Search Results - "Akturk, Eser S"

Mechanism-based design of labile precursors for chromium(I) chemistry by Akturk, Eser S, Yap, Glenn P A, Theopold, Klaus H

“…Dinitrogen complexes of the type Tp(R,R)Cr-N2-CrTp(R,R) are not the most labile precursors for Cr(i) chemistry, as they are sterically protected from…”
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Synthesis of Sterically Hindered β‑Diketones via Condensation of Acid Chlorides with Enolates by Crossman, Aaron S, Larson, Alec T, Shi, Jake X, Krajewski, Sebastian M, Akturk, Eser S, Marshak, Michael P

“…Bulky β-diketones have rarely exceeded dipivaloylmethane (DPM) in steric demand, largely due to synthetic limitations of the Claisen condensation. This work…”
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Bulky β‑Diketones Enabling New Lewis Acidic Ligand Platforms by Akturk, Eser S, Scappaticci, Steven J, Seals, Rachel N, Marshak, Michael P

“…The synthesis of a sterically encumbered β-diketone ligand (Aracac) substituted with 2,6-(2,4,6-Me3C6H2)2C6H3 is described. Coordination complexes of the type…”
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Dioxygen Activation by Non-Adiabatic Oxidative Addition to a Single Metal Center by Akturk, Eser S., Yap, Glenn P. A., Theopold, Klaus H.

“…A chromium(I) dinitrogen complex reacts rapidly with O2 to form the mononuclear dioxo complex [TptBu,MeCrV(O)2]…”
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Improved syntheses, and structural and electronic characterization of carboxamide-substituted Tp(CONHPh,Me) and Tp(CONHt-Bu,Me) ligands by Sirianni, Eric R, Yap, Glenn P A, Akturk, Eser S, Theopold, Klaus H

“…Improvements in the syntheses of the carboxamide-substituted tris(pyrazolyl)borate ligands Tp(CONHPh,Me) [tris(3-anilinocarbonyl-5-methylpyrazol-1-yl)borate]…”
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Dioxygen Activation by Non-Adiabatic Oxidative Addition to a Single Metal Center by Akturk, Eser S., Yap, Glenn P. A., Theopold, Klaus H.

“…A chromium(I) dinitrogen complex reacts rapidly with O2 to form the mononuclear dioxo complex [TptBu,MeCrV(O)2]…”
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Improved syntheses, and structural and electronic characterization of carboxamide-substituted TpCONHPh,Me and TpCONHt-Bu,Me ligands by Sirianni, Eric R., Yap, Glenn P. A., Akturk, Eser S., Theopold, Klaus H.

“…Improvements in the syntheses of the carboxamide‐substituted tris(pyrazolyl)borate ligands TpCONHPh,Me [tris(3‐anilinocarbonyl‐5‐methylpyrazol‐1‐yl)borate] and…”
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Mechanistic investigation of iron-catalyzed cross-coupling using sterically encumbered β-diketonate ligands by Scappaticci, Steven J., Crossman, Aaron S., Larson, Alec T., Maharaj, Franklin D.R., Akturk, Eser S., Marshak, Michael P.

“…A Kumada cross-coupling reaction catalyzed by iron acac was investigated using bulky acac ligands. Experimental data and DFT calculations support oxidative…”
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O2 Activation by Non-adiabatic Oxidative Addition to a Single Metal Center by Akturk, Eser. S., Yap, Glenn P. A., Theopold, Klaus H.

“…A chromium(I) dinitrogen complex reacts rapidly with O 2 to form the mononuclear dioxo complex Tp t Bu,Me Cr V (O) 2 , whereas the analogous reaction with…”
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Improved syntheses, and structural and electronic characterization of carboxamide-substituted Tp CONHPh,Me and Tp CONH t -Bu,Me ligands by Sirianni, Eric R., Yap, Glenn P. A., Akturk, Eser S., Theopold, Klaus H.

“…Improvements in the syntheses of the carboxamide-substituted tris(pyrazolyl)borate ligands Tp CONHPh,Me [tris(3-anilinocarbonyl-5-methylpyrazol-1-yl)borate]…”
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