Switzerland) (14-02-2020)“…The total synthesis of (-)-antrocin and its enantiomer are presented. Antrocin (-)- is an important natural product which acts as an antiproliferative agent in…”
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2
Brucine Diol-Catalyzed Enantioselective Morita-Baylis-Hillman Reaction in the Presence of Brucine N-Oxide
Published in Catalysts (01-02-2021)“…Brucine diol (BD) catalyzed asymmetric Morita–Baylis–Hillman (MBH) reaction is observed for the first time. Brucine N-oxide (BNO) was found to not have an…”
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3
Anti-addition of Dimethylsulfoxonium Methylide to Acyclic α,β-Unsaturated Ketones and Its Application in Formal Synthesis of an Eicosanoid
Published in ACS omega (31-08-2017)“…Cyclopropanation using dimethylsulfoxonium methylide (Corey–Chaykovsky reaction) was examined with a series of linear α,β-unsaturated ketones, and the results…”
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4
Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems
Published in Journal of the American Chemical Society (05-02-2020)“…Radical reduction of alkyl halides and aerobic oxidation of alkyl aromatics are reported using water-soluble container compounds (1 and 2). The reductions…”
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Synthesis of Optically Active Organofluorides by Ring Opening of Oxazolidinone-Fused Aziridines
Published in Organic letters (13-01-2023)“…A general method for synthesizing optically active, primary, secondary, and tertiary organofluorides was developed. This chiral pool synthesis utilized the…”
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New chiral morpholine-pyrrolidine ligands affecting asymmetric selectivity in copper catalyzed Henry reaction
Published in Tetrahedron letters (28-02-2019)“…[Display omitted] •New chiral amines having chiral morpholine and pyrrolidine moieties were prepared.•These chiral amines formed copper (II) complexes in situ…”
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Pharmacological activities of antroquinonol- Mini review
Published in Chemico-biological interactions (05-01-2019)“…Antrodia camphorata is an expensive mushroom that grows on the inner cavity of an endangered native tree of Taiwan namely Cinnamomum kanehirai Hayata. It is…”
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Asymmetric reactions of chiral organo-magnetic nanoparticles
Published in Applied catalysis. A, General (05-10-2015)“…[Display omitted] •Chiral organocatalysts supported on magnetic nano particles (MNPs) have been divided into five categories and discussed their application…”
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Synthesis of Methyl l‑Kijanosides by Regio- and Stereoselective Ring Opening of 2‑Oxazolidinone-Fused Aziridines
Published in Organic letters (20-03-2020)“…Kijanose is one of the most highly functionalized deoxysugars found in nature and a challenging synthetic target. We found that the ring opening of…”
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10
Chiral amine and macrocycle fabricated magnetic nanoparticle asymmetrically catalyzed direct aldol reaction
Published in Sustainable chemistry and pharmacy (01-09-2019)“…Chiral amine and their derivatives have been proved to be powerful organocatalysts for asymmetric transformations. There is a trend to combine organocatalyst…”
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11
Palladium-Catalyzed Allylic Substitution for the Synthesis of Pericosines
Published in Asian journal of organic chemistry (01-11-2016)“…A sequence of vinylalumination of α‐substituted aldehydes, ring‐closing metathesis (RCM), and palladium‐catalyzed allylic substitution was utilized to prepare…”
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