Search Results - "Addanki, Rupa Bai"
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Regio- and Stereoselective C‑Glycosylation of Indoles Using o‑[1‑(p‑MeO-Phenyl)vinyl]benzoates (PMPVB) as Glycosyl Donors under Brønsted Acid Catalysis
Published in Journal of organic chemistry (03-02-2023)“…The alkene-based o-[1-(p-MeO-phenyl)vinyl]benzoates (PMPVB) donors that can be remotely activated under catalytic Brønsted acidic conditions have been…”
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Sterically Strained Brønsted Pair Catalysis by Bulky Pyridinium Salts: Direct Stereoselective Synthesis of 2‑Deoxy and 2,6-Dideoxy-β-thioglycosides from Glycals
Published in Journal of organic chemistry (03-12-2021)“…A sterically strained ionic Brønsted pair complex obtained from a sterically bulky base 2,4,6-tri-tert-butylpyridine and hydrochloric acid imbues unusual…”
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Glycosyl o‑[1‑(p‑MeO-Phenyl)vinyl]benzoates (PMPVB) as Easily Accessible, Stable, and Reactive Glycosyl Donors for O‑, S‑, and C‑Glycosylations under Brønsted Acid Catalysis
Published in Journal of organic chemistry (03-06-2022)“…Methods suitable for the synthesis of both O- and S-glycosylations are relatively rare because commonly used promoters like halonium sources or gold catalysts…”
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TfO–···H–O–H Interaction-Assisted Generation of a Silicon Cation from Allylsilanes: Access to Phenylallyl Ferrier Glycosides from Glycals
Published in Organic letters (25-02-2022)“…We demonstrate here that the strained and bulky protonated 2,4,6-tri-tert-butylpyridine (TTBPy) triflate salt serves as a mild and efficient organocatalyst for…”
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Exploiting the Strained Ion-Pair Interactions of Sterically Hindered Pyridinium Salts Toward SN2 Glycosylation of Glycosyl Trichloroacetimidates
Published in Journal of organic chemistry (15-03-2024)“…We demonstrate here that strained and sterically hindered protonated 2,4,6-tri-tert-butylpyridinium (TTBPy) tetrafluoroborate, a crystalline, bench stable salt…”
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Exploiting the Strained Ion-Pair Interactions of Sterically Hindered Pyridinium Salts Toward S N 2 Glycosylation of Glycosyl Trichloroacetimidates
Published in Journal of organic chemistry (15-03-2024)“…We demonstrate here that strained and sterically hindered protonated 2,4,6-tri- -butylpyridinium (TTBPy) tetrafluoroborate, a crystalline, bench stable salt…”
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