Search Results - "Agrifoglio, Giuseppe"
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Room Temperature Liquid Salts of Cr and Mo as Self-Supported Oxidants
Published in Advanced synthesis & catalysis (01-02-2005)“…Room temperature liquid salts of Cr and Mo were synthesized and fully characterized including cyclic voltammetry of the neat Mo salt. These liquid salts were…”
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(Z)-4-(2,5-Di-tert-butyl-anilino)pent-3-en-2-one
Published in Acta crystallographica. Section E, Structure reports online (01-06-2011)“…In the crystal structure of the title ketoamine, C(19)H(29)NO, the bond lengths from the N atom through the alkene group to the ketone O atom show the presence…”
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2,6-Bis[1-(2-isopropyl-phenyl-imino)-ethyl]-pyridine
Published in Acta crystallographica. Section E, Structure reports online (01-01-2008)“…The title compound, C(27)H(31)N(3), has E substitution at each imine double bond where the two N atoms adopt a trans-trans relationship. The benzene rings are…”
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C 2 and C 1 ‐Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (16-10-2023)“…Abstract Dioxomolybdenum(VI) complexes ( 1 ‐ 6 ) were prepared in good yields (≥79 %) using enantiopure C 2 and C 1 ‐symmetric bidentate N,N‐ligands ( L 1 ‐ L…”
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C2 and C1‐Symmetric Camphopyrazole Dioxomolybdenum(VI) Complexes catalyze the Epoxidation of Cyclic Olefins
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (16-10-2023)“…Dioxomolybdenum(VI) complexes (1‐6) were prepared in good yields (≥79 %) using enantiopure C2 and C1‐symmetric bidentate N,N‐ligands (L1‐L6) derived from…”
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Ruthenium (II) complexes with C2- and C1-symmetric bis-(+)-camphopyrazole ligands and their evaluation in catalytic transfer hydrogenation of aldehydes
Published in Inorganica Chimica Acta (01-09-2021)“…[Display omitted] •The synthesis of two new chiral bis-(+)-camphopyrazole ligands is reported.•Five piano-stool ruthenium(II) complexes with camphopyrazole…”
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(4 R )-3-Hydroxy-7-isopropyl-4-methyl-5,6-dihydrobenzofuran-2(4 H )-one
Published in Acta crystallographica. Section E, Structure reports online (01-07-2014)“…In the title compound, alternatively called α-hydroxy-γ-alkylidenebutenolide, C 12 H 16 O 3 , two independent molecules ( A and B ) crystallize in the…”
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“Chiral-at-Metal” Hemilabile Nickel Complexes with a Latent d10-ML2 Configuration: Receiving Substrates with Open Arms
Published in Organometallics (10-09-2012)“…Complexes with highly reactive stereogenic metal centers are of great interest to asymmetric synthesis. Thus, by reacting [Ni(COD)2] with 2 equiv of the…”
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Camphopyrazole-based N,N- and N,P-ligands and chiral complexes of Ni, Pd, and Rh: P–N bond activation upon Rh(I) complexation
Published in Tetrahedron: asymmetry (01-09-2016)“…[Display omitted] Enantiomerically pure C1 and C2-symmetric bidentate N,N- and N,P-ligands are accessible from (+)-camphor in good yields (60–90%). Modified…”
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Camphorpyrazolium-based chiral functional ionic liquids
Published in Tetrahedron: asymmetry (15-10-2014)“…The solvent-less quaternization of N-phenyl-camphorpyrazole 4 with BrC4H9, IC2H4OCH3, and IC2H4OC2H4OC4H9 afforded the corresponding chiral pyrazolium halides…”
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( E )-3-(1-Naphthylamino)methylene-(+)-camphor
Published in Acta crystallographica. Section E, Structure reports online (01-01-2011)“…In the crystal structure of the title ketoamine {systematic name: (E)-1,7,7-trimethyl-3-[(1-naphthylamino)methylidene]bicyclo[2.2.1]heptan-2-one}, C21H23NO,…”
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“Chiral-at-Metal” Hemilabile Nickel Complexes with a Latent d 10 -ML 2 Configuration: Receiving Substrates with Open Arms
Published in Organometallics (10-09-2012)Get full text
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Resolution of (±)-Bicyclo[2.2.1]hept-5-ene-trans-2,3-dicarboxylic Acid: Crystal Structure of Its Cinchoninium Salt
Published in Journal of chemical crystallography (01-04-2016)“…Single crystals of (+)-cinchoninium (+)-bicyclo[2.2.1]hept-5-ene- trans -2-carboxyl-3-carboxylate (S,S) - 2 were obtained upon resolution of racemic…”
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Oxygen atom transfer photocatalyzed by molybdenum(VI) dioxodibromo-(4,4′-dicarboxylate-2,2′-bipyridine) anchored on TiO2
Published in Catalysis today (01-04-2008)Get full text
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Characterization of a reduced molybdenum-oxo compound derived from an oxo-transfer process under stoichiometric conditions
Published in Journal of molecular catalysis. A, Chemical (15-12-2006)“…The stoichiometric oxidation of phosphanes or alcohols by a Mo(VI) dioxo complex ( 1) followed both by UV spectroscopy results in the formation of a Mo (V)…”
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Synthesis, characterization and olefin polymerization studies of iron(II) and cobalt(II) catalysts bearing 2,6-bis(pyrazol-1-yl)pyridines and 2,6-bis(pyrazol-1-ylmethyl)pyridines ligands
Published in Applied catalysis. A, General (08-03-2005)“…The complexes Py(PzR 3) 2MCl 2 (R = H, Me; M = Fe, Co) and Py(CH 2 PzR 3) 2MCl 2 (R = H, Me; M = Fe, Co) have been synthesized, characterized and used in the…”
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Synthesis and Characterization of Halo, Cyanato, Thiocyanato and Selenocyanato Molybdenum(VI) Dioxo and Dioxo-μ-oxo Complexes
Published in Transition metal chemistry (Weinheim) (01-08-2006)Get full text
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Theoretical study of olefin oxidation process on a dioxo-μ-oxo Mo catalyst
Published in International journal of quantum chemistry (2008)“…The dimeric complex dioxo (μ‐oxo) thiocyanato of molybdenum(VI) bearing a 4,4′‐di‐ter‐butyl‐2,2′‐bipyridine ligand in trans conformation (complex 1) has been…”
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