Search Results - "Anderson, Gordon K"
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Synthesis of Neutral Molecular Squares Composed of Bis(phosphine)platinum Corner Units and Dialkynyl Linkers. Solid-State Characterization of [Pt(μ-C⋮CC⋮C)(dppp)]4
Published in Organometallics (13-09-2004)“…Coupling of dichloroplatinum complexes with ethyne or butadiyne, catalyzed by CuI in the presence of Et2NH, leads to complexes of the types [Pt(C⋮CH)2L2] (L2 =…”
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Palladium and Platinum Complexes Containing the Linear Tetraphosphine Bis[((diphenylphosphino)ethyl)phenylphosphino]methane
Published in Organometallics (31-03-2003)“…The linear tetraphosphine bis[((diphenylphosphino)ethyl)phenylphosphino]methane (DPPEPM) has been prepared and separated into its meso and racemic forms. Each…”
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Convenient method for the synthesis of chloro-bridged methyl- and acetylpalladium(II) dimers
Published in Organometallics (01-01-1994)Get full text
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Reductive Elimination of Alkanes and Arenes from [Pd2R2(μ-H)(μ-dppm)2]PF6 Complexes
Published in Journal of the American Chemical Society (01-09-1999)Get full text
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Cleavage of Metal−Carbon Bonds in Hydride-Bridged Platinum and Palladium A-Frame Complexes
Published in Organometallics (02-04-1996)“…The hydride-bridged A-frame complexes [RPt(μ-H)(μ-dppm)2PtR‘]PF6 and [RPt(μ-H)(μ-dppm)2PdR‘]PF6 react with HCl (generated by reaction of acetyl chloride with…”
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Nucleophilic Attack on Cyclooctadiene Complexes of Palladium: Stereochemistry of the Resulting Cyclooctenylpalladium Derivatives
Published in Organometallics (16-03-1998)“…Reaction of [PdClMe(cod)] with MeO2CC⋮CCO2Me occurs in two steps, namely, insertion of the alkyne into the Pd−Me bond followed by migratory insertion of one of…”
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Fluxional Behavior of η1,η2-Cyclooctenylpalladium Acetylacetonate and Related Complexes
Published in Organometallics (12-10-1998)“…The cyclooctenylpalladium complexes [Pd(η1,η2-C8H12·R)(acac)] exhibit fluxional behavior in solution that equilibrates the acac methyl environments. Free…”
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Concomitant polymorphism and conformational polymorphism in diiodobis[1,2-bis(diphenylphosphino)ethane]platinum(II)
Published in Inorganica Chimica Acta (10-06-2007)“…Crystallization of diiodobis[1,2-bis(diphenylphosphino)ethane]platinum(II) resulted in the formation of two concomitant polymorphs. In the structures of…”
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General Route to Halide-Bridged Organopalladium A-Frame Complexes and Studies of Reductive Elimination from These Bimetallic Systems
Published in Organometallics (26-11-2001)“…Reactions of [Pd2Cl2(μ-dppm)2] with RMgX (R = Me, Et, Bu, Ph, C6H4Me-4) at low temperature, followed by addition of CBr4 and excess NH4PF6 or 1 equiv of TlPF6,…”
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Synthesis and Structures of Platinum A-Frame Complexes
Published in Organometallics (27-11-2000)“…Reactions of [PtCl2(cod)] with the appropriate Grignard reagents produce [PtR2(cod)] (R = C6H5, C6H4CH3-4, C6H4CH3-2, CH2C6H5), which, on treatment with 1 mol…”
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Synthesis and reactions of platinum(IV) complexes with sodium ascorbate
Published in Inorganica Chimica Acta (25-11-2002)“…The platinum(IV) complexes [PtCl 2(OH) 2( N ∩ N)] ( N ∩ N=en, N, N-dmen, N, N′-dmen) were prepared by oxidation of [PtCl 2( N ∩ N)] with hydrogen peroxide. The…”
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Approaches to bi- and trimetallic platinum and palladium complexes using the DPPEPM ligand
Published in Inorganic chemistry communications (01-10-2003)“…Bis{(diphenylphosphinoethyl)phenylphosphino}methane (DPPEPM) reacts with [PtR 2(cod)] in 1:1 ratio to give [PtR 2(DPPEPM- PP)] ( 2a, R=Me; 2b, R=Ph), whereas…”
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Role of the trichlorostannate ligand in homogeneous catalysis. Mechanistic studies of the carbonylation of phenylplatinum(II) complexes
Published in Organometallics (01-01-1982)Get full text
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Synthesis and Characterization of Platinum(II) Complexes of l-Ascorbic Acid. Crystal Structure of Ascorbato-C 2,O 5-ethylenediamineplatinum(II) Dihydrate
Published in Inorganic chemistry (13-12-1999)“…Reactions between diaminediaquaplatinum complexes [Pt(N∩N)(H2O)2]2+ and sodium ascorbate (NaHAsc) have been studied using 1H and 195Pt NMR spectroscopy…”
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Synthesis and structures of hydride-bridged palladium A-frame complexes
Published in Inorganica Chimica Acta (30-04-2000)“…A series of hydride-bridged palladium A-frame complexes [Pd2R2(μ-H)(μ-dppm)2]PF6 has been prepared by reaction of [Pd2Cl2(μ-dppm)2] with 2 equiv. of a Grignard…”
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Reactions of [PdX2(dppm)] Complexes with Grignard Reagents
Published in Organometallics (11-11-1997)“…Reactions of [PdX2(dppm)] (X = Cl, Br) with a range of Grignard reagents have been investigated. Diorganopalladium complexes of the type [PdR2(dppm)] were…”
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Unsymmetrical Hydride-Bridged A-Frame Complexes of Platinum and Palladium
Published in Organometallics (01-10-1994)Get full text
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Synthesis, Molecular Structures, and Fluxional Behavior of dppm-Bridged Complexes of Platinum(II) with Linear Gold(I), Trigonal Silver(I), or Tetrahedral Mercury(II) Centers
Published in Organometallics (17-09-1996)“…The complexes [PtR(dppm-P,P)(dppm-P)]PF6 (R = Me, Et, Ph) react with [AuCl(SMe2)] to generate the dppm-bridged platinum−gold complexes…”
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Preparation and structure of new homochiral diazaphosphole ligands and their platinum(II) chloride complexes
Published in Tetrahedron: asymmetry (27-03-1998)“…A new series of homochiral diazaphosphole ligands and their platinum complexes were prepared…”
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