Heat conduction in oxide glasses: Balancing diffusons and propagons by network rigidity

Understanding the variation of thermal conduction in disordered oxides is important for applications related to energy saving and electronics but currently lacks fundamental insight into the phonon propagation mechanisms. In this Letter, we report a strong correlation between thermal conductivity an...

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Bibliographic Details
Published in:	Applied physics letters Vol. 117; no. 3
Main Authors:	Sørensen, Søren S., Pedersen, Elsebeth J., Paulsen, Frederikke K., Adamsen, Ida H., Laursen, Jonas L., Christensen, Sofia, Johra, Hicham, Jensen, Lars R., Smedskjaer, Morten M.
Format:	Journal Article
Language:	English
Published:	Melville American Institute of Physics 20-07-2020
Subjects:	Applied physics Conduction heating Conductive heat transfer Energy conservation Heat conductivity Phonons Propagation Rigidity Thermal conductivity
Online Access:	Get full text
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Summary:	Understanding the variation of thermal conduction in disordered oxides is important for applications related to energy saving and electronics but currently lacks fundamental insight into the phonon propagation mechanisms. In this Letter, we report a strong correlation between thermal conductivity and the speed of sound within two families of modified oxide glass formers, in agreement with phonon-gas-theory predictions for crystalline materials. Based on calculations of diffuson-mediated heat transport, we then show that thermal conductivity in borate glasses is dominated by diffusive vibrational modes, while both diffusive and propagative modes contribute to heat conduction in silicate glasses. This fundamental difference in the heat propagation mechanism originates from differences in the phonon mean free path of low-frequency modes caused by the inherent variation of atomic rigidity between silicate and borate glasses.
ISSN:	0003-6951 1077-3118
DOI:	10.1063/5.0013400