Search Results - "Amatucci, Glenn G"
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Tracking lithium transport and electrochemical reactions in nanoparticles
Published in Nature communications (13-11-2012)“…Expectations for the next generation of lithium batteries include greater energy and power densities along with a substantial increase in both calendar and…”
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Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes
Published in Journal of the American Chemical Society (23-11-2011)“…Materials that undergo a conversion reaction with lithium (e.g., metal fluorides MF2: M = Fe, Cu, ...) often accommodate more than one Li atom per…”
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Evolution of the Electrode–Electrolyte Interface of LiNi0.8Co0.15Al0.05O2 Electrodes Due to Electrochemical and Thermal Stress
Published in Chemistry of materials (13-02-2018)“…For layered oxide cathodes, impedance growth and capacity fade related to reactions at the cathode–electrolyte interface (CEI) are particularly prevalent at…”
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Transport, Phase Reactions, and Hysteresis of Iron Fluoride and Oxyfluoride Conversion Electrode Materials for Lithium Batteries
Published in ACS applied materials & interfaces (23-07-2014)“…Potentiostatic intermittent titration technique (PITT) was applied to FeF2, FeF3, and FeO0.67F1.33 to gain insight into the transport-related aspects of the…”
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How Bulk Sensitive is Hard X‑ray Photoelectron Spectroscopy: Accounting for the Cathode–Electrolyte Interface when Addressing Oxygen Redox
Published in The journal of physical chemistry letters (19-03-2020)“…Sensitivity to the “bulk” oxygen core orbital makes hard X-ray photoelectron spectroscopy (HAXPES) an appealing technique for studying oxygen redox candidates…”
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Effect of oxygen non-stoichiometry and temperature on cation ordering in LiMn2-xNixO4 (0.50 ≥ x ≥ 0.36) spinels
Published in Journal of power sources (25-02-2007)Get full text
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Sodiation via Heterogeneous Disproportionation in FeF2 Electrodes for Sodium-Ion Batteries
Published in ACS nano (22-07-2014)“…Sodium-ion batteries utilize various electrode materials derived from lithium batteries. However, the different characteristics inherent in sodium may cause…”
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Distinction between Intrinsic and X‑ray-Induced Oxidized Oxygen States in Li-Rich 3d Layered Oxides and LiAlO2
Published in Journal of physical chemistry. C (30-05-2019)“…Resonant inelastic X-ray scattering (RIXS) at the O K-edge is considered a prime technique to identify bulk oxidized oxygen formation, but its fundamental…”
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Surface Chemistry Dependence on Aluminum Doping in Ni-rich LiNi0.8Co0.2−yAlyO2 Cathodes
Published in Scientific reports (27-11-2019)“…Aluminum is a common dopant across oxide cathodes for improving the bulk and cathode-electrolyte interface (CEI) stability. Aluminum in the bulk is known to…”
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Stabilized iron fluoride cathodes
Published in Nature materials (01-12-2019)“…By using solid polymer electrolytes, insight into the local control of iron fluoride conversion based positive electrodes for stable next-generation lithium…”
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Direct-Write Dewetting of High Melting Temperature Metals on Flexible Substrates
Published in Applied sciences (01-08-2019)“…Microelectromechanical systems (MEMS) are pervasive in modern technology due to their reliability, small foot print, and versatility of function. While many of…”
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Subsurface diffusion of oxide electrolyte decomposition products in metal fluoride nanocomposite electrodes
Published in Electrochimica acta (01-01-2013)“…► XPS and NMR study of interactions of electrolytes with BiF3 during conversion. ► SEI decomposes during reconversion, resulting in oxyfluoride interfacial…”
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Structure, surface morphology and electrochemical properties of brominated activated carbons
Published in Carbon (New York) (01-06-2011)“…A study of the incorporation of bromine in activated carbons showed that highly reactive bromine facilitated a charge transfer reaction with the host carbon…”
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Revisiting metal fluorides as lithium-ion battery cathodes
Published in Nature materials (01-06-2021)“…Metal fluorides, promising lithium-ion battery cathode materials, have been classified as conversion materials due to the reconstructive phase transitions…”
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Silver copper fluoride: A novel perovskite cathode for lithium batteries
Published in Journal of power sources (15-09-2017)“…An electrochemically active nanostructured silver copper fluoride (SCF) perovskite, AgCuF3, was synthesized via a mechanochemical reaction between AgF and CuF2…”
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Surface Structural and Chemical Evolution of Layered LiNi0.8Co0.15Al0.05O2 (NCA) under High Voltage and Elevated Temperature Conditions
Published in Chemistry of materials (11-12-2018)“…This paper reports new insights into structural and chemical evolution of surface phases of LiNi0.8Co0.15Al0.05O2 (NCA) held at constant high voltages (up to…”
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Effect of cation and anion doping on microstructure and electrochemical properties of the LiMn1.5Ni0.5O4−δ spinel
Published in Journal of power sources (15-06-2014)“…A detailed investigation of the structural and electrochemical impact of lithium and fluorine substitutions on the 4.7 V LiMn1.5Ni0.5O4−δ (LMNO) positive…”
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Engineering high transport plastic separators for next-generation Li-ion batteries
Published in Ionics (2023)“…Benefited from their tunable porosity, bondability, high voltage stability, fast transport properties, and good electrolyte retention, plastic separators have…”
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Electrolyte-Induced Surface Transformation and Transition-Metal Dissolution of Fully Delithiated LiNi0.8Co0.15Al0.05O2
Published in Langmuir (19-09-2017)“…Enabling practical utilization of layered R3̅m positive electrodes near full delithiation requires an enhanced understanding of the complex…”
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