Search Results - "Adhikari, Debashis"
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Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction
Published in Chemical science (Cambridge) (21-08-2019)“…Storing and transferring electrons for multi-electron reduction processes are considered to be the key steps in various important chemical and biological…”
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2
Tuning the redox non-innocence of a phenalenyl ligand toward efficient nickel-assisted catalytic hydrosilylation
Published in Chemical science (Cambridge) (2018)“…In this report, a ligand-redox assisted catalytic hydrosilylation has been investigated. A phenalenyl ligand coordinated nickel complex has been utilized as an…”
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3
Retraction Note: Modulation instability induced supercontinuum generation in defective core photonic crystal fiber
Published in Optical and quantum electronics (11-09-2024)Get full text
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4
Cyclic (Alkyl)amino Carbene Based Iron Catalyst for Regioselective Dimerization of Terminal Arylalkynes
Published in Organometallics (14-11-2016)“…[(cAAC)Fe(CO)4] (1) catalyzed head-to-head dimerization of terminal arylalkynes toward conjugated enynes in very high yield and high E selectivity (up to…”
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5
Addition of Ammonia, Water, and Dihydrogen Across a Single Pd−Pd Bond
Published in Journal of the American Chemical Society (29-08-2007)“…Pincer-supported Pd alkyl complexes (PNP)PdR undergo photochemical conversion to a dimeric (PNP)Pd−Pd(PNP) complex with a single Pd−Pd bond. Dissociation of…”
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RETRACTED ARTICLE: Modulation instability induced supercontinuum generation in defective core photonic crystal fiber
Published in Optical and quantum electronics (2022)“…We theoretically investigate effect of defect on modulation instability induced supercontinuum generation in a defective core photonic crystal fiber. We…”
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7
Selective Surface and Near-Surface Modification of a Noncatenated, Catalytically Active Metal-Organic Framework Material Based on Mn(salen) Struts
Published in Inorganic chemistry (18-04-2011)“…From a combination of chiral Mn(salen) struts and the tetratopic ligand tetrakis(4-carboxyphenyl)benzene, a large-pore, noncatenated metal-organic framework…”
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[(Salcen)Cr(III) + Lewis base]-catalyzed synthesis of N-aryl-substituted oxazolidinones from epoxides and aryl isocyanates
Published in Chemical communications (Cambridge, England) (01-01-2014)“…[(Salcen)Cr(III) + Lewis base] was found to be a highly active and selective catalyst system in the [2+3] cycloaddition between epoxides and isocyanates to…”
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9
Mode division multiplexing free space optics system with 3D hybrid modulation under dust and fog
Published in Alexandria engineering journal (01-01-2023)“…Mode division multiplexing (MDM) is an emerging information transmission technique in which multiple data signals can be transmitted simultaneously on…”
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10
Structural, Spectroscopic, and Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis
Published in Journal of the American Chemical Society (19-03-2008)“…Pincer-type ligands are believed to be very robust scaffolds that can support multifarious functionalities as well as highly reactive metal motifs applied in…”
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Mild Protocol for the Synthesis of Stable Nickel Complexes Having Primary and Secondary Silyl Ligands
Published in Organometallics (13-04-2009)“…A mild protocol for the synthesis of (PNP)Ni(SiH 2 Ph) and (PNP)Ni(SiHPh2) (PNP − = N[2-P(CHMe2)2-4-MeC6H3]2) stemming from the hydride complex (PNP)NiH is…”
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12
Ligand-Based Redox: Catalytic Applications and Mechanistic Aspects
Published in ACS catalysis (21-10-2022)“…For the last few decades, coordination chemists have seen many ligands whose role pervades far beyond being a supporting ancillary. The ambiguity in their…”
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13
Homogeneous Nickel-Catalyzed Sustainable Synthesis of Quinoline and Quinoxaline under Aerobic Conditions
Published in Journal of organic chemistry (04-12-2020)“…Dehydrogenative coupling-based reactions have emerged as an efficient route toward the synthesis of a plethora of heterocyclic rings. Herein, we report an…”
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Phosphine-Free Manganese Catalyst Enables Selective Transfer Hydrogenation of Nitriles to Primary and Secondary Amines Using Ammonia–Borane
Published in ACS catalysis (05-03-2021)“…Herein we report the synthesis of primary and secondary amines by nitrile hydrogenation, employing a borrowing hydrogenation strategy. A class of…”
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15
Super-Reducing Behavior of Benzo[b]phenothiazine Anion Under Visible-Light Photoredox Condition
Published in Journal of the American Chemical Society (18-10-2023)“…Herein we describe the anion of benzo[b]phenothiazine as a super reductant species upon excitation by visible light. In contrary to N-substituted…”
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Nickel‐Catalyzed Selective Synthesis of α‐Alkylated Ketones via Dehydrogenative Cross‐Coupling of Primary and Secondary Alcohols
Published in Advanced synthesis & catalysis (04-01-2022)“…Herein, we describe an isolable, air‐stable, homogeneous, nickel catalyst that performs dehydrogenative cross‐coupling reaction between secondary and primary…”
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Borrowing Hydrogen-Mediated N‑Alkylation Reactions by a Well-Defined Homogeneous Nickel Catalyst
Published in ACS catalysis (04-10-2019)“…We report herein a well-defined and bench-stable azo-phenolate ligand-coordinated nickel catalyst which can efficiently execute N-alkylation of a variety of…”
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A 2‐Anilidomethylpyridine Ligand Framework Showcasing Hydride Storage and Transfer Abilities in Its Aluminum Chemistry
Published in Chemistry : a European journal (11-07-2023)“…Dearomatized 1,4‐dihydropyridyl motifs are significant in both chemistry and biology for their potential abilities to deliver the stored hydride, driven by…”
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H2S Reactivity on Oxygen-Deficient Heterotrimetallic Cores: Cluster Fluxionality Simulates Dynamic Aspects of Surface Chemical Reactions
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (28-01-2016)“…Understanding the mechanistic aspects of heterogeneous reactions on supported metal catalysts is challenging due to several disparate factors, among which the…”
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Shining Light on Organometallic Chemistry
Published in Organometallics (26-08-2024)Get full text
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