Search Results - "Abney, Kent D"
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Higher Order Speciation Effects on Plutonium L3 X-ray Absorption Near Edge Spectra
Published in Inorganic chemistry (12-01-2004)“…Pu L3 X-ray near edge absorption spectra for Pu(0−VII) are reported for more than 60 chalcogenides, chlorides, hydrates, hydroxides, nitrates, carbonates,…”
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2
Surface Effects on Cation Transport across Porous Alumina Membranes
Published in Langmuir (07-12-1999)“…Transport behavior of monovalent and divalent solutes across mesoporous Anopore γ-alumina membranes was investigated as a function of pore diameter, pH, ionic…”
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3
The effects of thermal annealing on commercial Nafion ® membranes
Published in Journal of membrane science (20-07-2007)“…The effect of thermal annealing as a pretreatment procedure for Nafion ® membranes was investigated. Commercial membranes with different thicknesses and ages…”
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4
Purification of Plutonium Chloride Solutions via Precipitation and Washing
Published in Separation science and technology (01-06-2006)“…Pyrochemical operations at Los Alamos Plutonium Facility use high temperature melts of calcium, sodium, and potassium salts in the plutonium metal purification…”
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Removal of Water from Aqueous Nitric Acid Using Bifunctional Perfluorinated Ionomer Membranes
Published in Industrial & engineering chemistry research (29-08-2007)“…A series of Nafion films with both carboxylic and sulfonic acid functional groups were prepared and tested for water/nitric acid permselectivity. Unlike the…”
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6
Synthesis and Characterization of AU2Se6 (A = K, Cs)
Published in Inorganic chemistry (19-04-2004)“…Two new ternary uranium selenides, AU2Se6 (A = K, Cs), were prepared using the reactive flux method. Single crystal X-ray diffraction was performed on single…”
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Synthesis and Structural Characterization of the First Quaternary Plutonium Thiophosphates: K3Pu(PS4)2 and APuP2S7 (A = K, Rb, Cs)
Published in Journal of the American Chemical Society (20-02-2002)“…The first quaternary plutonium metal thiophosphates have been synthesized by the reactive flux method and characterized by single-crystal X-ray diffraction: …”
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Three New Phases in the K/Cu/Th/S System: KCuThS3, K2Cu2ThS4, and K3Cu3Th2S7
Published in Inorganic chemistry (05-09-2005)“…Synthetic exploration of K/Cu/Th/S quaternary phase space has yielded three new compounds: KCuThS3 (I), K2Cu2ThS4 (II), and K3Cu3Th2S7 (III). All three phases…”
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Synthesis and Characterization of Six New Quaternary Actinide Thiophosphate Compounds: Cs8U5(P3S10)2(PS4)6 , K10Th3(P2S7)4(PS4)2, and A5An(PS4)3, (A = K, Rb, Cs; An = U, Th)
Published in Inorganic chemistry (04-06-2001)“…Six new actinide metal thiophosphates have been synthesized by the reactive flux method and characterized by single-crystal X-ray diffraction: …”
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10
Synthesis and Structural Characterization of Quaternary Thorium Selenophosphates: A2ThP3Se9 (A = K, Rb) and Cs4Th2P5Se17
Published in Inorganic chemistry (10-07-2000)“…Single crystals of A2ThP3Se9 (A = K (I), Rb (II)) and Cs4Th2PsSe17 (III) form from the reaction of Th and P in a molten A2Se3/Se (A = K, Rb, Cs) flux at 750 °C…”
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Surface Effects on Metal Ion Transport across Porous Alumina Membranes. 2. Trivalent Cations: Am, Tb, Eu, and Fe
Published in Langmuir (22-08-2000)“…Transport behavior of trivalent solutes across mesoporous Anopore γ-alumina membranes was investigated as a function of pore diameter, pH, ionic strength, and…”
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12
Low-Temperature Synthesis of Uranium Tetraboride by Solid-State Metathesis Reactions
Published in Inorganic chemistry (06-05-2002)“…A novel synthesis of uranium tetraboride (UB4) by solid-state metathesis reaction is demonstrated. This approach significantly lowers the temperature required…”
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13
Butyllithium Deprotonation vs Alkali Metal Reduction of Cobalt Dicarbollide: A New Synthetic Route to C-Substituted Derivatives
Published in Inorganic chemistry (26-02-1997)“…Reduction of Cs[Co(1,2-C2B9H11)2] (Cs[I]) with 1 equiv of Na(Hg) amalgam or Cs metal forms the cobalt(II) dianion, [Co(1,2-C2B9H11)2]2- (II), which reverts to…”
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14
Synthesis, Structure, and Properties of Cs4Th4P4Se26: A Quaternary Thorium Selenophosphate Containing the (P2Se9)6- Anion
Published in Inorganic chemistry (10-09-2001)“…Orange crystals of Cs4Th4P4Se26 were grown from the reaction of 232Th and P in a Cs2Se3/Se molten salt flux at 750 °C. Cs4Th4P4Se26 crystallizes in the…”
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15
New synthetic routes to B-halogenated derivatives of cobalt dicarbollide
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16
Metal corrosion studies with the fluorosulphonic acid–antimony pentafluoride superacid system
Published in Journal of alloys and compounds (25-02-2004)“…Because of their rapid dissolution of many actinide metals and refractory oxides, superacids such as HSO 3F/SbF 5 have potential applications in actinide…”
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Synthesis of [Li(THF)4]2[Th(η5-C2B9H11)2X2] (X = Cl, Br, I): The First Dicarbollide Complexes of Thorium
Published in Inorganic chemistry (10-09-1997)“…The first thorium complexes incorporating dicarbollide ligands, [Li(THF)4]2[Th(η5-C2B9H11)2X2] (X = Cl, Br, I) and [Li(THF)4][Th(η5-C2B9H11)Br3(THF)], have…”
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18
Plutonium Oxide Polishing for MOX Fuel Production
Published in Separation science and technology (01-01-2005)“…Los Alamos National Laboratory (LANL) has been tasked to produce 120 kg of plutonium as highly purified PuO 2 for the European Mixed Oxide (MOX) Lead Test…”
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19
Aqueous Ion Transport Studies in Stainless Steel Membranes
Published in Industrial & engineering chemistry research (11-06-2003)“…Aqueous ion transport through unmodified, acid/base resistant, stainless steel membrane material was investigated to determine the feasibility of using the…”
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Synthesis, Structure, and Reactivity of 1,2-(1‘,1‘,2‘,2‘-Tetramethyldisilane-1‘,2‘)carborane
Published in Inorganic chemistry (08-02-1999)“…The novel strained compound 1,2-(1‘,1‘,2‘,2‘-tetramethyldisilane-1‘,2‘)carborane (1) was synthesized by the reaction of 1,2-dilithiocarborane and…”
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