Search Results - "Agarwal, Rishi"

Determining Proton-Coupled Standard Potentials and X-H Bond Dissociation Free Energies in Nonaqueous Solvents Using Open-Circuit Potential Measurements by Wise, Catherine F, Agarwal, Rishi G, Mayer, James M

“…Proton-coupled electron transfer (PCET) reactions are increasingly being studied in nonaqueous conditions, where the thermochemistry of PCET substrates is…”
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Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications by Agarwal, Rishi G, Coste, Scott C, Groff, Benjamin D, Heuer, Abigail M, Noh, Hyunho, Parada, Giovanny A, Wise, Catherine F, Nichols, Eva M, Warren, Jeffrey J, Mayer, James M

“…We present an update and revision to our 2010 review on the topic of proton-coupled electron transfer (PCET) reagent thermochemistry. Over the past decade, the…”
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Nanoparticle O–H Bond Dissociation Free Energies from Equilibrium Measurements of Cerium Oxide Colloids by Agarwal, Rishi G, Kim, Hyun-Jo, Mayer, James M

“…A novel equilibrium strategy for measuring the hydrogen atom affinity of colloidal metal oxide nanoparticles is presented. Reactions between oleate-capped…”
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Coverage-Dependent Rate-Driving Force Relationships: Hydrogen Transfer from Cerium Oxide Nanoparticle Colloids by Agarwal, Rishi G., Mayer, James M.

“…Rate-driving force relationships, known as Brønsted–Evans–Polanyi (BEP) relations, are central to many methods for predicting the performance of heterogeneous…”
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Correction to “Coverage-Dependent Rate-Driving Force Relationships: Hydrogen Transfer from Cerium Oxide Nanoparticle Colloids” by Agarwal, Rishi G., Mayer, James M.

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Inverse kinetic isotope effects in the oxygen reduction reaction at platinum single crystals by Yang, Yao, Agarwal, Rishi G., Hutchison, Phillips, Rizo, Rubén, Soudackov, Alexander V., Lu, Xinyao, Herrero, Enrique, Feliu, Juan M., Hammes-Schiffer, Sharon, Mayer, James M., Abruña, Héctor D.

“…Although the oxygen reduction reaction (ORR) involves multiple proton-coupled electron transfer processes, early studies reported the absence of kinetic…”
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Redox Reactivity of Colloidal Nanoceria and Use of Optical Spectra as an In Situ Monitor of Ce Oxidation States by Damatov, Delina, Laga, Stephanie M, Mader, Elizabeth A, Peng, Jing, Agarwal, Rishi G, Mayer, James M

“…Nanoscale cerium oxide is of increasing interest in catalysis, biomedicine, renewable energy, and many other fields. Its versatility derives from the ability…”
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Correction to Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications by Agarwal, Rishi G, Wise, Catherine F, Warren, Jeffrey J, Mayer, James M

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A Compressed Sensing Approach to Pooled RT-PCR Testing for COVID-19 Detection by Ghosh, Sabyasachi, Agarwal, Rishi, Rehan, Mohammad Ali, Pathak, Shreya, Agarwal, Pratyush, Gupta, Yash, Consul, Sarthak, Gupta, Nimay, Ritika, Goenka, Ritesh, Rajwade, Ajit, Gopalkrishnan, Manoj

“…We propose 'Tapestry', a single-round pooled testing method with application to COVID-19 testing using quantitative Reverse Transcription Polymerase Chain…”
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Pituitary apoplexy secondary to dengue fever-induced-thrombocytopenia: A case report and review of literature by Agarwal, Rishi, Nehara, Hardeva, Meena, Babulal, Agrawal, R

“…Rationale: Pituitary apoplexy (PA) is a rare endocrine emergency that requires prompt diagnosis and management. Dengue fever-induced-thrombocytopenia may…”
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Single-injection thoracic paravertebral block and postoperative analgesia after mastectomy: a retrospective cohort study by Agarwal, Rishi R., MD, Wallace, Anne M., MD, Madison, Sarah J., MD, Morgan, Anya C., MA, CCRC, Mascha, Edward J., PhD, Ilfeld, Brian M., MD, MS

“…Abstract Background The treatment of postoperative pain after mastectomy is an area of increasing interest, as this treatment option is now considered a…”
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Impact of ovarian endometrioma on assisted reproduction outcomes by Gupta, Sajal, Agarwal, Ashok, Agarwal, Rishi, de Mola, J Ricardo Loret

“…The effects of ovarian endometrioma on fertility outcomes with IVF and embryo transfer have been causally related to poor outcomes. The objective of this…”
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Results From an All Wales Trainee Led Collaborative Prospective Audit on Management of Ankle Fractures by Gokhale, Sandeep, D'sa, Prashanth, Agarwal, Rishi, Clutton, Juliet, Roy, Kunal, Carpenter, Eleanor Clare, Mohanty, Khitish, Hodgson, Paul

“…Aim The purpose of this all Wales national audit was to compare compliance against British Orthopedic Association Standards for Trauma (BOAST) guidelines on…”
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Kyphoplasty for the treatment of an atypical osteoporotic vertebral compression fracture of the lumbar spine: A case report by Kumar, Sanjeev, Anijar, Leon, Agarwal, Rishi

“…Vertebral augmentation is a minimally invasive but sometimes technically challenging intervention typically reserved for the treatment of older patients with…”
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Timing of Intubation in Coronavirus Disease 2019: A Study of Ventilator Mechanics, Imaging, Findings, and Outcomes by Bavishi, Avni A, Mylvaganam, Ruben J, Agarwal, Rishi, Avery, Ryan J, Cuttica, Michael J

“…Determine the variation in outcomes and respiratory mechanics between the subjects who are intubated earlier versus later in their coronavirus disease 2019…”
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A comparative review of 1,004 orthopaedic trauma patients before and during the COVID-19 pandemic by Dayananda, Kathryn S S, Mercer, Scott T, Agarwal, Rishi, Yasin, Tariq, Trickett, Ryan W

“…COVID-19 necessitated abrupt changes in trauma service delivery. We compare the demographics and outcomes of patients treated during lockdown to a matched…”
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Combined Antiangiogenic and Mammalian Target of Rapamycin Inhibitor Targeted Therapy in Metaplastic Breast Cancer Harboring a PIK3CA Mutation by Agarwal, Rishi, Koenig, Kimberly, Rohren, Eric, Subbiah, Vivek

“…Metaplastic breast cancer (MpBC) is an extremely rare breast cancer subtype, characterized by a heterogeneous phenotype. MpBC aggressive biology is attributed…”
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Pontine stroke presenting as isolated facial nerve palsy mimicking Bell's palsy: a case report by Agarwal, Rishi, Manandhar, Lochana, Saluja, Paramveer, Grandhi, Bala

“…Isolated facial nerve palsy usually manifests as Bell's palsy. Lacunar infarct involving the lower pons is a rare cause of solitary infranuclear facial…”
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Continuous Transversus Abdominis Plane (TAP) Blocks for Postoperative Pain Control after Hernia Surgery: A Randomized, Triple‐Masked, Placebo‐Controlled Study by Heil, Justin W., Nakanote, Ken A., Madison, Sarah J., Loland, Vanessa J., Mariano, Edward R., Sandhu, NavParkash S., Bishop, Michael L., Agarwal, Rishi R., Proudfoot, James A., Ferguson, Eliza J., Morgan, Anya C., Ilfeld, Brian M.

“…Background Single‐injection transversus abdominis plane (TAP) block provides postoperative analgesia and decreases supplemental analgesic requirements…”
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Fe(IV) alkylidenes are actually Fe(II), and a related octahedral Fe(II) “alkylidene” is a conjugated vinyl complex by Jacobs, Brian P., Agarwal, Rishi G., Wolczanski, Peter T., Cundari, Thomas R., MacMillan, Samantha N.

“…Calculations on previously synthesized “Fe(IV) alkylidenes” are more consistent with Fe(II) centers bound to carbenium and oxidized chelate ligands. Attempts…”
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