Search Results - "Albores, Pablo"
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Single Molecule Magnet Features in the Butterfly [CoIII2LnIII2] Pivalate Family with Alcohol‐Amine Ligands
Published in European journal of inorganic chemistry (20-08-2021)“…We are reporting the synthesis and structural characterization of a new family of butterfly complexes with formula [Co2IIILn2III−(μ3−(OR))2] where −OR is an…”
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2
A New Strategy for Neurochemical Photodelivery: Metal−Ligand Heterolytic Cleavage
Published in Journal of the American Chemical Society (29-01-2003)“…A new strategy to build caged-compounds is presented. The approach is based on heterolytic photocleavage of a metal−ligand bond in a coordination compound. A…”
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3
Communication between Remote Moieties in Linear Ru–Ru–Ru Trimetallic Cyanide-Bridged Complexes
Published in Inorganic chemistry (18-03-2013)“…In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts…”
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A convenient synthesis of a 2,7-difunctional tetra(alkoxy)triphenylene involving 4,4′-diacetoxy-3,3′-dialkoxybiphenyl as a key precursor and its conversion to extended hybrid mesogenic compounds
Published in Liquid crystals (01-08-2013)“…A new rational pathway to 2,7-difunctionalised-β-hexa-substituted triphenylenes is presented, requiring less protection/deprotection and purification steps…”
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5
Slow relaxation of magnetization in the Co(II)‐phosphotungstate Keggin polyoxometalate
Published in European journal of inorganic chemistry (12-03-2024)“…We are reporting the single crystal structure of the tetrabutylammonium (TBA) salt of the old Co(II) Keggin phosphotungstate anion (Co(II)POM) and a study of…”
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6
Direct CH Metalation with Chromium(II) and Iron(II): Transition‐Metal Host / Benzenediide Guest Magnetic Inverse‐Crown Complexes
Published in Angewandte Chemie International Edition (20-04-2009)“…Check M(etal)ate: The chessboard and the figures represent a special reaction in which different low‐polarity metals can metalate arenes directly when they are…”
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7
A Co 36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3‐Dicarboxypyrazine
Published in Angewandte Chemie International Edition (23-11-2009)Get full text
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8
Recent Developments in CoIII2LnIII2 Single‐Molecule Magnets
Published in European journal of inorganic chemistry (07-06-2018)“…In this work we review the Co2IIILn2III family of compounds reported up to date that shows SMM features. The vast majority of them show a butterfly arrangement…”
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Synthesis and Characterization of New Mononuclear Ru (II) PolypyridylComplexes with Catalytic Activity
Published in European journal of inorganic chemistry (01-06-2023)“…In this work, we report the synthesis and physicochemical characterization of new chloro and aqua mononuclear Ru (II) complexes of formula [Ru(LLL)(dpp)Cl]PF6…”
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10
Class III Delocalization in a Cyanide-Bridged Trimetallic Mixed-Valence Complex
Published in Angewandte Chemie International Edition (27-01-2014)“…The NIR and IR spectroscopic properties of the cyanide‐bridged complex, trans‐[Ru(dmap)4{(μ‐CN)Ru(py)4Cl}2]3+ (py=pyridine, dmap=4‐dimethylaminopyridine)…”
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11
SMM Behaviour of the Butterfly {CrIII2DyIII2} Pivalate Complex and Magneto‐structurally Correlated Relaxation Thermal Barrier
Published in Chemistry : a European journal (21-10-2022)“…We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2}…”
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12
Crystal Structure and Electronic and Magnetic Properties of Hexacyanoosmate(III)
Published in Inorganic chemistry (20-03-2006)“…The [OsIII(CN)6]3- anion is prepared by chemical oxidation in aqueous solution and isolated as yellow prisms of [Ph4P]3[OsIII(CN)6]·6H2O (1). This species…”
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13
Tailoring the Exchange Interaction in Covalently Linked Basic Carboxylate Clusters through Bridging Ligand Selection
Published in Inorganic chemistry (06-08-2012)“…We are reporting new dimeric units of basic carboxylates bearing the {FeIII 2MIIO} motif for M = Co and Ni, covalently bound through the tetradentate bridging…”
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14
Structural and Magnetic Characterization of a μ-1,5-Dicyanamide-Bridged Iron Basic Carboxylate [Fe3O(O2C(CH3)3)6] 1D Chain
Published in Inorganic chemistry (15-09-2008)“…We are reporting an unprecedented example of a μ-1,5-dicyanamide (dca)-bridged iron basic carboxylate, [Fe3O(O2C(CH3)3)6], 1D chain. As revealed from X-ray…”
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15
Electronic Energy Transduction from {Ru(py)4} Chromophores to Cr(III) Luminophores
Published in Inorganic chemistry (19-03-2018)“…Despite the large body of work on {Ru(bpy)2} sensitizer fragments, the same attention has not been devoted to their {Ru(py)4} analogues. In this context, we…”
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Exploring the Slow Relaxation of the Magnetization in CoIII-Decorated {DyIII2} Units
Published in Chemistry : a European journal (26-09-2016)“…We have prepared and structurally characterized a new member of the butterfly‐like {CoIII2DyIII2} single‐molecule magnets (SMMs) through further CoIII…”
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Expanding the 2,2'-bipyrimidine bridged 1D homonuclear coordination polymers family: [M(II)(bpym)Cl2] (M = Fe, Co) magnetic and structural characterization
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2013)“…One pot reaction of hydrated chloride salts of Fe(II) and Co(II) with stoichiometric amounts of 2,2'-bipyrimidine (bpym) in a methanol-acetonitrile mixture…”
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Structural and magnetic characterization of a 1D chain of [Co(II)2(mu-aqua)(mu-carboxylate)2] strung cores
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2009)“…A novel 1D chain built up from stringing of [Co2(mu-OH2)(mu-O2CC(CH3)3)2] units with the bridging 2,2'-bipyrimidine ligand has been synthesized and…”
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Remarkable Changes of the Acidity of Bound Nitroxyl (HNO) in the [Ru(Me3[9]aneN3)(L2)(NO)] n+ Family (n = 1–3). Systematic Structural and Chemical Exploration and Bioinorganic Chemistry Implications
Published in Inorganic chemistry (01-10-2018)“…This work demonstrates that the acidity of nitroxyl (HNO) coordinated to a metal core is significantly influenced by its coordination environment. The…”
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cis-2,2′-Bipyrimidine-Bridged Polynuclear Complex: A Stairway-like Mixed-Valent {Fe4} Cluster
Published in Inorganic chemistry (04-10-2010)“…We report the first example of a polynuclear discrete coordination compound exhibiting only bpym bridges and containing a first-row d transition metal. A…”
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