Search Results - "Allonas, Xavier"
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Progress in the development of polymeric and multifunctional photoinitiators
Published in Progress in polymer science (01-12-2019)“…[Display omitted] UV-curing technology has been developed and widely used in industry for 6 decades. However, the migration of low-molecular-weight…”
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Experimental and theoretical investigations of free radical photopolymerization: Inhibition and termination reactions
Published in Polymer (Guilford) (03-01-2019)“…In this work, the inhibition and termination reactions occurring throughout a free radical photopolymerization initiated by a type-I photoinitiator are studied…”
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Fluorinated organozirconiums: Enhancement of overcoming oxygen inhibition in the UV-curing film
Published in Progress in organic coatings (01-07-2018)“…[Display omitted] •Novel fluorinated organozirconiums have been synthesized via a facile ligand substitution reaction.•Fluorinated organozirconiums can…”
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Versatility of Pyrylium Salt/Vinyl Ether Initiating System for Epoxide Dual‐Cure Polymerization: Kick‐Starting Effect of the Coinitiator
Published in Macromolecular rapid communications. (01-07-2017)“…Pyrylium salts combined with vinyl ethers are shown to act as new versatile dual‐cure initiating systems for both photochemical and thermal initiation of…”
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Exploration of the PET‐RAFT Initiation Mechanism for Two Commonly Used Photocatalysts
Published in ChemPhotoChem (01-11-2019)“…An investigation into the PET‐RAFT initiation mechanism (photoinduced electron/energy transfer‐reversible addition‐fragmentation chain transfer) for two…”
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Panchromatic Type II Photoinitiator for Free Radical Polymerization Based on Thioxanthone Derivative
Published in Macromolecules (14-05-2013)“…A new photoinitiator for free radical photopolymerization, belonging to the thioxanthone derivatives, was synthesized and characterized. It was found that the…”
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Analysis of Acrylic and Methacrylic Networks through Pyrolysis-GC/MS
Published in Polymers (12-12-2021)“…A direct analytical method developed to characterize UV-cured networks based on multi-step pyrolysis-gas chromatography-mass spectroscopy (GC/MS) is presented…”
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Spectroscopic Studies of the Interactions between a Cationic Cyanine Dye and a Synthetic Phyllosilicate: From Photophysics to Hybrid Materials
Published in Langmuir (11-07-2017)“…The interaction of the cationic organic dye Astrazon orange R (AO-R) with the synthetic phyllosilicate Laponite leads to very interesting hybrid materials…”
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A new safranin based three-component photoinitiating system for high resolution and low shrinkage printed parts via digital light processing
Published in RSC advances (02-12-2019)“…Additive manufacturing or 3D printing has attracted the interest of researchers in industry and academia because of its outstanding features. In this study, a…”
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On-Demand Photopolymerization of Fiber-Reinforced Polymers Exhibiting the Shape Memory Effect
Published in Polymers (09-12-2021)“…Fiber-reinforced polymers exhibiting the shape memory effect were created on the basis of a one-pot three-step chemical process. The first step is a Michael…”
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Novel Dual-Cure Initiating System for Cationic Polymerization of Epoxides
Published in Macromolecular chemistry and physics (01-05-2016)“…Pyrylium salts are found to be effective initiators for both photochemical and thermal cationic polymerization of epoxy resin. The photopolymerization results…”
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Dyes as Photoinitiators or Photosensitizers of Polymerization Reactions
Published in Materials (02-12-2010)“…A short but up-to-date review on the role of dyes in the photoinitiation processes of polymerization reactions is presented. Radical and cationic reactions are…”
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Confocal Raman microscopy study of several factors known to influence the oxygen inhibition of acrylate photopolymerization under LED
Published in Progress in organic coatings (01-03-2016)“…•Effect of physical and chemical factors known to participate in reducing O2 inhibition in FRP Depth conversion profile Confocal Raman microscopy.•An increase…”
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One-Pot Three-Step Polymerization System Using Double Click Michael Addition and Radical Photopolymerization
Published in ACS macro letters (15-12-2015)“…A click chemistry synthetic strategy based on aza-Michael addition and radical photopolymerization is proposed to generate a polymeric network via three…”
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Electron Spin Resonance Spin Trapping Technique: Application to the Cleavage Process of Photoinitiators
Published in Macromolecular chemistry and physics (06-11-2008)“…The cleavage of different photoinitiators (PIs) of polymerization is investigated by the ESR spin trapping using two different spin traps (STs):…”
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Photoinduced Cross-Linking of Dynamic Poly(disulfide) Films via Thiol Oxidative Coupling
Published in Macromolecular rapid communications. (01-01-2016)“…Initially developed as an elastomer with an excellent record of barrier and chemical resistance properties, poly(disulfide) has experienced a revival linked to…”
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Tris(trimethylsilyl)silyl versus tris(trimethylsilyl)germyl: Radical reactivity and oxidation ability
Published in Journal of organometallic chemistry (15-11-2008)“…A comparison of the tris(trimethylsilyl)silyl I and tris(trimethylsilyl)germyl II radical reactivity is provided. A large variety of chemical processes…”
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Optimization of a Safranine O three-component photoinitiating system for use in holographic recording
Published in Canadian journal of chemistry (01-12-2015)“…The coupling between a holographic resin, combining multiple monomers and additives, with photoinitiating systems (PIS) is not straightforward. In this paper,…”
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Role of the Medium on the Reactivity of Cleavable Photoinitiators in Photopolymerization Reactions
Published in Macromolecules (07-03-2006)“…The efficiency of 11 cleavable photoinitiators in polymerization reactions was determined in various media, such as oligomer, acrylate, and methacrylate…”
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Photochemistry of Naphthalimide Photoacid Generators
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (01-05-2008)“…The photophysical properties of a series of 1,8-naphthalimide photoacid generators were studied by steady state fluorescence and phosphorescence spectroscopy…”
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