Fabrication of hydrazine sensor based on silica-coated Fe2O3 magnetic nanoparticles prepared by a rapid microwave irradiation method

Fabrication of hydrazine sensor based on silica-coated Fe2O3 magnetic nanoparticles prepared by a rapid microwave irradiation method

A facile, efficient and rapid method for fabrication of silica-coated Fe2O3 magnetic nanoparticles (NPs) by a microwave (MW) irradiation method is reported. The homogeneous heating produced by the MW irradiation is the key to attaining the effective and uniform coating on Fe2O3 magnetic nanoparticle...

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Bibliographic Details
Published in:Journal of alloys and compounds Vol. 698; pp. 921 - 929
Main Authors: Akhter, Hashi, Murshed, Jannatul, Rashed, Md. A., Oshima, Yoshifumi, Nagao, Yuki, Rahman, Mohammed M., Asiri, Abdullah M., Hasnat, M.A., Uddin, Md. Nizam, Siddiquey, Iqbal Ahmed
Format: Journal Article
Language:English
Published: Lausanne Elsevier B.V 25-03-2017
Elsevier BV
Subjects:
Carcinogens
Coating effects
Ethanol
Glassy carbon
Hematite
Hydrazine
Iron oxides
Irradiation
Magnetic materials
Microwave heating
Nanoparticles
Sensitivity
Sensor
Sensors
Silica coating
Silicon dioxide
Sol-gel preparation
Zeta potential
Sol-gel preparation
Magnetic materials
Silica coating
Microwave heating
Hydrazine
Sensor
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Summary:A facile, efficient and rapid method for fabrication of silica-coated Fe2O3 magnetic nanoparticles (NPs) by a microwave (MW) irradiation method is reported. The homogeneous heating produced by the MW irradiation is the key to attaining the effective and uniform coating on Fe2O3 magnetic nanoparticles (NPs) in water-ethanol solution. HRTEM images confirmed the successful formation of uniform silica shells around the Fe2O3 NPs surface whereas FT-IR data show the structural differences between non-coated and silica-coated Fe2O3 NPs. These uniformly coated Fe2O3 NPs showed superior dispersibility than the bare Fe2O3 NPs as confirmed by the zeta potential measurements. For potential chemical sensor development, silica-coated Fe2O3 magnetic NPs were deposited onto a flat glassy carbon electrode (GCE, surface area, 0.0316 cm2) to give a sensor with a fast response against selective hydrazine in phosphate buffer phase. Hydrazine sensor also exhibits a good sensitivity with long-term stability and enhanced electrochemical performances. The calibration plot is linear (r2: 0.9911) over the 0.2 nM to 2.0 mM hydrazine concentration ranges. The sensitivity and detection limit are ∼12.658 μAmM−1cm−2 and 76.0 pM (signal-to-noise ratio, at a SNR of 3) respectively. It is also commenced a promising future sensitive sensor development using silica-coated Fe2O3 magnetic NPs by I-V method for the important applications of hazardous and carcinogenic compounds in environmental fields. [Display omitted] •Silica coated Fe2O3 nanoparticles were prepared by a fast MW assisted method.•Fe2O3 nanoparticles were uniformly coated with SiO2 by microwave irradiation.•The smooth silica shell enhanced the dispersibility of the Fe2O3 nanoparticles.•Fe2O3@SiO2 sensor showed good sensitivity and selectivity towards hydrazine.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2016.12.266