Search Results - "Andriyankova, Ludmila V."
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(Imidazol‐2‐yl)methyl‐1,3‐propanediones: Regioselective C–H Functionalization of the Imidazole Ring by Acylacetylene/Aldehyde Pairs
Published in European journal of organic chemistry (01-02-2016)“…The metal‐free regioselective C‐2–H functionalization of 1‐substituted imidazoles has been effected by a cascade reaction with aromatic or heteroaromatic…”
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Ring-Opening of Pyridines with Acylacetylenes and Water: Straightforward Access to 5-[(Z)-Acylethenyl]amino-2,4-pentadienals
Published in European journal of organic chemistry (01-12-2015)“…Pyridines undergo exceptionally facile ring opening under the action of acylacetylenes (e.g., benzoylphenylacetylene, furoylphenylacetylene, and…”
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Stereoselective Tandem Ring Opening of Imidazoles with Electron-Deficient Acetylenes and Water: Synthesis of Functionalized (Z,Z)‑1,4-Diaza-2,5-dienes
Published in Organic letters (03-05-2013)“…1-Substituted imidazoles undergo exceptionally facile stereoselective ring opening under the influence of electron-deficient acetylenes and water (equimolar…”
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Three-component reaction of imidazoles, cyanophenylacetylene, and chalcogens: stereoselective synthesis of 3-alkenyl-2-imidazolethiones and -selones
Published in Tetrahedron (01-02-2014)“…The three-component reaction of 1-substituted imidazoles, cyanophenylacetylene, and elemental sulfur or selenium proceeds readily (for sulfur at room…”
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Three-component reaction between imidazoles, isocyanates, and cyanophenylacetylene: a short-cut to N-(Z)-alkenylimidazole-2-carboxamides
Published in Tetrahedron letters (26-12-2012)“…1-Substituted imidazoles, isocyanates, and cyanophenylacetylene react under mild (rt), non-catalytic solvent-free conditions to give…”
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C(2)-Functionalization of 1-substituted imidazoles with cyanoacetylenes and aromatic or heteroaromatic aldehydes
Published in Tetrahedron (11-02-2011)“…Substituted imidazoles (substituents are Me, Et, i-Bu, n-Hexyl, (CH 2) 2S–Bu- n, Ph, Bn) react smoothly (room temperature, without catalyst and solvent) with…”
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Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water
Published in Mendeleev communications (01-07-2014)“…Trialkylamines react with acyl- and cyanoacetylenes in the presence of water (90–100°C, 37–43h) to give functionalized N,N-dialkyl-vinylamines, the products of…”
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2,4-Diphenylpyrido[2,1-a]isoquinolinium nitrite from the domino reaction between isoquinoline, 1,3-diphenylprop-2-yn-1-one and nitromethane
Published in Mendeleev communications (01-05-2014)“…The three-component reaction between isoquinoline, 1,3-diphenylprop-2-yn-1-one and nitromethane (90–100°C, 26h) affords 2,4-diphenyl-…”
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Cascade cyclization of quinoline and quinoxaline with nitriles of α,β-acetylenic γ-hydroxy acids
Published in Mendeleev communications (2003)“…Quinoline and quinoxaline react regiospecifically and stereoselectively with the nitriles of α,β-acetylenic γ-hydroxy acids to form new annelated heterocyclic…”
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Ring-opening of pyridines and imidazoles with electron-deficient acetylenes: En route to metal-free organic synthesis
Published in Mendeleev communications (01-03-2017)“…[Display omitted] The article is focused on the recently developed methodology for the efficient synthesis of diverse highly unsaturated previously unknown…”
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C2-Functionalization of 1-Substituted Imidazoles with Aldehydes and Electron-Deficient Acetylenes: A Novel Three-Component Reaction
Published in European Journal of Organic Chemistry (01-03-2010)“…A novel three‐component reaction between 1‐substituted imidazoles, aldehydes, and electron‐deficient acetylenes proceeds under mild conditions (20–25 °C, no…”
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Reaction of imidazole derivatives with trifluoromethylated arylacetylenes
Published in Journal of fluorine chemistry (01-08-2016)“…[Display omitted] •Nucleophilic addition of imidazoles to CF3-acetylenes leads to Z-isomers.•Mixture of β- and α- vinylated imidazoles and benzimidazoles is…”
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A three-component reaction between 1-substituted-2-methylimidazoles, cyanophenylacetylene, and various aldehydes: stereoselective synthesis of (Z)-(2-cyano-1-phenyl)vinyl ethers of 2-(2-hydroxyalkyl)imidazoles
Published in Tetrahedron letters (28-08-2013)“…A three-component reaction between 1-substituted-2-methylimidazoles (1-Me, Bn), cyanophenylacetylene, and aliphatic (Me, i-Pr, n-Bu) and aromatic (Ph, 4-CN-,…”
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Insertion of 1,3-diphenylprop-2-yn-1-one into imidazo[4,5-b]pyridines in the presence of water: one-pot synthesis of pyrido[2,3-b][1,4]diazocin-9-ones
Published in Mendeleev communications (01-01-2016)“…[Display omitted] 1,3-Diphenylprop-2-yn-1-one is inserted into 3-substituted imidazo[4,5-b]pyridines upon refluxing in MeCN in the presence of equimolar amount…”
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The reaction of 1,5,6-trimethylbenzimidazole with 1,3-diphenylprop-2-yn-1-one and water: en route to β-amino enones and benzodiazocinones
Published in Mendeleev communications (01-07-2015)“…Refluxing the mixture of 1,5,6-trimethylbenzimidazole, 1,3-diphenylprop-2-yn-1-one and water in MeCN for 70h affords…”
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Annelation of Benzimidazoles with α,β-Acetylenic γ-Hydroxyacid Nitriles and Hydrolytic Rearrangement of the Cycloadducts on Alumina
Published in European Journal of Organic Chemistry (01-02-2007)“…1‐Substituted benzimidazoles are readily annelated regio‐ and stereoselectively with α,β‐acetylenic γ‐hydroxyacidnitriles under mild conditions (20–25 °C, no…”
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Book Review Journal Article -
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Stereoselective annelation of 3-substituted imidazo[4,5-b]pyridines with cyanoacetylenic alcohols and domino rearrangement of the adducts
Published in ARKIVOC (16-04-2012)Get full text
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Regio- and stereoselective annelation of phenanthridines with α,β-acetylenic γ-hydroxyacid nitriles
Published in Tetrahedron (15-08-2005)“…Phenanthridines (3,4-, 7,8-benzoquinolines and methyloctahydrophenanthridine) are annelated regio- and stereoselectively with α,β-acetylenic γ-hydroxyacid…”
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A facile annelation of pyridines with nitriles of α,β-acetylenic γ-hydroxyacids
Published in Tetrahedron letters (04-02-2002)“…Pyridines are readily annelated with nitriles of α,β-acetylenic γ-hydroxyacids under mild conditions (ambient temperature, no catalyst, no solvent) to give new…”
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