Search Results - "Alpers, Dirk"
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A Photoredox‐Induced Stereoselective Dearomative Radical (4+2)‐Cyclization/1,4‐Addition Cascade for the Synthesis of Highly Functionalized Hexahydro‐1H‐carbazoles
Published in Angewandte Chemie International Edition (24-01-2017)“…A stereoselective synthesis of functionalized hexahydrocarbazoles was developed based on an unprecedented photoredox‐induced dearomative radical…”
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Visible Light Mediated Aryl Migration by Homolytic C−N Cleavage of Aryl Amines
Published in Angewandte Chemie International Edition (10-09-2018)“…The photocatalytic preparation of aminoalkylated heteroarenes from haloalkylamides via a 1,4‐aryl migration from nitrogen to carbon, conceptually analogous to…”
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Photoredox‐Induced Radical 6‐exo‐trig Cyclizations onto the Indole Nucleus: Aromative versus Dearomative Pathways
Published in European journal of organic chemistry (18-04-2017)“…The investigation of photoredox‐induced intra‐ and intermolecular radical [4+2] annulations of indoles confronted us with a puzzling dichotomous behavior of…”
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A Visible Light Photocatalytic Cross-Dehydrogenative Coupling/Dehydrogenation/6[pi]-Cyclization/Oxidation Cascade: Synthesis of 12-Nitroindoloisoquinolines from 2-Aryltetrahydroisoquinolines
Published in Chemistry : a European journal (01-06-2015)“…A visible light-induced photocatalytic dehydrogenation/6π-cyclization/oxidation cascade converts 1-(nitromethyl)-2-aryl-1,2,3,4-tetrahydroisoquinolines into…”
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A Visible Light Photocatalytic Cross-Dehydrogenative Coupling/Dehydrogenation/6π-Cyclization/Oxidation Cascade: Synthesis of 12-Nitroindoloisoquinolines from 2-Aryltetrahydroisoquinolines
Published in Chemistry : a European journal (01-06-2015)“…A visible light‐induced photocatalytic dehydrogenation/6π‐cyclization/oxidation cascade converts 1‐(nitromethyl)‐2‐aryl‐1,2,3,4‐tetrahydroisoquinolines into…”
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Iridium(III) Photocatalysis: A Visible‐Light‐Induced Dearomatizative Tandem [4+2] Cyclization to Furnish Benzindolizidines
Published in Chemistry : a European journal (24-08-2015)“…A photocatalytic dearomatizative tandem [4+2] cyclization between N‐(2‐iodoethyl)indoles and a variety of alkenes leads to tri‐ and tetracyclic…”
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A Photoredox‐Induced Stereoselective Dearomative Radical (4+2)‐Cyclization/1,4‐Addition Cascade for the Synthesis of Highly Functionalized Hexahydro‐1 H ‐carbazoles
Published in Angewandte Chemie International Edition (24-01-2017)“…A stereoselective synthesis of functionalized hexahydrocarbazoles was developed based on an unprecedented photoredox‐induced dearomative radical…”
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8
High‐Throughput Optimization of Photochemical Reactions using Segmented‐Flow Nanoelectrospray‐Ionization Mass Spectrometry
Published in Angewandte Chemie International Edition (10-07-2023)“…Within the realm of drug discovery, high‐throughput experimentation techniques enable the rapid optimization of reactions and expedited generation of drug…”
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Frontispiece: A Visible Light Photocatalytic Cross-Dehydrogenative Coupling/Dehydrogenation/6π-Cyclization/Oxidation Cascade: Synthesis of 12-Nitroindoloisoquinolines from 2-Aryltetrahydroisoquinolines
Published in Chemistry : a European journal (01-06-2015)“…Cross‐Dehydrogenative Coupling The photocatalytic C1‐functionalization of 2‐aryltetrahydroisoquinolines by cross‐dehydrogenative coupling with nitroalkanes is…”
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11
Glycoconjugated Amphiphilic Polymers via Click-Chemistry for the Encapsulation of Quantum Dots
Published in Langmuir (08-10-2013)“…Herein, we present a strategy for the glycoconjugation of nanoparticles (NPs), with a special focus on fluorescent quantum dots (QDs), recently described by us…”
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High‐Throughput Optimization of Photochemical Reactions using Segmented‐Flow Nanoelectrospray‐Ionization Mass Spectrometry
Published in Angewandte Chemie (10-07-2023)“…Within the realm of drug discovery, high‐throughput experimentation techniques enable the rapid optimization of reactions and expedited generation of drug…”
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13
Photoredox‐induzierte stereoselektive desaromatisierende radikalische (4+2)‐Cyclisierungs/1,4‐Additions‐Kaskade zur Synthese hoch funktionalisierter Hexahydro‐1 H ‐carbazole
Published in Angewandte Chemie (24-01-2017)“…Eine stereoselektive Synthese funktionalisierter Hexahydrocarbazole basiert auf einer neuartigen photoredox‐induzierten desaromatisierenden radikalischen…”
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Photoredox‐induzierte stereoselektive desaromatisierende radikalische (4+2)‐Cyclisierungs/1,4‐Additions‐Kaskade zur Synthese hoch funktionalisierter Hexahydro‐1H‐carbazole
Published in Angewandte Chemie (24-01-2017)“…Eine stereoselektive Synthese funktionalisierter Hexahydrocarbazole basiert auf einer neuartigen photoredox‐induzierten desaromatisierenden radikalischen…”
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15
Arylmigration durch sichtbares Licht unter homolytischer C‐N‐Spaltung in Arylaminen
Published in Angewandte Chemie (10-09-2018)“…Die photokatalytische Synthese von aminoalkylierten Heteroaromaten aus Halogenalkylamiden gelingt durch die einer Smiles‐Umlagerung konzeptionell analogen…”
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Formation of the immunogenic alpha 1,3-fucose epitope: Elucidation of substrate specificity and of enzyme mechanism of core fucosyltransferase A
Published in Insect biochemistry and molecular biology (01-02-2012)“…Glycans of glycoproteins are often associated with IgE mediated allergic immune responses. Hymenoptera venoms, e.g., carry alpha 1,3-fucosyl residues linked to…”
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Formation of the immunogenic α1,3-fucose epitope: Elucidation of substrate specificity and of enzyme mechanism of core fucosyltransferase A
Published in Insect biochemistry and molecular biology (01-02-2012)“…Glycans of glycoproteins are often associated with IgE mediated allergic immune responses. Hymenoptera venoms, e.g., carry α1,3-fucosyl residues linked to the…”
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Photoredox-induzierte stereoselektive desaromatisierende radikalische (4+2)-Cyclisierungs/1,4-Additions-Kaskade zur Synthese hoch funktionalisierter Hexahydro-1H-carbazole
Published in Angewandte Chemie (24-01-2017)“…Eine stereoselektive Synthese funktionalisierter Hexahydrocarbazole basiert auf einer neuartigen photoredox-induzierten desaromatisierenden radikalischen…”
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