Search Results - "Akella, Sarma V S"
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Total Synthesis and Structural Revision of Greensporone F and Dechlorogreensporone F
Published in Journal of organic chemistry (02-10-2020)“…The first asymmetric total syntheses of the real isolation product (2S,5R,8R)-greensporone F and (2S,5R,8R)-dechlorogreensporone F, 14-membered resorcylic acid…”
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2
Versatile Intramolecular Aza-Prins and Prins Cyclization of Aryl Epoxides: A Facile Synthesis of Diaza-, Oxa-aza-, and Dioxa-bicycles
Published in Journal of organic chemistry (19-03-2010)“…Aryl epoxides undergo coupling smoothly with (E)-hex-3-ene-1,6-ditosylamide in the presence of 10 mol % p-TSA in 1,2-dichloroethane at 75 °C to produce the…”
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3
Three-Component Reaction of Aldose Sugars, Aryl Amines, and 1,3-Diones: A Novel Synthesis of Annulated Pyrroles
Published in Journal of organic chemistry (18-04-2008)“…Aldose sugars undergo smooth coupling with enamines, generated in situ from aryl amines and 1,3-diketones, in the presence of 10 mol % of InCl3 in water at 80…”
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4
Investigation of Anion−π Interactions Involving Thiophene Walls Incorporated Calix[4]pyrroles
Published in Journal of organic chemistry (06-02-2015)“…Thiophene containing “two-wall” aryl extended calix[4]pyrroles were synthesized for the first time, through acid catalyzed condensation of 2-acetylthiophenes…”
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5
Solvent-Directed Switch of a Left-Handed 10/12-Helix into a Right-Handed 12/10-Helix in Mixed β‑Peptides
Published in Journal of organic chemistry (17-02-2017)“…Present study describes the synthesis and conformational analysis of β-peptides from C-linked carbo-β-amino acids [β-Caa(l)] with a d-lyxo furanoside side…”
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Epimeric Excolides from the Stems of Excoecaria agallocha and Structural Revision of Rhizophorin A
Published in Organic letters (05-06-2015)“…Excolides A–B (1–4) represent the first examples of a new class of secolabdanoids with an unprecedented framework, which were isolated from the stems of…”
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7
Quantifying sodium in the human wrist in vivo by using MR imaging
Published in Radiology (01-08-2002)“…The authors quantified sodium content in the wrist joints of six healthy volunteers with no known history of arthritis or pain. Average sodium concentrations…”
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8
Multiple Ligand-Bound States of a Phosphohexomutase Revealed by Principal Component Analysis of NMR Peak Shifts
Published in Scientific reports (13-07-2017)“…Enzymes sample multiple conformations during their catalytic cycles. Chemical shifts from Nuclear Magnetic Resonance (NMR) are hypersensitive to conformational…”
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9
Design and Synthesis of Peptides with Hybrid Helix-Turn-Helix (HTH) Motif and Their Conformational Study
Published in Journal of organic chemistry (19-09-2014)“…The present study is aimed at the design and synthesis of peptides with hybrid helix-turn-helix (HTH) motif and their conformational analysis (NMR, MD, and CD…”
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10
Proteoglycan loss in human knee cartilage: quantitation with sodium MR imaging--feasibility study
Published in Radiology (01-06-2004)“…The feasibility of using sodium magnetic resonance (MR) imaging to detect proteoglycan loss in early-stage osteoarthritis is evaluated. Fixed charge density…”
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11
Chemical shift assignments of domain 4 from the phosphohexomutase from Pseudomonas aeruginosa suggest that freeing perturbs its coevolved domain interface
Published in Biomolecular NMR assignments (01-10-2014)“…A domain needed for the catalytic efficiency of an enzyme model of simple processivity and domain–domain interactions has been characterized by NMR. This…”
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12
Influence of sulphonation on Al-MCM-41 catalyst for effective bio-glycerol conversion to Solketal
Published in Microporous and mesoporous materials (01-01-2024)“…Al-MCM-41 and sulphate modified Al-MCM-41 catalysts with variable sulphate loadings (0.25-1SAM) were synthesized through sol-gel and impregnation techniques…”
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13
Solution NMR of a 463-Residue Phosphohexomutase: Domain 4 Mobility, Substates, and Phosphoryl Transfer Defect
Published in Biochemistry (Easton) (24-01-2012)“…Phosphomannomutase/phosphoglucomutase contributes to the infectivity of Pseudomonas aeruginosa, retains and reorients its intermediate by 180°, and rotates…”
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6‐Strand to Stable 10/12 Helix Conformational Switch by Incorporating Flexible β‐hGly in the Homooligomers of Camphor Derived β‐Amino Acid: NMR and X‐Ray Crystallographic Evidence
Published in Angewandte Chemie International Edition (27-05-2024)“…Rational design of unnatural amino acid building blocks capable of stabilizing predictable secondary structures similar to protein fragments is pivotal for…”
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15
Methane conversion to H2 and carbon nanofibers over supported Ni catalysts: A sustainable process through utilization of deactivated catalysts
Published in Environmental progress & sustainable energy (01-01-2024)“…The renewable resource such as rice husk has been utilized to synthesize Hβ zeolite as a support for Ni catalysts for the production of clean hydrogen and…”
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16
An innovative in situ method of creating hybrid dendrimer nano-assembly: An efficient next generation dendritic platform for drug delivery
Published in Nanomedicine (01-10-2019)“…Dendrimers have proven to be effective for drug delivery and their biodisposition varies with change on their surface, generation and core. In an effort to…”
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17
Synthesis of rebaudioside-A by enzymatic transglycosylation of stevioside present in the leaves of Stevia rebaudiana Bertoni
Published in Food chemistry (01-06-2016)“…•Enzyme mediated transglycosylation of stevioside to rebaudioside-A.•The glucosyl moiety transglycosylated stereospecifically to get 13-O-β-stevioside.•The…”
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18
Diphenic Acid as a General Conformational Lock in the Design of Bihelical Structures
Published in Chemistry : a European journal (01-01-2007)“…The bihelical (figure of “∞”) topology was examined from vantages of design, crystal structures, chirality, circular dichroism (CD) studies and…”
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6‐Strand to Stable 10/12 Helix Conformational Switch by Incorporating Flexible β‐hGly in the Homooligomers of Camphor Derived β‐Amino Acid: NMR and X‐Ray Crystallographic Evidence
Published in Angewandte Chemie (27-05-2024)“…Rational design of unnatural amino acid building blocks capable of stabilizing predictable secondary structures similar to protein fragments is pivotal for…”
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20
Design and synthesis of trans-3-aminopyran-2-carboxylic acid (APyC) and α/β-peptides with 9/11-helix
Published in Organic & biomolecular chemistry (07-12-2011)“…A new β-amino acid, trans-3-aminopyran-2-carboxylic acid (APyC), was designed and synthesized from (R)-glyceraldehyde derivative and used in the synthesis of…”
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