Search Results - "Adams, Matt R."

Diazaphospholene Precatalysts for Imine and Conjugate Reductions by Adams, Matt R., Tien, Chieh‐Hung, Huchenski, Blake S. N., Ferguson, Michael J., Speed, Alexander W. H.

“…The first examples of 1,3,2‐diazaphospholene‐catalyzed imine reduction and conjugate reduction reactions are reported. This approach employs readily…”
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Asymmetric Imine Hydroboration Catalyzed by Chiral Diazaphospholenes by Adams, Matt R., Tien, Chieh‐Hung, McDonald, Robert, Speed, Alexander W. H.

“…The first use of diazaphospholenes as chiral catalysts has been demonstrated with enantioselective imine hydroboration. A chiral diazaphospholene prepared in a…”
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Hydroboration Catalyzed by 1,2,4,3-Triazaphospholenes by Tien, Chieh-Hung, Adams, Matt R, Ferguson, Michael J, Johnson, Erin R, Speed, Alexander W. H

“…The synthesis and study of the catalytic activity of 1,2,4,3-triazaphospholenes (TAPs) is reported. TAPs represent a more modular scaffold than previously…”
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Enantioselective Imine Reduction Catalyzed by Phosphenium Ions by Lundrigan, Travis, Welsh, Erin N, Hynes, Toren, Tien, Chieh-Hung, Adams, Matt R, Roy, Kayelani R, Robertson, Katherine N, Speed, Alexander W. H

“…The first use of phosphenium cations in asymmetric catalysis is reported. A diazaphosphenium triflate, prepared in two or three steps on a multigram scale from…”
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Correction to “Enantioselective Imine Reduction Catalyzed by Phosphenium Ions” by Lundrigan, Travis, Welsh, Erin N., Hynes, Toren, Tien, Chieh-Hung, Adams, Matt R., Roy, Kayelani R., Robertson, Katherine N., Speed, Alexander W. H.

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Total Synthesis of Entrectinib with Key Photo‐Redox Mediated Cross‐Coupling in Flow by Cordell, Morgan J., Adams, Matt R., Vincent‐Rocan, Jean‐François, Riley, John G.

“…By using photo‐redox catalysis in flow the newly marketed drug entrectinib (referred to by the brand name Rozlytrek) was synthesized in 6 linear steps from…”
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Synthesis and Catalytic Reactivity of Bis(amino)cyclopropenylidene Carbene–Borane Adducts by Huchenski, Blake S. N, Adams, Matt R, McDonald, Robert, Ferguson, Michael J, Speed, Alexander W. H

“…The first reported neutral boron­(III) adducts of bis­(amino)­cyclopropenylidene carbenes (BAC carbenes) have been synthesized, structurally characterized, and…”
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A computational investigation into the redox chemistry of Mo- and W-tris(diselenolene) complexes by Bushnell, Eric A. C., Adams, Matt R., Boyd, Russell J.

“…Since the 1960s, dithiolene complexes have been intensely studied; however, the same cannot be said about diselenolene complexes. Thus, the chemistry…”
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Asymmetric Imine Hydroboration Catalyzed by Chiral Diazaphospholenes by Adams, Matt R., Tien, Chieh‐Hung, McDonald, Robert, Speed, Alexander W. H.

“…The first use of diazaphospholenes as chiral catalysts has been demonstrated with enantioselective imine hydroboration. A chiral diazaphospholene prepared in a…”
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Diazaphospholene Precatalysts for Imine and Conjugate Reductions by Adams, Matt R., Tien, Chieh‐Hung, Huchenski, Blake S. N., Ferguson, Michael J., Speed, Alexander W. H.

“…The first examples of 1,3,2‐diazaphospholene‐catalyzed imine reduction and conjugate reduction reactions are reported. This approach employs readily…”
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Cover Feature: Total Synthesis of Entrectinib with Key Photo‐Redox Mediated Cross‐Coupling in Flow (Eur. J. Org. Chem. 4/2022) by Cordell, Morgan J., Adams, Matt R., Vincent‐Rocan, Jean‐François, Riley, John G.

“…The Cover Feature shows two surfers going with the flow, riding the flow of the waves, inspired by photo‐redox flow chemistry. The surfers ride beautiful blue…”
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Process Intensification and Increased Safety for the On-Demand Continuous Flow Synthesis of Dithiothreitol, a Crucial Component in Polymerase Chain Reaction Testing Kits by Dubois, Maryne A. J., Carreras, Virginie, Adams, Matt R., Kairouz, Vanessa, Vincent-Rocan, Jean-François, Riley, John G., Charette, André B.

“…The importance of rapid access to diagnostics tools in the identification of pathogensincluding their crucial component, bioreagentswas recently underscored…”
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Organotin bond dissociation energies: An interesting challenge for contemporary computational methods by Adams, Matt R., Bushnell, Eric A.C., Bruce Grindley, T., Boyd, Russell J.

“…[Display omitted] •Little is known about organotin BDEs experimentally or computationally.•Organotin BDEs are a challenge for contemporary computational…”
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