Experimental and predicted data of excess molar enthalpies and excess molar volumes for the ternary system (1,3-dichlorobenzene + benzene + 1-chlorohexane) at T = 298.15 K

Experimental excess molar enthalpies, densities and excess molar volumes for the ternary system {x sub(1) 1,3-dichlorobenzene + x sub(2) benzene + (1 - x sub(1) - x sub(2)) 1-chlorohexane} have been determined at the temperature of 298.15 K and atmospheric pressure. Values of excess molar enthalpies...

Full description

Saved in:

Bibliographic Details
Published in:	The Journal of chemical thermodynamics Vol. 73; pp. 190 - 196
Main Authors:	Mato, Marta M, Verdes, Pedro V, Andrade, MIPaz, Legido, Jose Luis
Format:	Journal Article
Language:	English
Published:	01-06-2014
Subjects:	Benzene Densimeters Density Enthalpy Liquids Molar volume Polynomials Ternary systems
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Description
Summary:	Experimental excess molar enthalpies, densities and excess molar volumes for the ternary system {x sub(1) 1,3-dichlorobenzene + x sub(2) benzene + (1 - x sub(1) - x sub(2)) 1-chlorohexane} have been determined at the temperature of 298.15 K and atmospheric pressure. Values of excess molar enthalpies were measured using a Calvet microcalorimeter, and excess molar volumes were determined from the densities of the pure liquids and mixtures, using a vibrating-tube densimeter. The results were fitted by means of different variable degree polynomials. Smooth representations of the results are presented and used to construct constant contours of excess molar enthalpy and excess molar volume on Roozeboom diagrams. Several empirical expressions that have been suggested for use with parameters and predicting excess properties of ternary mixtures from the experimental binary data were tested.
Bibliography:	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
ISSN:	0021-9614
DOI:	10.1016/j.jct.2013.12.024