Search Results - "Amaya, Jose A"
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On the Structure and Reaction Mechanism of Human Acireductone Dioxygenase
Published in Chemistry : a European journal (06-04-2018)“…Acireductone dioxygenase (ARD) is an intriguing enzyme from the methionine salvage pathway that is capable of catalysing two different oxidation reactions with…”
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2
Mixed regiospecificity compromises alkene synthesis by a cytochrome P450 peroxygenase from Methylobacterium populi
Published in Journal of inorganic biochemistry (01-05-2016)“…Intensive interest has focused on enzymes that are capable of synthesizing hydrocarbons, alkenes and alkanes, for sustainable fuel production. A recently…”
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3
Proton Relay Network in the Bacterial P450s: CYP101A1 and CYP101D1
Published in Biochemistry (Easton) (11-08-2020)“…Cytochrome P450s are among nature’s most powerful catalysts. Their ability to activate molecular dioxygen to form high-valent ferryl intermediates (Compounds I…”
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The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry
Published in Biochemistry (Easton) (05-07-2017)“…OleT is a cytochrome P450 enzyme that catalyzes the removal of carbon dioxide from variable chain length fatty acids to form 1-alkenes. In this work, we…”
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Experimental and Theoretical Examination of the Kinetic Isotope Effect in Cytochrome P450 Decarboxylase OleT
Published in The journal of physical chemistry. B (19-05-2022)“…Using a combination of experimental studies, theory, simulation, and modeling, we investigate the hydrogen atom transfer (HAT) reaction by the high-valent…”
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A Distal Loop Controls Product Release and Chemo- and Regioselectivity in Cytochrome P450 Decarboxylases
Published in Biochemistry (Easton) (23-01-2018)“…Cytochrome P450 OleT utilizes hydrogen peroxide (H2O2) to catalyze the decarboxylation or hydroxylation of fatty acid (FA) substrates. Both reactions are…”
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7
Unexpected Differences between Two Closely Related Bacterial P450 Camphor Monooxygenases
Published in Biochemistry (Easton) (28-07-2020)“…The bacterial cytochrome P450cam catalyzes the oxidation of camphor to 5-exo-hydroxycamphor as the first step in the oxidative assimilation of camphor as a…”
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8
Enhancing ferryl accumulation in H2O2-dependent cytochrome P450s
Published in Journal of inorganic biochemistry (01-03-2024)“…A facile strategy is presented to enhance the accumulation of ferryl (iron(IV)-oxo) species in H2O2 dependent cytochrome P450s (CYPs) of the CYP152 family. We…”
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Structural analysis of P450 AmphL from Streptomyces nodosus provides insights into substrate selectivity of polyene macrolide antibiotic biosynthetic P450s
Published in The Journal of biological chemistry (01-04-2022)“…AmphL is a cytochrome P450 enzyme that catalyzes the C8 oxidation of 8-deoxyamphotericin B to the polyene macrolide antibiotic, amphotericin B. To understand…”
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10
Activation of C–H Bonds of Alkyl- and Arylnitriles by the TaCl5–PPh3 Lewis Pair
Published in Inorganic chemistry (02-10-2017)“…A new pathway of activation of C–H bonds of alkyl- and arylnitriles by a cooperative action of TaCl5 and PPh3 under mild conditions is reported. Coordination…”
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11
Divergent mechanisms of iron-containing enzymes for hydrocarbon biosynthesis
Published in Journal of biological inorganic chemistry (01-04-2017)“…Increasing levels of energy consumption, dwindling resources, and environmental considerations have served as compelling motivations to explore renewable…”
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12
Activation of C-H Bonds of Alkyl- and Arylnitriles by the TaCl 5 -PPh 3 Lewis Pair
Published in Inorganic chemistry (02-10-2017)“…A new pathway of activation of C-H bonds of alkyl- and arylnitriles by a cooperative action of TaCl and PPh under mild conditions is reported. Coordination of…”
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13
Enhancing ferryl accumulation in H 2 O 2 -dependent cytochrome P450s
Published in Journal of inorganic biochemistry (01-03-2024)“…A facile strategy is presented to enhance the accumulation of ferryl (iron(IV)-oxo) species in H O dependent cytochrome P450s (CYPs) of the CYP152 family. We…”
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14
Historia del nombre genérico Escallonia mutis ex L. Fil. Historia del nombre genérico Escallonia mutis ex L. Fil
Published in Caldasia (01-06-1991)“…According with the historical context of the Real Expedición Botánica del Nuevo Reino de Granada (1783-1816), the nomenclatural history of the generic name…”
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EL APORTE DEL DIPLOMÁTICO SUECO HANS JACOB GAHN (1748-1800) A LA FORMACIÓN DE LA BIBLIOTECA DE HISTORIA NATURAL DE JOSÉ CELESTINO MUTIS (1732-1808)
Published in Historia crítica (Bogotá, Colombia) (01-01-1995)“…Se trata de profundizar en el estudio del papel que desempeñó la ciencia sueca en la implantación de la historia natural en el virreinato de la Nueva Granada…”
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HISTORIA DEL NOMBRE GENERICO ESCALLONIA MUTIS EX L. FIL
Published in Caldasia (01-07-1991)“…Dentro del contexto histórico de la Real Expedición Botánica del Nuevo Reino de Granada (1783-1816), se realiza el seguimiento del nombre genérico Escallonia…”
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