Search Results - "Abbenhuis, Hendrikus C. L."
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An Efficient Hybrid, Nanostructured, Epoxidation Catalyst: Titanium Silsesquioxane-Polystyrene Copolymer Supported on SBA-15
Published in Chemistry : a European journal (01-01-2007)“…A novel interfacial hybrid epoxidation catalyst was designed with a new immobilization method for homogeneous catalysts by coating an inorganic support with an…”
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Metal functionalized POSS as fire retardants in polypropylene
Published in Polymer degradation and stability (01-10-2006)“…This paper deals with the study of the combustion properties of dimeric and oligomeric Al-and Zn-isobutyl silsesquioxane (POSS)/polypropylene (PP) composites,…”
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Mesoporous Organic-Inorganic Hybrid Materials Built Using Polyhedral Oligomeric Silsesquioxane Blocks
Published in Angewandte Chemie International Edition (01-01-2007)“…Rounding up the POSSe: Polyhedral oligomeric silsesquioxanes (POSS), one of the smallest hybrid nano building blocks, were weaved into multifunctional…”
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Role of Intermolecular Interactions in Oxygen Transfer Catalyzed by Silsesquioxane Trisilanolate Vanadium(V)
Published in Inorganic chemistry (01-06-2009)“…The polyhedral oligomeric silsesquioxane trisilanolate vanadium(V) complex 1 efficiently catalyzes oxidations at room temperature using cumyl hydroperoxide as…”
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Lignin oxidation with an organic peroxide and subsequent aromatic ring opening
Published in International journal of biological macromolecules (15-02-2019)“…The oxidation of an organosolv lignin with tert-butylhydroperoxide, initiated by titanium grafted into the lignin structure, was investigated. Titanation of…”
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Iron(III) species dispersed in porous silica through sol–gel chemistry
Published in Journal of non-crystalline solids (15-01-2008)“…Fe/SiO2 catalysts have been prepared by two different sol–gel methods, cogelation and dissolution. The cogelation and dissolution preparative methods lead to…”
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Microporous Mg−Si−O and Al−Si−O Materials Derived from Metal Silsesquioxanes
Published in Chemistry of materials (17-09-2001)“…Microporous amorphous metallosilicates designated as Mg−Si−O and Al−Si−O, with a very narrow pore size distribution around 6 Å diameter, typical surface areas…”
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Organo-bridged silsesquioxane titanates for heterogeneous catalytic epoxidation with aqueous hydrogen peroxide
Published in Journal of catalysis (25-10-2007)“…Organo-bridged silsesquioxane titanates for heterogeneous catalytic epoxidation with aqueous hydrogen peroxide were synthesized through the acid-catalyzed…”
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Solid-Phase Immobilization of a New Epoxidation Catalyst
Published in Angewandte Chemie International Edition (16-02-1998)“…The heterogenization of a titanium(IV) silsesquioxane complex in an MCM‐41 molecular sieve, by tailoring the polarity of MCM‐41, results in self‐assembled…”
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Enantioselective epoxidation of β-methylstyrene catalyzed by immobilized Mn(salen) catalysts in different mesoporous silica supports
Published in Journal of catalysis (10-06-2008)“…Mesoporous silica-supported chiral Mn(salen) catalysts were prepared and evaluated in the heterogeneous asymmetric epoxidation of β-methylstyrene with NaClO as…”
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The Dynamic Status Quo of Polyhedral Silsesquioxane Coordination Chemistry
Published in European journal of inorganic chemistry (01-02-2004)“…The chemistry of polyhedral oligomeric silsesquioxanes (POSS) has taken a tremendous leap over the past decade. New synthetic approaches have been developed,…”
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Successful Application of a "Forgotten" Phosphine in Asymmetric Catalysis: A 9-Phosphabicyclo[3.3.1]non-9-yl Ferrocene Derivative as Chiral Ligand
Published in Organometallics (01-02-1995)Get full text
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Hierarchical fabrication of silica cocoon with hexagonally ordered channel constructed wall via an emulsion-assisted process
Published in Microporous and mesoporous materials (01-03-2012)“…[Display omitted] ► Hierarchical silica cocoons with hexagonally ordered channels were synthesized via an O/W emulsion-assisted process. ► The length of the…”
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Carbon-carbon and carbon-nitrogen bond formation mediated by ruthenium(II) complexes: synthesis of (1H)-isoquinolinium derivatives
Published in Organometallics (01-11-1993)Get full text
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Half-Sandwich Group 4 Metal Siloxy and Silsesquioxane Complexes: Soluble Model Systems for Silica-Grafted Olefin Polymerization Catalysts
Published in Organometallics (20-12-1999)“…The cuboctameric hydroxysilsesquioxane (c-C5H9)7Si8O12(OH) (2), obtained after hydrolysis of (c-C5H9)7Si8O12Cl (1), and triphenylsilanol have been applied as…”
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Synthesis and Characterization of Microporous Fe−Si−O Materials with Tailored Iron Content from Silsesquioxane Precursors
Published in The journal of physical chemistry. B (07-03-2002)“…Calcination of mixtures of (c-C5H9)7Si7O9(OH)3, 1, and (c-C5H9)7Si7O12Fe(tmeda), 2 (tmeda = N,N,N‘,N‘-tetramethylethylenediamine), led to microporous amorphous…”
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Half-Sandwich Titanium Complexes Stabilized by a Novel Silsesquioxane Ligand: Soluble Model Systems for Silica-Grafted Olefin Polymerization Catalysts
Published in Organometallics (23-11-1998)“…The cuboctameric silsesquioxane silanol (c-C5H9)7Si8O12(OH) has been applied as a model support for silica-grafted olefin polymerization catalysts. Complexes…”
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Ethylene Polymerization with Dimeric Zirconium and Hafnium Silsesquioxane Complexes
Published in Organometallics (21-12-1998)“…Treatment of the silanol (c-C5H9)7Si8O12(OH) with Cp‘‘Ti(CH2Ph)3 (Cp‘‘ = 1,3-C5H3(SiMe3)2) or TiCl4 selectively affords the mono(silsesquioxane) complexes…”
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Configurational Preferences and Alkylidene-Centered Reactivity of Tantalum Alkoxide Complexes Containing an Aryldiamine Spectator Ligand
Published in Organometallics (01-08-1994)Get full text
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